期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 19, 页码 12574-12585出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c00659J
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- ICT-IOC Bhubaneswar
A strategy for the synthesis of biologically relevant acyclic nucleoside analogs via highly regio-and stereoselective C-H functionalization employing heteroatom-assisted palladium-catalyzed carboxylation of 9-allyl adenine is disclosed. Different carboxylic acids were employed as substrates, providing decent to good yields of the desired products. The method also allowed for the synthesis of deuterated analogs.
Strategy for the synthesis of acyclic nucleoside analogs of biological relevance via highly regio-and stereoselective C-H functionalization employing heteroatom-assisted palladium -catalyzed carboxylation of 9-allyl adenine is disclosed. Substrate scope with different carboxylic acids was performed giving decent to good yields of the desired products. The method also allowed for the synthesis of deuterated analogs.
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