期刊
NANO ENERGY
卷 30, 期 -, 页码 217-224出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2016.09.029
关键词
Energy storage; Ni-Fe battery; Anode; Iron nanoparticles; Carbon shell
类别
资金
- China Scholarship Council [201306770015]
- Key Scientific Project of Wuhan City [2013011801010598]
- Scientific Project of AQSIQ [2013IK093]
Aqueous Ni-Fe battery with high safety and low cost is a promising candidate for large-scale electrical energy storage; their performance, however, has been limited by the poor performance of the Fe electrodes. We reported herein a facile synthesis of Fe particles coated with graphitic shell for high-performance Fe anodes. The anodes exhibit a high capacity of 224 mAh g(-1) at a high current density of 32 A g(-1), and a high capacity retention of 90% after 1000 cycles. When coupled with a cathode made from the composites of Ni(OH)(2) and nitrogen-doped graphene, the battery delivers a high energy density of 136.7 Wh kg(-1) at power density of 0.7 kW kg(-1) or 71.4 Wh kg-1 at 11.7 kW kg(-1) (based on the total mass of active materials). This work provides highly promising materials towards better Ni-Fe batteries.
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