期刊
NANO ENERGY
卷 22, 期 -, 页码 269-277出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2016.02.017
关键词
NiO; Nanodots; Self-assembly; Supercapacitor; Lithium-ion battery
类别
资金
- Chinese Ministry of Education in a framework of the Changjiang Scholar Innovative Research Team Program [IRT_15R52]
- Department of Chemistry, University of Cambridge
- International Science & Technology Cooperation Program of Chinese Ministry of Science and Technology [2015DFE52870]
- Chinese Ministry of Education [20120143120019]
- Hubei Provincial Natural Science Foundation [2014CFB160]
- National Science Foundation for Young Scholars of China [51302204]
- Royal Academy of Engineering through a research Fellowship (Graphlex)
We report a binder-free three-dimensional (3D) macro-mesoporous electrode architecture via self-assembly of 3 nm NiO nanodots on macroporous nickel foam for high performance supercapacitor-like lithium battery. This electrode architecture provides a hierarchically 3D macro-mesoporous electrolyte -filled network that simultaneously enables rapid ion transfer and ultra-short solid-phase ion diffusion. Benefitting from the structural superiority owing to the interconnected porous hierarchy, the electrode exhibits supercapacitor-like high rate capabilities with high lithium battery capacities during the discharge-charge process: a very high capacity of 518 mA h g(-1) at an ultrahigh current density of 50 A g(-1). It exceeds at least similar to 10 times than that of the state-of-the-art graphite anode, which shows only similar to 50 mA h g(-1) at 2 to 3 A g(-1) as anode for Li-ion batteries. The preparation method of 3D interconnected hierarchically macro-mesoporous electrode presented here can provide an efficient new binder-free electrode technique towards the development of high-performance supercapacitor-like Li-ion batteries. (C) 2016 Elsevier Ltd. All rights reserved.
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