期刊
NANO ENERGY
卷 20, 期 -, 页码 176-184出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2015.12.022
关键词
Lithium-sulfur batteries; Carbon coating; Separator; Rate capability; Sulfur loading
类别
资金
- SCEYE S. A. [2015-0888]
Lithium-sulfur batteries have received intense attention because of their high theoretical capacity, low cost and environmental friendliness. However, low active material utilization and poor cycle life limit their practical applications. Here, we report a strategy to obtain high capacity with long cycle life and rapid charge rate by introducing a carbon coating on the separator. Excellent cycling performance with a high capacity 956 mAh g(-1) after 200 cycles and outstanding high-rate response up to 4 C are achieved, which are among the best reports so far. High electrochemical performance can be obtained even at a high sulfur loading of 3.37 mg cm(-2). Such improved results could be ascribed to the conductive carbon coating, which not only reduces the cell resistance but blocks the diffusion of soluble polysulfides avoiding shuttle effect during cycling. This study demonstrates a feasible, low cost and scalable approach to address the long-term cycling challenge for lithium-sulfur batteries. (C) 2015 Elsevier Ltd. All rights reserved.
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