Versatile hydrogen-bonded organic framework (HOF) platform for simultaneous detection and efficient removal of heavy metal ions

The ever-deteriorating water pollution problem caused by heavy metal ions has spurred the development of new materials for efficient detection and removal of heavy metal ions. In this work, a porous hydrogen-bonded organic framework (HOF) PFC-1 was found to be excellent sensors for Pb2+ and Cu2+ via fluorescent quench-ing effect, with good selectivity and low limit of detection (LOD) values. Surprisingly, PFC-1 also exhibited superior removal abilities towards Pb2+ and Cu2+, with maximum adsorption capacities of 384.6 and 214.1 mg/g at 298.15 K, respectively, which are comparable with the performance of some MOFs and COFs adsorbents. Langmuir isotherm model and pseudo-second-order kinetic model could well illustrate the adsorption processes towards these two heavy metals. PXRD, FTIR, XPS and DFT modeling were employed together to investigate the mechanism of fluorescent quenching and adsorption for Pb2+ and Cu2+. The results indicated that electrostatic interactions and host-guest interactions afforded PFC-1 excellent detection and removal performance for Pb2+ and Cu2+. Results presented in this work provided new inspirations for broader applications of HOFs materials in the area of environmental remediation.

Automated summary

In this study, a porous hydrogen-bonded organic framework (HOF) PFC-1 was found to be an excellent sensor and remover for Pb2+ and Cu2+ ions. The results showed that PFC-1 exhibited remarkable adsorption capacities for Pb2+ and Cu2+, and the adsorption processes can be well described by Langmuir isotherm model and pseudo-second-order kinetic model. The mechanism of fluorescent quenching and adsorption for Pb2+ and Cu2+ was investigated using PXRD, FTIR, XPS, and DFT modeling, revealing the importance of electrostatic interactions and host-guest interactions in the performance of PFC-1. These findings provide new inspirations for the broader applications of HOF materials in environmental remediation.