期刊
LIGHT-SCIENCE & APPLICATIONS
卷 5, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/lsa.2016.24
关键词
high-color-rendering; single Eu2+-activated; solid solution; white-emitting phosphor
类别
资金
- National Natural Science Foundations of China [51302034, 11304035, 51372036, 31271442, 91233204]
- National Basic Research Program [2012CB933703]
- Fundamental Research Funds for the Central Universities [12QNJJ007, 12SSXM001]
- International Science & Technology Cooperation Program of China [2013DFG50150]
- 111 project [B13013]
Single-phased, high-color-rendering index (CRI) white-light phosphors are emerging as potential phosphor-converted white-light-emitting diodes (WLEDs) and as an alternative to blends of tricolor phosphors. However, it is a challenge to create a high CRI white light from a single-doped activator. Here, we present a high CRI (Ra =91) white-light phosphor, Sr-5(PO4)(3-x)(BO3)(x)Cl:Eu2+, composed of Sr-5(PO4)(3)Cl as the beginning member and Sr-5(BO3)(3)Cl as the end member. This work utilized the solid-solution method, and tunable Eu2+ emission was achieved. Color-tunable Eu2+ emissions in response to structural variation were observed in Sr-5(PO4)(3-x)(BO3)(x)Cl solid solutions. This was further confirmed using X-ray Rietveld refinement, electron paramagnetic resonance spectroscopy, and in the photoluminescence spectra. The color-tunable emissions included the white light that originated from the combination of the blue emission of Sr-5(PO4)(3)Cl:Eu2+ and an induced Eu2+ yellow emission at approximately 550 nm in the solid solution. Importantly, the white-light phosphors showed a greater R9 = 90.2 under excitation at 365 nm. This result has rarely been reported in the literature and is greater than that of (R9 = 14.3) commercial Y3Al5O12:Ce3+-based WLEDs. These findings demonstrate the great potential of Sr-5(PO4)(3-x)(BO3)(x)Cl:0.04Eu(2+) as a white-light phosphor for near-UV phosphor-converted WLEDs. These results also provide a shortcut for developing a high CRI white-light phosphor from a single Eu2+-doped compound.
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