☆ 4.8 Review

S-scheme heterojunction photocatalysts for CO2 reduction

MATTER (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Physical

TiO2/In2S3 S-scheme photocatalyst with enhanced H2O2-production activity

Yi Yang et al.

Summary: An S-scheme heterojunction is constructed in a hybrid TiO2/In2S3 photocatalyst, which greatly promotes the separation of photogenerated carriers and enhances the production of H2O2. Computational methods and experiments are used to study the charge transfer and separation mechanisms within the S-scheme heterojunction.

NANO RESEARCH (2023)

添加到收藏夹

Review Chemistry, Multidisciplinary

Emerging S-Scheme Photocatalyst

Liuyang Zhang et al.

Summary: This article presents the superiority and design criteria of the emerging S-scheme heterojunction in photocatalysis. By overcoming the challenges faced by single photocatalysts through the construction of heterojunctions, the S-scheme heterojunction has demonstrated its potential in improving photocatalysis. The critical understanding of the curved Fermi level in the S-scheme heterojunction interface and the current challenges and prospects of S-scheme heterojunction photocatalysts are also discussed.

ADVANCED MATERIALS (2022)

添加到收藏夹

Article Chemistry, Physical

Defective g-C3N4/covalent organic framework van der Waals heterojunction toward highly efficient S-scheme CO2 photoreduction

Jiangpeng Wang et al.

Summary: This study introduces a novel vdW heterojunction composite of g-C3N4 with nitrogen vacancies and Tp-Tta COF, showing effective interface contact area and improved photocatalytic CO2 reduction performance. The presence of nitrogen vacancies widens the Fermi level gap between g-C3N4 and Tp-Tta COF, leading to enhanced carrier recombination and higher photocatalytic activity and stability. The efficient electron transfer and CO2 affinity of Tp-Tta contribute to the enhanced CO selectivity in the S-scheme heterojunction photocatalyst design for CO2 reduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

添加到收藏夹

Article Chemistry, Physical

In situ construction of S-scheme AgBr/BiOBr heterojunction with surface oxygen vacancy for boosting photocatalytic CO2 reduction with H2O

Zerui Miao et al.

Summary: In this study, an AgBr/BiOBr heterojunction with surface oxygen vacancies was synthesized using a simple chemical method, which showed significantly improved photoreduction rates of CO2 compared to pure BiOBr. The unique S-scheme band structure and oxygen vacancies were found to enhance the utilization of sunlight and increase the separation and transfer of photogenerated charge carriers, leading to efficient photocatalytic reduction of CO2.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

添加到收藏夹

Article Chemistry, Physical

Photocatalytic CO2 reduction to HCOOH over core-shell Cu@Cu2O catalysts

Hui Wang et al.

Summary: In this study, uniform core-shell nanoparticles composed of a Cu core encapsulated by a Cu2O shell were fabricated by thermal treatment of a Cu-MOF precursor, showing catalytic activity in the conversion of CO2 to HCOOH. Mechanistic studies revealed that the Cu2O shell acted as the active sites for the adsorption and activation of CO2, contributing to the high HCOOH production rate achieved without any additives at room temperature.

CATALYSIS COMMUNICATIONS (2022)

添加到收藏夹

Article Chemistry, Physical

S-Scheme Heterojunction and Defect Site Engineering on CuxIn5S8-Cu2-ySe for Highly Efficient Photoreduction of CO2 to methanol

Hui Zhao et al.

Summary: The study successfully synthesized a new photocatalyst and revealed its excellent activity and new mechanism in the reduction of CO2 to methanol. This provides a promising approach to improve photocatalytic performance and opens up a new pathway for selective CO2 photocatalytic reduction to methanol.

CHEMCATCHEM (2022)

添加到收藏夹

Article Engineering, Environmental

Tungsten oxide quantum dots deposited onto ultrathin CdIn2S4 nanosheets for efficient S-scheme photocatalytic CO2 reduction via cascade charge transfer

Zhenzong Zhang et al.

Summary: A novel S-scheme photocatalytic heterojunction composite nanomaterial, WCIS, has been developed for efficient CO2 reduction to CO and CH4. The composite shows higher yields compared to CIS due to the electron transfer path between WQDs and CIS. Additionally, WCIS exhibits a stable crystal structure and recycling ability.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Article Engineering, Environmental

Formation of hierarchical Bi2MoO6/ln2S3 S-scheme heterojunction with rich oxygen vacancies for boosting photocatalytic CO2 reduction

Bo Yu et al.

Summary: Hierarchical Bi2MoO6@In2S3 heterostructured nanotubes with surface oxygen vacancies were synthesized and demonstrated remarkable activity in visible-light-driven CO2 reduction. The combination of charge transfer mechanism and unique hierarchical hollow architectures effectively promoted the efficiency of light utilization and provided abundant reactive sites, leading to high yield rate and selectivity for CO-generation.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Step-Scheme Photocatalyst of CsPbBr3 Quantum Dots/BiOBr Nanosheets for Efficient CO2 Photoreduction

Zhijie Zhang et al.

Summary: In this study, a novel photocatalyst with outstanding performance in CO2 reduction was synthesized through a self-assembly process. The designed CsPbBr3 quantum dots/BiOBr nanosheets heterojunction showed superior photocatalytic activity, offering potential applications in the field of photocatalysis and solar energy utilization.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

Ultrathin indium vanadate/cadmium selenide-amine step-scheme heterojunction with interfacial chemical bonding for promotion of visible-light-driven carbon dioxide reduction

Feifei Mei et al.

Summary: The study focuses on the formation of interfacial chemical bonding in heterostructures to promote carrier transport. By preparing ultrathin InVO4 nanosheets and in-situ depositing CdSe-DETA nanobelts, a tight chemical bond is formed at the interface to enhance charge transfer, leading to improved photocatalytic CO2 reduction efficiency.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Inorganic Metal-Oxide Photocatalyst for H2O2 Production

Linxi Wang et al.

Summary: Hydrogen peroxide is a versatile oxidizing agent used in various applications, with its production via anthraquinone oxidation process being considered inefficient and environmentally unfriendly. Photocatalytic production of H2O2 using inorganic metal oxide semiconductors is a green and cost-effective alternative, although productivity is still a challenge in laboratory research. Efforts are being made to enhance the photocatalytic activity for H2O2 production, with modifications and quantification methods being explored for future advancements in this field.

SMALL (2022)

添加到收藏夹

Article Chemistry, Physical

Step-by-Step Mechanism Insights into the TiO2/Ce2S3 S-Scheme Photocatalyst for Enhanced Aniline Production with Water as a Proton Source

Feiyan Xu et al.

Summary: In this study, an S-scheme heterojunction was developed through theoretical design by growing Ce2S3 nanoparticles onto TiO2 nanofibers, resulting in enhanced photocatalytic activity. Density functional theory calculations and in situ experimental techniques revealed the electron transfer between Ce2S3 and TiO2, as well as the separation mechanism of photoexcited charge carriers.

ACS CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Physical

Sulfide-Based Photocatalysts Using Visible Light, with Special Focus on In2S3, SnS2 and ZnIn2S4

Jose C. Conesa

Summary: Sulfides are commonly used photocatalysts with strong visible light absorption, but also prone to photocorrosion. This article provides a summary of various sulfides used in photocatalytic processes and discusses their behavior. Experimental results show that octahedral sulfides can modify their wavelength-dependent photocatalytic activities and achieve artificial photosynthesis by combining with enzymes.

CATALYSTS (2022)

添加到收藏夹

Article Green & Sustainable Science & Technology

EPR Investigation on Electron Transfer of 2D/3D g-C3N4/ZnO S-Scheme Heterojunction for Enhanced CO2 Photoreduction

Mahmoud Sayed et al.

Summary: The study fabricated a robust S-scheme heterojunction that enhances the efficiency of CO2 photocatalytic conversion. This heterojunction is composed of 3D ZnO hollow spheres wrapped by 2D g-C3N4 layers. The photocatalyst showed a significantly higher CH4 production rate compared to pure ZnO and g-C3N4.

ADVANCED SUSTAINABLE SYSTEMS (2022)

添加到收藏夹

Article Chemistry, Physical

Electric Field Coupling in the S-Scheme CdS/BiOCl Heterojunction for Boosted Charge Transport toward Photocatalytic CO2 Reduction

Sai-Sai Wang et al.

Summary: In this study, the coupling of multiple electric fields and the accelerating of charge transfer in the CdS/BiOCl heterojunction were achieved by regulating the contact interface of CdS and BiOCl. The enhanced CO2 reduction activity of Cx-B001 is attributed to the more effective charge transport driven by the electric field at the heterojunction interface and the polarization electric field in the BiOCl phase.

ACS APPLIED ENERGY MATERIALS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Site-Specific Electron-Driving Observations of CO2-to-CH4 Photoreduction on Co-Doped CeO2/Crystalline Carbon Nitride S-Scheme Heterojunctions

Lei Cheng et al.

Summary: This study reports a method of controlling directional charge transfer by embedding single-atomic Co into CeO2 catalyst to achieve selective CO2 photoreduction to CH4. The results show that Co embedded into CeO2 catalyst can accelerate the transfer of electrons from carbon nitride to specific Co sites, thereby promoting CH4 formation. This method achieves high yield and high turnover number of CH4 production without the need for any sacrificial agent.

ADVANCED MATERIALS (2022)

添加到收藏夹

Article Engineering, Environmental

Embedding CsPbBr3 perovskite quantum dots into mesoporous TiO2 beads as an S-scheme heterojunction for CO2 photoreduction

Zhongliang Dong et al.

Summary: In this study, a CsPbBr3@mesoporous TiO2 beads (MTB) S-scheme heterojunction was developed, which showed boosted charge separation and CO2 photoreduction. The intimate interfacial interaction and staggered band structures of CsPbBr3 quantum dots embedded in MTB provided an efficient charge transfer route. The hybrid of 0.15CsPbBr3@MTB exhibited a remarkable enhancement in CO2 photoreduction, with a yield of 145.28 μmol g(-1)h(-1) under simulated sunlight irradiation, which was 4.64 and 3.49-fold higher than that of pristine MTB and CsPbBr3, respectively. This study provides valuable guidance for the design of perovskite-based heterojunctions for photocatalytic applications.

CHEMICAL ENGINEERING JOURNAL (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Non-Noble Plasmonic Metal-Based Photocatalysts

Mahmoud Sayed et al.

Summary: This review comprehensively summarizes the recent advances and applications of non-noble plasmonic metal (NNPMs)-based photocatalysts. By introducing the principles of surface plasmon resonance (SPR) and discussing the functionalities and attributes of NNPMs in photocatalysis, their applications in pollutant removal, water splitting, CO2 reduction, and organic transformations are explored. The review concludes by addressing the current challenges and future prospects in the field of plasmon-based photocatalysis, emphasizing its interdisciplinary nature across materials science, chemistry, and physics.

CHEMICAL REVIEWS (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Interior and Surface Synergistic Modifications Modulate the SnNb2O6/Ni-Doped ZnIn2S4 S-Scheme Heterojunction for Efficient Photocatalytic H2 Evolution

Chunxue Li et al.

Summary: Synergistic modifications of the interior and surface can enhance the photocatalytic activity at the atomic level. A new 2D/2D SnNb2O6/Ni-doped ZnIn2S4 (SNO/Ni-ZIS) S-scheme heterojunction was synthesized and showed significantly improved PHE activity under visible light. Theoretical calculations revealed that the S-scheme heterojunction promotes the desorption of H atoms for rapid H2 evolution. This work provides advanced insight for developing high-performance S-scheme systems.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Engineering, Environmental

High-performance photocatalytic decomposition of PFOA by BiOX/TiO2 heterojunctions: Self-induced inner electric fields and band alignment

Xiaoqing Liu et al.

Summary: BiOX/TiO2 photocatalysts prepared by hydrothermal method showed enhanced efficiency in photocatalytic decomposition of PFOA compared to sole BiOX or TiO2. The formation of p-n heterojunctions and the driving force of internal electric fields enabled the migration of photo-induced holes from TiO2 to BiOX, facilitating PFOA decomposition.

JOURNAL OF HAZARDOUS MATERIALS (2022)

添加到收藏夹

Article Materials Science, Multidisciplinary

Solar fuel generation over nature-inspired recyclable TiO2/g-C3N4 S-scheme hierarchical thin-film photocatalyst

Libo Wang et al.

Summary: In this study, a photocatalyst with high light utilization was designed, and efficient CO2 reduction was achieved through biomimetic plant structure and heterojunction construction. It has great potential for practical applications and industrial utilization.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

添加到收藏夹

Article Chemistry, Physical

Dynamics of Photogenerated Charge Carriers in Inorganic/Organic S-Scheme Heterojunctions

Linxi Wang et al.

Summary: By studying the behavior of photogenerated charge carriers in a heterojunction, we found that interfacial charge transfer in the step-scheme heterojunction occurs on a shorter time scale than recombination, leading to efficient charge separation. The charge-discharge property of polydopamine induces electron backflow, which is detrimental to practical photocatalytic applications. The composite showed higher photocatalytic H2O2-production activities due to faster H2O2 formation and suppressed H2O2 decomposition.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Challenges for photocatalytic overall water splitting

Chuanbiao Bie et al.

Summary: Photocatalytic overall water splitting is a promising technology for hydrogen production, but its current performance is insufficient for large-scale production. This paper provides a theoretical and practical analysis of the challenges associated with photocatalytic overall water splitting, including unfavorable thermodynamics, slow kinetics, dissolved oxygen, and rapid backward reaction.

CHEM (2022)

添加到收藏夹

Article Energy & Fuels

BiOBr/NiO S-Scheme Heterojunction Photocatalyst for CO2 Photoreduction

Zhongliao Wang et al.

Summary: The study demonstrates enhanced CO2 photoreduction activity through an S-scheme BiOBr/NiO heterojunction, showcasing improved understanding of the mechanism through integration of in situ monitoring techniques with density functional theory calculation.

SOLAR RRL (2022)

添加到收藏夹

Article Chemistry, Applied

Organic amine surface modified one-dimensional CdSe0.8S0.2-diethylenetriamine/two-dimensional SnNb2O6 S-scheme heterojunction with promoted visible-light-driven photocatalytic CO2 reduction

Hui Yang et al.

Summary: Achieving both strong redox ability and high visible-light absorption ability in a single semiconductor material is challenging. Designing a heterojunction between two semiconductor materials provides a feasible solution. In this study, a CdSe0.8S0.2-DETA/SnNb2O6 heterostructure material with improved CO production rate was prepared. The results demonstrate the significance of optimizing the band structure to promote the separation of photogenerated carriers and enhance the efficiency of CO2 reduction.

CHINESE JOURNAL OF CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Applied

Efficient photocatalytic hydrogen evolution over graphdiyne boosted with a cobalt sulfide formed S-scheme heterojunction

Zhiliang Jin et al.

Summary: Graphdiyne (GDY), a novel two-dimensional carbon hybrid material, has attracted significant attention due to its unique and excellent properties. This study reports new progress in the preparation of a composite material, Co9S8-GDY-CuI, using CuI powder as a catalytic material and a facile hydrothermal method. The Co9S8-GDY-CuI exhibited hydrogen production activity 10.29 times higher than that of pure GDY in the sensitization system. Characterization techniques provided evidence for the successful preparation of the material and its superior photocatalytic activity. A possible reaction mechanism and the effects of Co9S8 nanoparticles were also discussed.

CHINESE JOURNAL OF CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Applied

1D/2D TiO2/ZnIn2S4 S-scheme heterojunction photocatalyst for efficient hydrogen evolution

Jinmao Li et al.

Summary: A novel 1D/2D TiO2/ZnIn2S4 heterostructure was designed to address the limitations of TiO2 photocatalyst and achieved significant improvement in photocatalytic hydrogen evolution.

CHINESE JOURNAL OF CATALYSIS (2022)

添加到收藏夹

Article Chemistry, Physical

Dynamics of Photogenerated Charge Carriers in Inorganic/Organic S-Scheme Heterojunctions

Linxi Wang et al.

Summary: The study investigated the behavior of photogenerated charge carriers within step-scheme heterojunction, revealing efficient charge separation mechanism. The charge-discharge property of polydopamine may result in electron backflow, which is not suitable for practical photocatalytic applications.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2022)

添加到收藏夹

Article Engineering, Environmental

The type-II n-n inorganic/organic nano-heterojunction of Ti3+ self-doped TiO2 nanorods and conjugated co-polymers for photoelectrochemical water splitting and photocatalytic dye degradation

Nani Gopal Ghosh et al.

Summary: This article reports the synthesis of two organic semiconductors coupled with Ti3+ self-doped TiO2 nanorods to create type-II n-n inorganic/organic nano-heterostructures. These nano-heterostructures not only enhance visible-light absorption but also improve the delocalization and transportation of photogenerated carriers due to advantageous band alignments. The organic semiconductors exhibit better photoelectrochemical performances than Ti3+/TiO2 NRs, with TP1 NHs showing the highest photocatalytic efficiency.

CHEMICAL ENGINEERING JOURNAL (2021)

添加到收藏夹

Article Engineering, Environmental

S-scheme heterojunction based on p-type ZnMn2O4 and n-type ZnO with improved photocatalytic CO2 reduction activity

Hongzhao Deng et al.

Summary: Hierarchical ZnMn2O4/ZnO nanofibers were prepared as photocatalysts, outperforming pristine ZnO nanofibers by showing a about 4-fold increment in CO and CH4 yields. The enhanced charge separation efficiency and the realization of S-scheme charge transfer were demonstrated in the composite, providing new insights into the design of S-scheme photocatalysts composed of p-type and n-type semiconductors.

CHEMICAL ENGINEERING JOURNAL (2021)

添加到收藏夹

Article Chemistry, Physical

Efficient interfacial charge transfer of 2D/2D porous carbon nitride/bismuth oxychloride step-scheme heterojunction for boosted solar-driven CO2 reduction

Yao Huo et al.

Summary: Heterostructured photocatalysts, such as the step-scheme porous g-C3N4/Bi12O17Cl2 (PGCN/BOC) nanocomposite, show enhanced photocatalytic performance by promoting interfacial charge migration and shortening the diffusion path of charge carriers. This work provides new insights into constructing novel heterojunctions for photocatalytic CO2 reduction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

添加到收藏夹

Article Energy & Fuels

Construction of an Ultrathin S-Scheme Heterojunction Based on Few-Layer g-C3N4 and Monolayer Ti3C2Tx MXene for Photocatalytic CO2 Reduction

Yali Yang et al.

Summary: The ultrathin S-scheme heterojunction g-C3N4/TiO2/C was constructed using electrostatic self-assembly and calcination method, showing excellent photocatalytic CO2 reduction performance due to large contact area and strong interaction between the compositions. The results confirm the importance of interface contact for efficient charge carrier transfer in photocatalytic processes.

SOLAR RRL (2021)

添加到收藏夹

Article Chemistry, Physical

Construction of S-scheme 0D/2D heterostructures for enhanced visible-light-driven CO2 reduction

Shuaiqi Gong et al.

Summary: The study describes the fabrication of a step-scheme (S-scheme) 0D/2D hetero-structure with InVO4 QDs and g-C3N4 (CN) ultrathin nanosheets for photocatalytic CO2 reduction, achieving a highly selective reduction of CO2 to CO with good photocatalytic performance. The formation of this heterostructure facilitates the separation of electron-hole pairs and reduces the recombination of charge carriers, contributing to efficient photocatalysis.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

rGO modified R-CeO2/g-C3N4 multi-interface contact S-scheme photocatalyst for efficient CO2 photoreduction

Xin Li et al.

Summary: Constructing a 2D-1D-2D sandwich photocatalyst by loading R-CeO2 and rGO on the g-C3N4 surface significantly enhances the CO2 photocatalytic reduction activity, with increased yields of CO and CH4. Photoelectrochemical tests demonstrate that the introduction of rGO can enhance the transmission and separation of photogenerated electrons, as well as improve CO2 adsorption capacity, while ensuring good stability of the composite material.

APPLIED SURFACE SCIENCE (2021)

添加到收藏夹

Review Chemistry, Physical

Near-Infrared-Responsive Photocatalysts

Yi Yang et al.

Summary: Expanding light absorption to the near-infrared region is crucial in photocatalysis; NIR-responsive photocatalysts can utilize diffuse solar energy; This study summarizes recent progress and different photocatalytic systems.

SMALL METHODS (2021)

添加到收藏夹

Article Energy & Fuels

Integrated S-Scheme Heterojunction of Amine-Functionalized 1D CdSe Nanorods Anchoring on Ultrathin 2D SnNb2O6 Nanosheets for Robust Solar-Driven CO2 Conversion

Xiaochun Ke et al.

Summary: A novel S-scheme SnNb2O6/CdSe-diethylenetriamine heterojunction was designed and showed enhanced activity in the solar-driven photocatalytic conversion of CO2 to CO, attributed to the synergy between CdSe-diethylenetriamine nanorods and SNO nanosheets in the S-scheme system.

SOLAR RRL (2021)

添加到收藏夹

Article Chemistry, Physical

Amine-Modified S-Scheme Porous g-C3N4/CdSe-Diethylenetriamine Composite with Enhanced Photocatalytic CO2 Reduction Activity

Yao Huo et al.

Summary: Amine modification and the formation of the S-scheme heterojunction optimize the photocatalytic CO2 reduction performance of A-PCN/CdSe-DETA composite, achieving a remarkable CO production rate of 25.87 mu mol/(h g) under visible-light irradiation without the need for a sacrificial agent. This work sheds light on the functionalization of S-scheme photocatalysts using amine functional groups, opening up vast opportunities for applications beyond photocatalysis.

ACS APPLIED ENERGY MATERIALS (2021)

添加到收藏夹

Article Chemistry, Physical

Graphene-Modulated PDI/g-C3N4 All-Organic S-Scheme Heterojunction Photocatalysts for Efficient CO2 Reduction under Full-Spectrum Irradiation

Rui Sun et al.

Summary: This study successfully constructed efficient S-scheme heterojunction photocatalyst PDI/G-CN for converting CO2 into CO and CH4, with a 16-time performance improvement compared to natural CN nanosheets. Through interface modulation, effective S-scheme charge transfer and separation are enhanced, and the optimized amount of highly dispersed PDI is increased, demonstrating the potential practicality of all-organic CN-based S-scheme photocatalysts for efficient solar-to-energy conversion via CO2 reduction.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Fully Conjugated 3D Covalent Organic Framework Exhibiting Band-like Transport with Ultrahigh Electron Mobility

Shitao Wang et al.

Summary: A fully conjugated 3D COF with high electron mobility was synthesized, demonstrating a band-like transport mechanism different from common organic materials. The findings suggest that fully conjugated 3D COFs could provide new pathways for electron delocalization and charge transport, potentially revolutionizing the design of organic semiconducting materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Hierarchically Porous ZnO/g-C3N4S-Scheme Heterojunction Photocatalyst for Efficient H2O2 Production

Bowen Liu et al.

Summary: Hierarchically porous ZnO/g-C3N4 S-scheme heterojunction photocatalysts were prepared with ZIF-8 and urea as precursors, showing high activity in photocatalytic H2O2 production. The mechanism of charge transfer and separation within the S-scheme heterojunction was studied using Kelvin probe, in situ irradiated X-ray photoelectron spectroscopy (ISI-XPS), and electron paramagnetic resonance (EPR).

LANGMUIR (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

An Inorganic/Organic S-Scheme Heterojunction H2-Production Photocatalyst and its Charge Transfer Mechanism

Chang Cheng et al.

Summary: This study introduces a strategy for preparing high-efficiency photocatalysts by growing inorganic semiconductors on organic semiconductors, leading to the successful synthesis of an S-scheme heterojunction photocatalyst. Through optimization, the composite material exhibits high hydrogen evolution rate and quantum efficiency.

ADVANCED MATERIALS (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Step-scheme heterojunction photocatalysts for solar energy, water splitting, CO2 conversion, and bacterial inactivation: a review

Vasudha Hasija et al.

Summary: The article discusses the mechanism and advantages of S-scheme photocatalysts in improving the efficiency of photoelectric conversion by introducing the separation and recombination of photogenerated electron-hole pairs, as well as relevant experimental and theoretical research methods. The S-scheme heterojunctions show promise for achieving highly efficient photocatalysis by optimizing factors such as co-catalyst loading, bandgap tuning, and interfacial optimization.

ENVIRONMENTAL CHEMISTRY LETTERS (2021)

添加到收藏夹

Article Chemistry, Physical

Developments in stability and passivation strategies for black phosphorus

Haizeng Song et al.

Summary: Black phosphorus has attracted attention for its advantageous characteristics, but its high chemical activity and rapid degradation under ambient conditions have limited its applications. Passivation techniques have helped alleviate these issues, allowing for excellent performance in various devices. Passivated black phosphorus not only shows good stability under ambient conditions, but also exhibits better performance compared to the original material, contributing to its potential applications.

NANO RESEARCH (2021)

添加到收藏夹

Review Energy & Fuels

S-Scheme Photocatalytic Systems

Yujie Bao et al.

Summary: The development history, advantages, applications, challenges and outlook of S-scheme photocatalysts have been summarized and discussed in this article, providing insights for utilizing their potential in renewable energy generation and environmental remediation.

SOLAR RRL (2021)

添加到收藏夹

Article Nanoscience & Nanotechnology

Surface Basicity of Metal@TiO2 to Enhance Photocatalytic Efficiency for CO2 Reduction

Lei Jin et al.

Summary: Photocatalytic reduction of CO2 to valuable chemical fuels is of broad interest due to its potential to activate greenhouse gases using renewable energy input. The choice of metal cocatalysts and surface basicity of TiO2 can enhance the photocatalytic efficiency for CO2 photoreduction, with different metals showing varying activity and selectivity for CO and hydrocarbon production. The improvement of electron density and low proton affinity of metal cocatalysts play a key role in CO2 photoreduction.

ACS APPLIED MATERIALS & INTERFACES (2021)

添加到收藏夹

Article Chemistry, Physical

TiO2/polydopamine S-scheme heterojunction photocatalyst with enhanced CO2-reduction selectivity

Aiyun Meng et al.

Summary: This study fabricated polydopamine-modified TiO2 hollow spheres and investigated their effect on the photocatalytic CO2 reduction activities. The results showed that the PDA wrapping significantly enhanced the photocatalytic activity and methane selectivity, leading to improved yields.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Physical

In situ self-assembled S-scheme BiOBr/pCN hybrid with enhanced photocatalytic activity for organic pollutant degradation and CO2 reduction

Tao zhang et al.

Summary: Researchers have developed a unique S-scheme heterostructure by immobilizing hollow hierarchical BiOBr microspheres onto protonated g-C3N4, resulting in enhanced photocatalytic activity for degradation of RhB and reduction of CO2. The introduction of pCN improved the adsorption capability and transformed RhB and CO2 molecules, while enhancing the separation of photogenerated charge carriers. The hybrid catalyst showed significantly improved activity under visible-light irradiation, with the 10% pCN/BiOBr hybrid demonstrating the best performance for RhB degradation and CO2 reduction.

APPLIED SURFACE SCIENCE (2021)

添加到收藏夹

Article Engineering, Environmental

Recent advances on Bismuth-based Photocatalysts: Strategies and mechanisms

Li Zhang et al.

Summary: This review summarizes the methods and strategies for modifying Bi-based photocatalysts, including defect regulation, exposed facet control, etc. It focuses on the application and reaction mechanisms of BiOCl photocatalysts.

CHEMICAL ENGINEERING JOURNAL (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

In situ Irradiated XPS Investigation on S-Scheme TiO2@ZnIn2S4 Photocatalyst for Efficient Photocatalytic CO2 Reduction

Libo Wang et al.

Summary: Efficient hierarchical photocatalysts, such as the S-scheme core-shell TiO2@ZnIn2S4 heterojunction, have gained attention for photocatalytic CO2 reduction. The improved performance is attributed to the inhibited recombination of photogenerated charge carriers induced by the S-scheme heterojunction, as well as the large specific surface areas and abundant active sites. In situ irradiated X-ray photoelectron spectroscopy, work function calculation, and electron paramagnetic resonance measurements confirm the S-scheme photogenerated charge transfer mechanism.

SMALL (2021)

添加到收藏夹

Review Chemistry, Physical

A general review on the thiospinels and their energy applications

F. Ozel et al.

Summary: Material science plays a crucial role in engineering versatile compounds for various technological applications. Thiospinels have attracted great interest due to their unique characteristics and potential utilizations, making them an essential class of material. This work summarizes broadband studies on thiospinels for the first time, covering synthesis methods, properties, and applications, and highlights future research needs and challenges.

MATERIALS TODAY ENERGY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Recent advances in bismuth oxyhalide photocatalysts for degradation of organic pollutants in wastewater

Yang Li et al.

Summary: This review provides an overview of controllable synthesis, doping, surface modification, and heterojunction formation of BiOX-based photocatalysts, as well as future research trends. The main purpose is to provide practical guidelines for developing high-performance BiOX photocatalysts.

RSC ADVANCES (2021)

添加到收藏夹

Article Nanoscience & Nanotechnology

DFT Study on Regulating the Electronic Structure and CO2 Reduction Reaction in BiOBr/Sulphur-Doped G-C3N4 S-Scheme Heterojunctions

Xingang Fei et al.

Summary: In this study, the effect of S doping on S-scheme heterojunctions composed of BiOBr and g-C3N4 for CO2 reduction was thoroughly investigated using DFT calculations. The results showed that S doping can improve photocatalytic activity and enhance visible light absorption, leading to the preferential production of CH3OH over CH4. The study suggests that S doping is predicted to be an efficient photocatalyst for reducing CO2 into CH3OH.

FRONTIERS IN NANOTECHNOLOGY (2021)

添加到收藏夹

Article Chemistry, Physical

2D/2D Black Phosphorus/g-C3N4 S-Scheme Heterojunction Photocatalysts for CO2 Reduction Investigated using DFT Calculations

Xingang Fei et al.

Summary: The hybridization of different photocatalysts, such as BP and g-C3N4, has been shown to enhance the photocatalytic efficiency for CO2 reduction. Theoretical calculations indicate that electrons transfer from g-C3N4 to BP due to the built-in electric field at the interface, leading to efficient separation of photogenerated charge carriers. The S-scheme heterojunction between BP and g-C3N4 allows for the optimized reduction of CO2, making the BP/g-C3N4 composite a promising CO2 reduction photocatalyst.

ACTA PHYSICO-CHIMICA SINICA (2021)

添加到收藏夹

Review Chemistry, Physical

Recent Advances in Surface-Modified g-C3N4-Based Photocatalysts for H2 Production and CO2 Reduction

Yunfeng Li et al.

Summary: Solar energy is the largest renewable energy source in the world, and photocatalysis technology plays an important role in solving water resource issues and reducing CO2 emissions. Surface modification of g-C3N4 photocatalysts can significantly improve their performance.

ACTA PHYSICO-CHIMICA SINICA (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Enhanced solar-to-chemical energy conversion of graphitic carbon nitride by two-dimensional cocatalysts

Chuanbiao Bie et al.

Summary: This paper introduces the current research status of g-C3N4 in photocatalysis strengthened by 2D cocatalysts, highlighting the advantages of 2D/2D heterojunctions and their application in STC energy conversion. The future development and challenges are also discussed.

ENERGYCHEM (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Recent advances in g-C3N4 composites within four types of heterojunctions for photocatalytic CO2 reduction

Meidan Que et al.

Summary: In recent years, studies on the photocatalytic conversion of CO2 into hydrocarbon fuels have been booming as a promising solution to alleviate global warming and energy issues. Researchers are focusing on developing g-C3N4 composite photocatalysts with excellent performance and stability. Different types of heterojunctions of g-C3N4 composites are widely adopted, aiming to understand the photocatalytic mechanisms and characteristics for future development.

NANOSCALE (2021)

添加到收藏夹

Article Chemistry, Physical

Photocatalytic reduction of CO2 using Pt/C3N4 photocatalyts

Kamila Koci et al.

APPLIED SURFACE SCIENCE (2020)

添加到收藏夹

Article Engineering, Environmental

How g-C3N4 Works and Is Different from TiO2 as an Environmental Photocatalyst: Mechanistic View

Jonghun Lim et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

添加到收藏夹

Article Materials Science, Multidisciplinary

Step-scheme CdS/TiO2 nanocomposite hollow microsphere with enhanced photocatalytic CO2 reduction activity

Zhongliao Wang et al.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2020)

添加到收藏夹

Article Chemistry, Physical

Enhancement of Alkyne Semi-Hydrogenation Selectivity by Electronic Modification of Platinum

Zhenshu Wang et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Physical

Photocatalytic CO2 Reduction to C2+Products

Josep Albero et al.

ACS CATALYSIS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Xenes as an Emerging 2D Monoelemental Family: Fundamental Electrochemistry and Energy Applications

Tingting Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

S-Scheme Heterojunction Photocatalyst

Quanlong Xu et al.

CHEM (2020)

添加到收藏夹

Article Chemistry, Physical

2D/2D/0D TiO2/C3N4/Ti3C2 MXene composite S-scheme photocatalyst with enhanced CO2 reduction activity

Fei He et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

添加到收藏夹

Article Materials Science, Multidisciplinary

S-scheme photocatalyst Bi2O3/TiO2 nanofiber with improved photocatalytic performance

Rongan He et al.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2020)

添加到收藏夹

Article Multidisciplinary Sciences

Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction

Feiyan Xu et al.

NATURE COMMUNICATIONS (2020)

添加到收藏夹

Review Energy & Fuels

Effectiveness of modified CO2 injection at improving oil recovery and CO2 storage-Review and simulations

Saira et al.

ENERGY REPORTS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Industrial carbon dioxide capture and utilization: state of the art and future challenges

Wanlin Gao et al.

CHEMICAL SOCIETY REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Matching and adjusting energy band structures of Pd-modified sulphides (ZnS, In2S3 and CuS) and improving the photocatalytic activity of CO2 photoreduction

Hanbo Li et al.

NANOSCALE (2020)

添加到收藏夹

Article Chemistry, Applied

Bifunctional S-scheme g-C3N4/Bi/BiVO4 hybrid photocatalysts toward artificial carbon cycling

Quan Xie et al.

CHINESE JOURNAL OF CATALYSIS (2020)

添加到收藏夹

Review Environmental Sciences

Carbon dioxide storage through mineral carbonation

Sandra O. Snaebjornsdottir et al.

NATURE REVIEWS EARTH & ENVIRONMENT (2020)

添加到收藏夹

Article Multidisciplinary Sciences

Selective electroreduction of carbon dioxide to methanol on copper selenide nanocatalysts

Dexin Yang et al.

NATURE COMMUNICATIONS (2019)

添加到收藏夹

Article Chemistry, Physical

Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst

Junwei Fu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

添加到收藏夹

Article Chemistry, Physical

CO2 Hydrogenation to Methanol over ZrO2-Containing Catalysts: Insights into ZrO2 Induced Synergy

Kongzhai Li et al.

ACS CATALYSIS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

State-of-the-art progress in the use of ternary metal oxides as photoelectrode materials for water splitting and organic synthesis

Huichao He et al.

NANO TODAY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficient Electrosynthesis of Syngas with Tunable CO/H2 Ratios over ZnxCd1-xS-Amine Inorganic-Organic Hybrids

Nannan Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Applied

Charge carrier trapping, recombination and transfer during TiO2 photocatalysis: An overview

Ruifeng Qian et al.

CATALYSIS TODAY (2019)

添加到收藏夹

Article Chemistry, Physical

Photocatalytic Reduction of CO2 to CH3OH Coupling with the Oxidation of Amine to Imine

Tian Yang et al.

CATALYSIS LETTERS (2018)

添加到收藏夹

Article Chemistry, Physical

Exploring Indium-Based Ternary Thiospinel as Conceivable High-Potential Air-Cathode for Rechargeable Zn-Air Batteries

Gengtao Fu et al.

ADVANCED ENERGY MATERIALS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enabling Visible-Light-Driven Selective CO2 Reduction by Doping Quantum Dots: Trapping Electrons and Suppressing H-2 Evolution

Jin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Article Chemistry, Physical

TiO2 complexed with dopamine-derived polymers and the visible light photocatalytic activities for water pollutants

Sujeong Kim et al.

JOURNAL OF CATALYSIS (2017)

添加到收藏夹

Review Physics, Applied

Recent developments in complex metal oxide photoelectrodes

Fatwa F. Abdi et al.

JOURNAL OF PHYSICS D-APPLIED PHYSICS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals

Moritz F. Kuehnel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Isolation of Cu Atoms in Pd Lattice: Forming Highly Selective Sites for Photocatalytic Conversion of CO2 to CH4

Ran Long et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Materials Science, Multidisciplinary

Enhanced photo catalytic performance of nickel doped bismuth selenide under visible light irradiation

Chiranjit Kulsi et al.

MATERIALS RESEARCH EXPRESS (2017)

添加到收藏夹

Article Chemistry, Physical

Enhanced selective photocatalytic CO2 reduction into CO over Ag/CdS nanocomposites under visible light

Zezhou Zhu et al.

APPLIED SURFACE SCIENCE (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

CO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts

Xiaoxia Chang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

添加到收藏夹

Article Geosciences, Multidisciplinary

Anthropogenic carbon release rate unprecedented during the past 66 million years

Richard E. Zeebe et al.

NATURE GEOSCIENCE (2016)

添加到收藏夹

Article Chemistry, Physical

A new understanding of the photocatalytic mechanism of the direct Z-scheme g-C3N4/TiO2 heterostructure

Jianjun Liu et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bismuth oxyhalides: synthesis, structure and photoelectrochemical activity

Davinder S. Bhachu et al.

CHEMICAL SCIENCE (2016)

添加到收藏夹

Article Nanoscience & Nanotechnology

Tunable Photoinduced Carrier Transport of a Black Phosphorus Transistor with Extended Stability Using a Light-Sensitized Encapsulated Layer

Po-Hsun Ho et al.

ACS PHOTONICS (2016)

添加到收藏夹

Review Nanoscience & Nanotechnology

Carbon Quantum Dots and Applications in Photocatalytic Energy Conversion

K. A. Shiral Fernando et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Polymeric Photocatalysts Based on Graphitic Carbon Nitride

Shaowen Cao et al.

ADVANCED MATERIALS (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels

Jinli Qiao et al.

CHEMICAL SOCIETY REVIEWS (2014)

添加到收藏夹

Review Chemistry, Multidisciplinary

Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes

Evgenii V. Kondratenko et al.

ENERGY & ENVIRONMENTAL SCIENCE (2013)

添加到收藏夹

Article Chemistry, Physical

Enhanced photocatalytic performance of direct Z-scheme g-C3N4-TiO2 photocatalysts for the decomposition of formaldehyde in air

Jiaguo Yu et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

添加到收藏夹

Article Materials Science, Multidisciplinary

Unoccupied electronic band structure of the semi-metallic Bi(111) surface probed with two-photon photoemission

Christopher Bronner et al.

PHYSICAL REVIEW B (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Nano-photocatalytic Materials: Possibilities and Challenges

Hua Tong et al.

ADVANCED MATERIALS (2012)

添加到收藏夹

Article Multidisciplinary Sciences

The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts

Malte Behrens et al.

SCIENCE (2012)

添加到收藏夹

Review Plant Sciences

Improving yield potential in crops under elevated CO2: integrating the photosynthetic and nitrogen utilization efficiencies

Surya Kant et al.

FRONTIERS IN PLANT SCIENCE (2012)

添加到收藏夹

Article Engineering, Chemical

Recent developments on carbon capture and storage: An overview

J. C. M. Pires et al.

CHEMICAL ENGINEERING RESEARCH & DESIGN (2011)

添加到收藏夹

Article Chemistry, Physical

Covalent Organic Frameworks with High Charge Carrier Mobility

Shun Wan et al.

CHEMISTRY OF MATERIALS (2011)

添加到收藏夹

Review Chemistry, Multidisciplinary

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources

Sunho Choi et al.

CHEMSUSCHEM (2009)

添加到收藏夹

Article Chemistry, Physical

The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation

Yasuyoshi Sasaki et al.

JOURNAL OF CATALYSIS (2008)

添加到收藏夹

Article Physics, Multidisciplinary

Transition-metal-substituted indium thiospinels as novel intermediate-band materials:: Prediction and understanding of their electronic properties

P. Palacios et al.

PHYSICAL REVIEW LETTERS (2008)

添加到收藏夹

Article Nanoscience & Nanotechnology

Tuning the energy bandgap of CdSe nanocrystals via Mg doping

Woo-Chul Kwak et al.

NANOTECHNOLOGY (2007)

添加到收藏夹

Article Chemistry, Physical

All-solid-state Z-scheme in CdS-Au-TiO2 three-component nanojunction system

Hiroaki Tada et al.

NATURE MATERIALS (2006)

添加到收藏夹

Article Multidisciplinary Sciences

Photoelectrochemical cells

M Grätzel

NATURE (2001)

添加到收藏夹

Article Chemistry, Physical

A new type of water splitting system composed of two different TiO2 photocatalysts (anatase, rutile) and a IO3-/I- shuttle redox mediator

R Abe et al.

CHEMICAL PHYSICS LETTERS (2001)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.