期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 4, 期 7, 页码 1543-1549出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5tc04002g
关键词
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资金
- National Natural Science Foundation of China [21571142]
- Developing Science Fund of Tongji University
A novel highly fluorescent hybrid (Eu3+/CDs@MOF-253) has been synthesized based on metal-organic frameworks (MOFs) by encapsulating optical active carbon dots (CDs) and Eu3+. The as-prepared fluorescent-functionalized MOFs not only maintained the excellent optical properties of CDs and Eu3+ to give dual-emission but also have good stability in an aqueous solution. It was further used as a novel fluorescent probe for detecting Hg2+. The relative fluorescence intensity ratio (I-Eu/I-CD) increased linearly with increasing Hg2+ concentration in the 0.065-150 mu M range with a 13 ppb detection limit. The possible mechanism is discussed. This study represents a new approach for the fabrication of ratiometric and colorimetric Hg2+ fluorescent sensors, as it highlights the opportunity of existing MOFs encapsulated CDs and Eu3+ sensitizing, simultaneously. In addition, removal of Hg2+ from a solution can also be achieved by the fluorescent MOF hybrids.
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