期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 4, 期 37, 页码 8787-8794出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6tc02917e
关键词
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资金
- National Natural Science Foundation of China [51273108, 51673113]
- National Basic Research Program of China (973 Program) [2013CB834803]
- National Natural Science Foundation of China (NSFC) [51373029, 61421002, 51533005]
- Preeminent Youth Fund of Sichuan Province [2015JQ0006]
- Fundamental Research Funds for the Central Universities [ZYGX2015J048]
Typical pi-pi stacking is suppressed by the asymmetric molecular design for high fluorescence quantum yield (Phi(f)) blue light emission, overcoming the aggregation caused quenching (ACQ) limitation. In this research, two novel blue fluorescent materials with asymmetric structure: 2-(4'-((4-(9H-carbazol-9-yl)-phenyl)sulfonyl)- [1,1'-biphenyl]-4-yl)-1-(4-(tert-butyl)phenyl)-1H-phenanthro [9,10-cnimidazole (PSC) and 2-(4'-((4'-(9H-carbazol-9-yl)-[1,1'-biphenyl]-4-yl)sulfonyl)-[1,1'-biphenyl]-4-yl)-1-(4-(tert-butyl)phenyl)-1H-phenanthro[9,10-d]imidazole (PSBC), consisting of a sulfone group as the electron acceptor and two different electron donors, carbazole and phenanthroimidazole, were designed and synthesized. The two compounds have high Phi(f) (95.3% for PSC and 81.1% for PSBC) in film because of the restricting pi-pi stacking, and. show apparent mechanochromic properties, i.e., an emission change from deep blue to blue-green resulting from external mechanical stimuli. The emissions display 50 nm/23 nm red shifts after grinding. Organic light emitting diodes (OLEDs) using the two compounds as emitters exhibited good efficiencies: the doped PSC-based device emitted blue light at 444 nm with CIE co-ordinates of (0.151, 0.072). The PSBC-based device also emitted blue light at 444 nm with CIE co-ordinates of (0.151, 0.068). A maximal external quantum efficiency (EQE) of 5.43% was also achieved.
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