4.6 Article

A novel method for the synthesis of 1,2-benzisoxazoline-3-one and its application to hypochlorite recognition

期刊

JOURNAL OF MATERIALS CHEMISTRY B
卷 4, 期 30, 页码 5101-5104

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6tb01392a

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资金

  1. National Natural Science Foundation of China [21472118]
  2. Taiyuan Technology star special [12024703]
  3. Program for the Top Young and Middle-aged Innovative Talents of Higher Learning Institutions of Shanxi [2013802]
  4. Talents Support Program of Shanxi Province [2014401]
  5. Shanxi Province Outstanding Youth Fund [2014021002]
  6. National Science Foundation [CHE-1507119]
  7. National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) - Korean government (MSIP) [2012R1A3A2048814]
  8. Division Of Chemistry [1507119] Funding Source: National Science Foundation

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The reaction of salicylhydroxamic acid with hypochlorite produces 1,2-benzisoxazoline-3-one, a heterocycle that contains a fluorophore. As a result, this reaction was used as the basis for a new, selective and sensitive fluorescence system for the recognition of hypochlorite. The effectiveness of the method was demonstrated by its use to detect hypochlorite in a disinfectant solution as well as to image hypochlorite in cells.

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