期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 4, 期 29, 页码 11342-11350出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta03518c
关键词
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资金
- National Basic Research Program of China [2014CB932103]
- National Natural Science Foundation of China [51272020, 21236003, U1407118]
- Research fund for the Doctoral Program of Higher Education of China [20120010110013]
- Beijing Engineering Center for Hierarchical catalysts
- Fundamental Research Funds for the Central Universities [YS1406]
Unique hollow hybrid structures composed of well-dispersed catalyst nanoparticles embedded in a carbon matrix offer great advantages for constructing advanced supported catalysts. Herein, we report the designed synthesis of Co9S8 and nitrogen doped hollow carbon sphere (Co9S8/NHCS) composites by carbonization of metanilic anions within the confinement of two-dimensional galleries of hollow spherical cobalt-aluminum layered double hydroxides. The Co9S8/NHCS composites are composed of numerous porous carbon nanoflakes, and monodisperse Co9S8 nanoparticles are embedded within the carbon nanoflakes. Electrochemical measurements show that the Co9S8/NHCS catalysts prepared at 900 degrees C exhibit superior oxygen reduction reaction (ORR) activity, resulting in the highest ORR performance to date among all transition metal sulfide-based ORR catalysts in both alkaline and acidic electrolytes. This interlayer confined reaction approach may provide an efficient platform for the synthesis of other functional materials for alternative applications.
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