4.6 Article

N-doped WS2 nanosheets: a high-performance electrocatalyst for the hydrogen evolution reaction

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 4, 期 29, 页码 11234-11238

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta04082a

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资金

  1. National Basic Research Program of China [2012CB933101]
  2. National Natural Science Foundation of China [11474137, 51301081, 11274146]
  3. Fundamental Research Funds for the Central Universities [lzujbky-2014-27, lzujbky-2016-130]

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Non-Pt-based catalysts are urgently required to produce abundant hydrogen in electrochemical water splitting, in order to make the hydrogen evolution reaction (HER) feasible and energy efficient. Here, N-doped WS2 nanosheets were synthesized by a one step sol-gel process, which are electrochemically active toward the HER with a low onset potential of 86 mV, a large cathodic current density (100 mA cm(-2) at an overpotential of 197 mV) and long-term durability. We anticipate that this synthetic method will be a powerful tool for creating high-performance electrocatalysts from other transition metal dichalcogenides.

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