期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 4, 期 44, 页码 17560-17571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta07400f
关键词
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资金
- Basic Research Laboratory Program [2014R1A4A1008140]
- Nano-Material Technology Development Program [2016M3A7B4900117]
- Leading Human Resource Training Program of Regional Neo Industry through National Research Foundation (NRF) - Ministry of Science, ICT & Future Planning of Republic of Korea [2016H1D5A1909049]
A novel strategy for the synthesis of high-quality ternary cobalt copper sulfide nanoparticles (NPs) anchored on nitrogen doped graphene nanosheets (Co2CuS4/NG) was developed via a one-pot solvothermal method. FE-SEM and TEM images showed that the Co2CuS4 NPs with an average size of similar to 21 nm were anchored to NG nanosheets. The NG nanosheets provide a large surface area to reduce self-aggregation and confine the shape of the Co2CuS4 NPs for a highly conductive network to boost the charge transport properties of energy storage devices. Impressively, the synergetic Co2CuS4/NG composite showed a high specific capacitance of similar to 1005 F g(-1) at 1 A g(-1), excellent rate capability (770 F g(-1) at 50 A g(-1)), and outstanding stability (96.3% capacitance retention after 5000 cycles). The electrochemical performance of the Co2CuS4/NG composite was superior to that of monometallic CoS/NG, Cu2S/NG composite, pure Co2CuS4, and NG. An asymmetric supercapacitor device fabricated using the Co2CuS4/NG composite as the positive electrode material and NG as the negative electrode material illustrates the outstanding performance for practical energy storage devices. The asymmetric supercapacitor device delivers superb energy density (53.3 W h k g(-1)), high power density (similar to 10 936 W k g(-1) at 38.4 W h k g(-1)), and a long-cycle life (similar to 4000 times).
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