4.6 Article

Binding TiO2-B nanosheets with N-doped carbon enables highly durable anodes for lithium-ion batteries

期刊

JOURNAL OF MATERIALS CHEMISTRY A
卷 4, 期 21, 页码 8172-8179

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta01955b

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资金

  1. National High-tech R&D Program of China (863 Program) [2015AA034601]
  2. National Natural Science Foundation of China [51522205, 51472098, 21271078]
  3. Program for New Century Excellent Talents in University [NECT-12-0223]

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An effective strategy of binding TiO2-B nanosheets with N-doped carbon is developed to construct highly stable TiO2-B (001)vertical bar carbon interfaces with enhanced electronic conductivity and Li-uptake capability. The interfaces provide not only additional interfacial lithium-storage capability but also highly conductive pathways for the fast transport of electrons and lithium ions. The hybrid as an anode for lithium-ion batteries exhibits a safe operating potential window of similar to 1.5 V, superior rate capability with 180 mA h g(-1) at 6 A g(-1), and ultra-long cycle life of more than 2000 cycles, holding great promise for safe and high-power energy storage applications.

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