期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 4, 期 7, 页码 2590-2596出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ta10258h
关键词
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资金
- National Natural Science Foundation of China [21273004]
- Research Fund for the Doctoral Program of Higher Education of China [20113250110007]
- State Key Laboratory of Heavy Oil Processing
- Priority Academic Program Development of Jiangsu Higher Education Institutions
We present a proof-of-concept demonstration of surface cavities for incorporation of noble metal nanoparticles with remarkable catalytic performance involved in liquid phase catalytic reactions. Mesoporous Ni(OH)(2) (m-Ni(OH)(2)) nanowires with surface cavities have been chosen as multifunctional supports for Au nanoparticles with a well controlled size (2 nm) and high dispersity through a facile room-temperature in situ reduction process without any additional stabilizer. In addition to immobilizing Au nanoparticles, the cavities also can prevent aggregation of neighboring noble metal nanoparticles, thus ensuring high stability/recyclability for Au/m-Ni(OH)(2) supported nanocatalysts. The results from catalytic reactions involved in the reduction of 4-nitrophenol in the presence of NaBH4 using Au/m-Ni(OH)(2) as the catalyst demonstrated its remarkable catalytic performance due to its nanoscale configuration.
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