Facile construction of lignin-based network composite hydrogel for efficient adsorption of methylene blue from wastewater

Adsorption method is an effective approach to treat wastewater containing methylene blue. Herein, a costeffective and eco-friendly lignin-based network composite hydrogel adsorbent (PAA@SML) was constructed by using polyacrylic acid (PAA) to crosslink with sulfomethylated lignin (SML) via free radical polymerization for adsorption of methylene blue (MB) from wastewater. The constructed PAA@SML-0.2 exhibited remarkable adsorption performance towards removal of MB, with a maximum theoretical adsorption capacity of 777.1 mg & BULL;g � 1. The improved efficiency can be attributed to the well-established network structure and abundant hydrophilic functional groups present in the adsorbent, promoting the interaction between methylene blue (MB) molecules and the adsorption sites of the adsorbent. The adsorption process of the adsorbent for MB followed the pseudo-second-order kinetic and the Langmuir isotherm models, which illustrated the adsorption process attributed to monolayer chemisorption. Mechanism investigation confirmed that the adsorption of MB by PAA@SML-0.2 primarily relied on hydrogen bonding and electrostatic interactions. Moreover, the recyclability test demonstrated excellent regeneration usability and stability of PAA@SML-0.2, and the adsorption capacity maintained above 74.0 % after five cycles. This constructed lignin-based network composite hydrogel is considered to have great potential in the treatment of organic dye in wastewater.

Automated summary

A cost-effective and eco-friendly lignin-based network composite hydrogel adsorbent was successfully constructed for the adsorption of methylene blue from wastewater. The adsorbent exhibited remarkable adsorption performance, with a maximum theoretical adsorption capacity of 777.1 mg/g. The adsorption process followed pseudo-second-order kinetic and Langmuir isotherm models. Mechanism investigation revealed that hydrogen bonding and electrostatic interactions played a crucial role in the adsorption process. The adsorbent also showed excellent regeneration usability and stability after multiple cycles.