4.6 Review

Recent advances in MXenes: a future of nanotechnologies

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Summary: A low-temperature salt-assisted chemical vapor deposition method was used to grow single-domain Bi2O2Se on a millimeter scale with multilayer to monolayer thickness. The layer-dependent Raman spectroscopy of Bi2O2Se was systematically investigated, showing a redshift of the A(1g) mode at 162.4 cm(-1). The environmental stability of approximately 2.4 nm thick Bi2O2Se was confirmed after exposure to air for 1.5 years. The backgated field effect transistor based on a few-layered Bi2O2Se exhibited decent carrier mobility (approximately 287 cm(2) V(-1)s(-1)) and an ON/OFF ratio of up to 10(7), indicating a technique for growing large-domain thickness controlled Bi2O2Se single crystals for electronics.
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Interlayer Injection of Low-Valence Zn Atoms to Activate MXene-Based Micro-Redox Capacitors With Battery-Type Voltage Plateaus

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Summary: This study presents a novel strategy to overcome the energy output limitation of micro-supercapacitors (MSCs) by anchoring low-valence Zn atoms onto MXene flakes. By combining a hydrogel electrolyte rich in Cl- and Zn2+ ions, the redox couples between symmetrical electrodes are activated, leading to a battery-type voltage plateau and enhanced energy density. The results show substantially improved power output stability compared to conventional MSCs.

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Highly efficient, remarkable sensor activity and energy storage properties of MXenes and borophene nanomaterials

Chuan Li et al.

Summary: Sensors, integrated with AI, 5G, ML, and IoTs, are crucial for sustainable development and are widely used in various sectors. The combination of 2D nanomaterials with these technologies has revolutionized sensor applications in different fields. The development of 2D NMs, such as MXenes and borophene, has greatly advanced the construction of novel sensors and ESDs.

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Recent Progress in Emerging Novel MXenes Based Materials and their Fascinating Sensing Applications

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Summary: MXenes are a novel and extensive class of 2D materials family, which consist of early transition metals based 2D carbides, nitrides and carbonitrides nanomaterials. MXenes possess distinctive surface chemistry, graphene like shape, metallic conductivity, high hydrophilicity, outstanding mechanical and thermal properties, redox capacity and are affordable with mass-produced nature, making them of tremendous scientific and technological significance.
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Optically Reconfigurable Complementary Logic Gates Enabled by Bipolar Photoresponse in Gallium Selenide Memtransistor

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Borophene-based mixed-dimensional van der waals heterojunctions for high-performance self-powered photodetector

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Facile Fabrication of Highly Oriented Dense Ti3C2 Fibers with Enhanced Strength and Supercapacitance Performance by Coagulation Condition Tuning

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Valence-switchable and biocatalytic vanadium-based MXene nanoplatform with photothermal-enhanced dual enzyme-like activities for anti-infective therapy

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Recent Advances in Oxidation Stable Chemistry of 2D MXenes

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Holdups in Nitride MXene's Development and Limitations in Advancing the Field of MXene

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Recent advance in MXenes: New horizons in electrocatalysis and environmental remediation technologies

Karim Khan et al.

Summary: MXenes nanomaterials have gained significant attention as cutting-edge materials with strong electrocatalytic activity in a variety of industrial applications. This article reviews the latest progress in the synthesis, properties, and potential applications of MXenes as electrocatalysts for reactions such as HER, OER, overall water splitting, ORR, N2RR, and CO2RR. The article also discusses approaches for enhancing the electrocatalytic activity of MXenes and highlights the current obstacles and future suggestions for their use as electrocatalysts.

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Room and low-temperature magnetic characterization of Cr doped CoFe2O4 nanostructures

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Summary: In this study, the magnetic properties of Co ferrite were significantly improved by Cr substitution. The results showed that Cr substitution had a significant impact on the lattice contraction and magnetic properties of Co ferrite. In addition, the study of low-temperature magnetic properties provided insights into the temperature-dependent behavior of the magnetic properties.

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Infrared Light Emission Devices Based on Two-Dimensional Materials

Wenyi Li et al.

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Enhanced and Passivated Co-doping Effect of Organic Molecule and Bromine on Graphene/HfO2/Silicon Metal-Insulator-Semiconductor (MIS) Schottky Junction Solar Cells

Kalyani D. Kadam et al.

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Multi-enzyme activity nanozymes for biosensing and disease treatment

Li Su et al.

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Recent major advances and challenges in the emerging graphene-based nanomaterials in electrocatalytic fuel cell technology

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Article Chemistry, Multidisciplinary

van der Waals integration of mixed-dimensional CeO2@Bi heterostructure for high-performance self-powered photodetector with fast response speed

Xinlin Liu et al.

Summary: In this research, a mixed-dimensional van der Waals heterostructure (vdWH) CeO2@Bi was synthesized through a facile hydrothermal method. The resulting photodetector showed self-powered photodetection capability with fast photoresponse speed and high photocurrent and photoresponsivity under 365 nm illumination. Additionally, good long-term cycle stability was observed in a harsh environment.

NANOSCALE (2022)

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Recent advances in novel graphene: new horizons in renewable energy storage technologies

Ayesha Khan Tareen et al.

Summary: This study provides an overview of the research and development of high-performance batteries and supercapacitors based on graphene nanomaterials for next-generation and smart electronics. Firstly, graphene-based rechargeable batteries with high energy density, longer life, improved safety, and shape-diversity capabilities are discussed. Secondly, graphene-based supercapacitors, which outperform traditional batteries in terms of power density and cyclability, are explored. Finally, the prospects and issues of graphene-based electrodes for energy storage devices are briefly reviewed.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

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Novel Porphyrin-Perylene diimide for ultrafast high-performance resistive memory devices

Qudrat Ullah Khan et al.

Summary: A novel solution-processable porphyrin-perylene diimide compound was synthesized and evaluated for its optical and electrochemical properties. The compound showed good solubility in organic solvents, making it suitable for thin-film formation and electronic device applications. Testing of the memory device indicated excellent memory behavior and stability.

ORGANIC ELECTRONICS (2022)

Review Chemistry, Multidisciplinary

Sensing Applications of Atomically Thin Group IV Carbon Siblings Xenes: Progress, Challenges, and Prospects

Karim Khan et al.

Summary: The discovery of 2D graphene nanosheets is a revolutionary event in materials science, leading to the study of novel 2D materials like Xenes. These atomically thin materials offer potential sensing applications and exhibit a range of electronic structures, from insulators to semiconductors to semimetals. Various synthesis methods, properties, and potential applications of 2D Xenes are briefly discussed in this review.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Inorganic & Nuclear

Confinement in two-dimensional materials: Major advances and challenges in the emerging renewable energy conversion and other applications

Ayesha Khan Tareen et al.

Summary: The study emphasizes the importance of energy production with low-carbon emission and introduces the concept of using nonprecious metals catalysts in 2D materials to replace rare precious metal catalysts. The NPMCs 2DMs show higher efficiency, selectivity, and sustainability in oxygen reduction, oxygen/hydrogen evolution reactions.

PROGRESS IN SOLID STATE CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Highly Electroconductive and Mechanically Strong Ti3C2Tx MXene Fibers Using a Deformable MXene Gel

Hwansoo Shin et al.

Summary: MXene nanosheets self-assembled into hydrogels can be spun into highly aligned fibers with increased electrical conductivity and Young's modulus. These oriented MXene fibers are expected to have widespread applications in electrical wiring and signal transmission.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

In-Situ Electrochemically Activated Surface Vanadium Valence in V2C MXene to Achieve High Capacity and Superior Rate Performance for Zn-Ion Batteries

Ying Liu et al.

Summary: This study presents the use of V2C MXene as a potential cathode material for high energy density ZIBs with superior rate capability. By activating the V2CTx cathode, the surface vanadium valence is significantly increased, forming a nanoscale vanadium oxide coating that undergoes multi-electron reactions effectively. The activated V2CTx demonstrates an ultrahigh rate performance and excellent stability, providing insights into the design of high-performance cathode materials for advanced ZIBs.

ADVANCED FUNCTIONAL MATERIALS (2021)

Review Chemistry, Multidisciplinary

MXenes for Rechargeable Batteries Beyond the Lithium-Ion

Fangwang Ming et al.

Summary: MXenes have shown great potential as electrode materials in next-generation batteries, with their unique properties and versatile applications. Researchers have proposed various comprehensive utilization methods and also provided a perspective on future research directions for MXenes and MXene-based materials.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Solution-Processed Ti3C2Tx MXene Antennas for Radio-Frequency Communication

Meikang Han et al.

Summary: This study presents the application of MXene material in RF communication, including low-energy attenuation transmission lines and high-power radiation antennas. MXene material shows excellent performance in patch antennas, with high radiation efficiency, smaller thickness, and weight compared to traditional copper antennas.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Achieving High-Performance 3D K+-Pre-intercalated Ti3C2Tx MXene for Potassium-Ion Hybrid Capacitors via Regulating Electrolyte Solvation Structure

Shuoqing Zhao et al.

Summary: A three-dimensional K+-pre-intercalated Ti3C2Tx MXene was constructed for efficient electrochemical potassium-ion storage, and the optimized solvation structure of the concentrated ether-based electrolyte led to the formation of a thin and inorganic-rich solid electrolyte interphase on the electrode, showing promising electrochemical performances. These results highlight the significant roles of rational structure design and electrolyte optimization for highly reactive MXene-based anode materials in energy storage devices.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Novel W-based in-plane chemically ordered (W2/3R1/3)2AlC (R = Gd, Tb, Dy, Ho, Er, Tm and Lu) MAX phases and their 2D W1.33C MXene derivatives

Jiaxin Yang et al.

Summary: Novel rare-earth-contained W-based in-plane chemically ordered i-MAX phases were reported for the first time, with the magnetic ground state found to change depending on the rare-earth element used. By preparing a composite MXene, the specific capacitance performance was significantly enhanced.

CARBON (2021)

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Mixed-dimensional niobium disulfide-graphene foam heterostructures as an efficient catalyst for hydrogen production

Sehrish Aslam et al.

Summary: The developed mixed-dimensional heterostructures of niobium disulfide (NbS2) with graphene foam grown on nickel foam (NbS2-Gr-NF) exhibit exceptionally high current density and fast reaction kinetics in alkaline electrolytes, making them a potential candidate for water-splitting applications.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Materials Science, Multidisciplinary

The Broad Chromatic Range of Two-Dimensional Transition Metal Carbides

Kathleen Maleski et al.

Summary: Transition metal carbides and nitrides (MXenes) are a relatively new class of 2D materials with diverse optical properties, showing changes in carrier concentration and chemical composition. The study introduces the optical properties of nine carbide MXenes, which vary systematically in composition and atomic structure, and suggests the potential for this class of optoelectronic building blocks.

ADVANCED OPTICAL MATERIALS (2021)

Article Green & Sustainable Science & Technology

Hydrogen Evolution Reaction for Vacancy-Ordered i-MXenes and the Impact of Proton Absorption into the Vacancies

Hans Lind et al.

Summary: The study investigates the hydrogen evolution reaction (HER) for Mo-, W-, and Nb-based MXenes, focusing on the W1.33C MXene with ordered vacancies. It is found that under high cathodic potentials, the HER activity and onset potential of W1.33C MXene are significantly enhanced, with potential for thermoneutral values of hydrogen adsorption in vacancies. This enhancement is attributed to protons transferring to vacancies and remaining in a metastable state as hydrogen atoms.

ADVANCED SUSTAINABLE SYSTEMS (2021)

Article Chemistry, Multidisciplinary

Selective Etching Quaternary MAX Phase toward Single Atom Copper Immobilized MXene (Ti3C2Clx) for Efficient CO2 Electroreduction to Methanol

Qi Zhao et al.

Summary: An efficient method for producing single atom copper immobilized MXene for catalyzing CO2 reduction to methanol through selective etching of hybrid A layers in quaternary MAX phases was demonstrated. The single atom Cu catalyst exhibited high Faradaic efficiency and good electrocatalytic stability, attributed to its unique electronic structure and surface functional groups.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

High Concentration of Ti3C2Tx MXene in Organic Solvent

Qingxiao Zhang et al.

Summary: MXenes are widely studied as two-dimensional materials due to their properties, but dispersing MXene materials in organic solvents poses a significant challenge. The tuned microenvironment method (TMM) has been developed to prepare highly concentrated Ti3C2Tx organic solvent dispersion efficiently. The method allows for clean, uniform, and large-size Ti3C2Tx nanosheets to be dispersed in organic solvents with excellent oxidation resistance.

ACS NANO (2021)

Article Chemistry, Physical

Enhancing the low-temperature performance in lithium ion batteries of Nb2O5 by combination of W doping and MXene addition

Yao Chen et al.

Summary: The W-doped Nb2O5/MXene composites show significantly improved electrochemical performance at low temperature, with high reversible capacity, excellent rate capability, and good cycling stability, making them promising candidates for the negative electrode in lithium ion batteries to address safety concerns in cold climates.

JOURNAL OF POWER SOURCES (2021)

Article Materials Science, Ceramics

Improvement of gas sensing property for two-dimensional Ti3C2Tx treated with oxygen plasma by microwave energy excitation

Ming Hou et al.

Summary: Ti3C2Tx activated at 500 degrees C exhibited excellent gas-sensing properties at room temperature to 100 ppm ethanol with a value of 22.47, attributed to the enhancement of the amount of oxygen functional groups and defects on the MXene Ti3C2Tx film. The enhancement of ethanol-sensing performance demonstrated that the activated Ti3C2Tx possess great potential in gas sensing.

CERAMICS INTERNATIONAL (2021)

Article Chemistry, Inorganic & Nuclear

A first principle study: Effect of tin substitution on magnetic properties of bismuth ferrite nanoparticles prepared by sol-gel synthesis method

Maryam Kiani et al.

Summary: This study successfully synthesized Sn substituted BiFeO3 nanocomposite using an improved sol-gel method, where structural and morphological analyses showed a transition in crystal structure and particle size reduction with the addition of Sn. Dielectric analyses indicated a decrease in dielectric properties with increasing frequency, while magnetic properties exhibited a ferromagnetic trend with enhanced magnetization due to Sn content. Both theoretical and experimental results suggested the potential enhancement of magnetization in the prepared samples through Sn content, making the resulting hard magnetic nanomaterials significant for data storage devices.

INORGANIC CHEMISTRY COMMUNICATIONS (2021)

Article Materials Science, Multidisciplinary

Nonlinear optical properties and ultrafast photonics of 2D BP/Ti3C2 heterostructures

Xuefeng Xia et al.

Summary: In this study, a 2D black phosphorous (BP)/MXene (Ti3C2) heterostructure was successfully prepared by stacking BP and Ti3C2 using van der Waals forces, demonstrating its excellent stability in water and air, as well as its potential as an optical switch. Nonlinear properties were also shown through Z-scan measurements, indicating high modulation depth and small saturation intensity. The performance of the BP/Ti3C2 heterostructure as a saturable absorber in an Er-doped mode-locked fiber laser was demonstrated, achieving a 735 fs pulse duration at a center wavelength of 1559.8 nm, along with harmonic mode-locking at a peak repetition rate of 588 MHz. These results suggest significant potential applications of 2D BP/Ti3C2 heterostructures in ultrafast photonics.

OPTICAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

Broadband Nonlinear Photonics in Few-Layer Borophene

Chunyang Ma et al.

Summary: Borophene is synthesized through liquid-phase exfoliation, demonstrating excellent saturable absorber properties and broad applications as an optical switch in near- and mid-infrared laser systems. Stable ultrashort pulses are achieved at different wavelengths, showing significant potential for extending the frontiers of photonic technologies with borophene.
Article Chemistry, Physical

Stretchable Zn-Ion Hybrid Battery with Reconfigurable V2CTx and Ti3C2Tx MXene Electrodes as a Magnetically Actuated Soft Robot

Yang Li et al.

Summary: Stretchable Zn-ion hybrid batteries were developed using MXene cathodes and anodes for wearable electronics. The battery features large deformability, low weight, and ultralow self-discharge rate, demonstrating rechargeable and strain-insensitive specific capacities. The stretchable battery was further used to power a magnetically actuated soft robot for charging/discharging tasks.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Assembly of Nanofluidic MXene Fibers with Enhanced Ionic Transport and Capacitive Charge Storage by Flake Orientation

Shuo Li et al.

Summary: MXenes are highly conductive 2D materials with electrochemical storage features, and oriented Ti3C2Tx fibers exhibit excellent volumetric capacitive charge storage capability and mechanical strength. The wet spinning process can improve the electronic conductivity and morphology of the fibers, making them ideal for applications in electrochemical energy storage, biosensors, and potentially biocompatible fibrillar tissues.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Sulfonic-Group-Grafted Ti3C2Tx MXene: A Silver Bullet to Settle the Instability of Polyaniline toward High-Performance Zn-Ion Batteries

Ying Liu et al.

Summary: The research focuses on enhancing the performance of PANI cathode material in Zn-ion batteries using surface-engineered Ti3C2Tx MXene, which provides protons and maintains a low pH to suppress the instability of PANI, and improves performance through fast redox reactions and buffering of swelling/shrinking.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti3C2 MXene

Tyler S. Mathis et al.

Summary: By including excess aluminum during the synthesis of the Ti3AlC2 MAX phase precursor, improved Al-Ti3C2 nanosheets with enhanced crystallinity and carbon stoichiometry are produced, leading to higher resistance to oxidation and increased electronic conductivity. The shelf life of aqueous suspensions of stoichiometric single-to few-layer Al-Ti3C2 flakes made from the modified precursor is extended to over ten months, compared to 1 to 2 weeks for previously published Ti3C2. Additionally, the improved Al-Ti3C2 exhibits oxidation initiation at temperatures 100-150 degrees C higher than conventional Ti3C2, demonstrating potential for widespread use of this material.

ACS NANO (2021)

Review Chemistry, Multidisciplinary

MXenes-A New Class of Two-Dimensional Materials: Structure, Properties and Potential Applications

Maksym Pogorielov et al.

Summary: MXenes, a new class of two-dimensional nanomaterials composed of carbides/nitrides/carbonitrides of transition and refractory metals, have attracted attention for their exceptional properties. Since the synthesis of the first family member in 2011, research related to MXenes has been rapidly increasing. Studies have shown widespread applications of MXenes in various fields, with significant implications in the medical field.

NANOMATERIALS (2021)

Article Chemistry, Multidisciplinary

Biodegradable and Excretable 2D W1.33C i-MXene with Vacancy Ordering for Theory-Oriented Cancer Nanotheranostics in Near-Infrared Biowindow

Bangguo Zhou et al.

Summary: MXenes are a new class of 2D nanomaterials showing great potential in biological applications. This study explores a unique W1.33C i-MXene with multiple theranostic functionalities, fast biodegradation, and satisfactory biocompatibility. The constructed ultrathin W1.33C nanosheets exhibit excellent photothermal-conversion effectiveness and fast degradation in normal tissues, showcasing potential for tailored biomedical applications.

ADVANCED SCIENCE (2021)

Article Chemistry, Physical

Nanoscale CuTe electrocatalyst immobilized at conductor surface for remarkable hydrogen

Qudrat Ullah Khan et al.

Summary: This study successfully demonstrated a copper tellurides nano-structures based electrocatalyst with high activity and remarkable stability for efficient hydrogen generation. The catalyst showed comparable performance to platinum-based electrocatalysts in water splitting, along with good kinetic behavior and stability.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Physical

Direct methane activation by atomically thin platinum nanolayers on two-dimensional metal carbides

Zhe Li et al.

Summary: The study demonstrates that atomically thin Pt nanolayers supported on MXene can efficiently catalyze the conversion of methane to ethane/ethylene, operating for 72 hours at high temperatures with >98% selectivity, providing important insights into designing highly active and stable catalysts.

NATURE CATALYSIS (2021)

Article Chemistry, Physical

Architecting Amorphous Vanadium Oxide/MXene Nanohybrid via Tunable Anodic Oxidation for High-Performance Sodium-Ion Batteries

Wang Zhang et al.

Summary: The study presents a nanohybrid architecture of amorphous vanadium oxide conformally coated on layered V2C MXene, demonstrating high reversible capacity, decent rate capability, and good cycling stability for sodium-ion batteries. The nanohybrid enables reversible and fast Na+ insertion/extraction, while providing abundant electron/ion transfer channels to boost electrochemical performance. The structural superiority and improved reversibility of the nanohybrid are clearly revealed by various in situ techniques, showcasing its potential for advanced rechargeable batteries.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Toward a Practical Zn Powder Anode: Ti3C2Tx MXene as a Lattice-Match Electrons/Ions Redistributor

Xinliang Li et al.

Summary: The study focuses on utilizing Ti(3)C(2)Tx MXene as a redistributor for zinc powder anodes, constructing a stable and highly reversible zinc powder anode to address dendrite growth and polarization issues, improving the cycle life and rate capability of zinc-based full batteries.

ACS NANO (2021)

Article Chemistry, Multidisciplinary

Development of Fluorine-Free Tantalum Carbide MXene Hybrid Structure as a Biocompatible Material for Supercapacitor Electrodes

Alireza Rafieerad et al.

Summary: Innovative synthesis of Ta4C3Tx MXene-tantalum oxide (TTO) hybrid structure was demonstrated, showing potential for TTO composite as an efficient biocompatible material for supercapacitor electrodes. The TTO electrode exhibited long-term stability and high energy-storage performance, outperforming previous biomaterial-based supercapacitors.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Multidisciplinary

High-Entropy Atomic Layers of Transition-Metal Carbides (MXenes)

Zhiguo Du et al.

Summary: By selectively etching a novel high-entropy MAX phase, high-entropy transition-metal carbides (HE-MXene) can be synthesized, exhibiting stable structures and distinct lattice distortions that efficiently guide dendrite-free lithium nucleation and growth on HE-MXene. This approach achieves long cycling stability of up to 1200 hours and good deep stripping-plating levels of up to 20 mAh cm(-2).

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Ten Years of Progress in the Synthesis and Development of MXenes

Michael Naguib et al.

Summary: Since their discovery in 2011, the number of 2D transition metal carbides and nitrides (MXenes) has steadily increased to over 40 compositions, potentially becoming the largest family of 2D materials. MXenes exhibit unique properties such as high electrical conductivity, which make them useful in various applications like energy storage and optoelectronics. The production of MXenes using methods like selective etching has led to rapid growth in research publications and patents, indicating promising commercialization potential.

ADVANCED MATERIALS (2021)

Review Chemistry, Multidisciplinary

Advances in the Synthesis of 2D MXenes

Yi Wei et al.

Summary: MXenes, versatile materials with adjustable structures and rich surface chemistry, have been recognized as potential 2D materials for various applications. Recent research has focused on synthetic routes, etching methods, and delamination strategies for large-scale preparation and stable storage. Antioxidation strategies for MXenes have also been summarized for future developments and practical applications.

ADVANCED MATERIALS (2021)

Article Chemistry, Physical

Anchoring single atom cobalt on two-dimensional MXene for activation of peroxymonosulfate

Haoran Song et al.

Summary: A simple and general vacancy defects anchoring strategy was developed for the synthesis of single atom metals, which exhibited excellent performance for peroxymonosulfate activation. The single atom Co catalyst not only showed outstanding performance in PMS activation, but also performed well even under alkaline conditions or in actual river water.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

Article Environmental Sciences

Kinetics, isotherm and chemical speciation analysis of Hg(II) adsorption over oxygen-containing MXene adsorbent

Xiaolan Hu et al.

Summary: The study found that the two-dimensional MXene showed good adsorption performance for heavy metal mercury ions in wastewater treatment, especially under low pH conditions. It also maintained a high adsorption capacity at high temperatures and different pH values.

CHEMOSPHERE (2021)

Article Materials Science, Multidisciplinary

Synthesis and characterization of Cr2C MXenes

Otitoaleke Akinola et al.

Summary: This study developed a method for synthesizing Cr2C from Cr2AlC MAX phase, optimizing etching using sodium fluoride and hydrogen chloride, and using a minimally intensive layer delamination method in a cold environment. Additionally, sonication and washing methods were optimized for intercalation and delamination, resulting in a characterized crystal structure of Cr2C.

JOURNAL OF MATERIALS RESEARCH (2021)

Article Materials Science, Multidisciplinary

The Ti3SiC2 max phases as promising materials for high temperature applications: Formation under various synthesis conditions

S. N. Perevislov et al.

Summary: A new method for synthesis of Ti3SiC2 MAX phases was proposed, achieving a purity of 99.2% and demonstrating high mechanical properties and radiation resistance. The Ti/SiC/TiC powder mixture proved to be the most suitable for synthesizing Ti3SiC2, with a relative density of 99.4%.

MATERIALS CHEMISTRY AND PHYSICS (2021)

Review Chemistry, Multidisciplinary

Novel emerging graphdiyne based two dimensional materials: Synthesis, properties and renewable energy applications

Karim Khan et al.

Summary: Graphdiyne (GDY), a novel two-dimensional carbon allotrope with unique structure and properties, has attracted increasing attention for its wide range of potential applications. Efforts have been made to develop various forms of GDY materials, but challenges remain in fully understanding growth methods, fabricating single crystal GDY films, and achieving practical applications.

NANO TODAY (2021)

Article Physics, Condensed Matter

Structural, electronic, optical and thermoelectric analysis of perovskites XRuO3 (X=Ca, Sr)

Muhammad Saeed et al.

Summary: This study applied first principles calculations to investigate the structural, electronic, optical, and thermoelectric properties of perovskites (CaRuO3 and SrRuO3). The results suggest that these semiconductor materials have potential applications in optics and thermoelectrics. The calculated thermoelectric properties show promising results for the potential use of CaRuO3 and SrRuO3 in thermoelectric applications.

PHYSICA B-CONDENSED MATTER (2021)

Review Chemistry, Inorganic & Nuclear

Navigating recent advances in monoelemental materials (Xenes)-fundamental to biomedical applications

Karim Khan et al.

Summary: The emerging two-dimensional materials Xenes have shown potential in various technological fields and fundamental science, showcasing outstanding properties for biomedical applications. This review categorizes and summarizes the properties of 2D-Xenes, highlighting their synthetic methods and biomedical applications in the end.

PROGRESS IN SOLID STATE CHEMISTRY (2021)

Editorial Material Materials Science, Ceramics

A decade of discovery: A review of MXenes, the family of 2D transition metal carbides and nitrides

Yury Gogotsi

AMERICAN CERAMIC SOCIETY BULLETIN (2021)

Article Engineering, Electrical & Electronic

Graphene foam-polymer based electronic skin for flexible tactile sensor

Xiaolan Tang et al.

Summary: The impact of static and dynamic pressure on graphene foam-polymer composites was investigated, with dynamic pressure showing higher sensitivity and quicker recovery time compared to static pressure. The sensitivity of the dynamic pressure sensor was found to be almost double that of the static pressure sensor.

SENSORS AND ACTUATORS A-PHYSICAL (2021)

Review Chemistry, Multidisciplinary

Advanced Devices for Tumor Diagnosis and Therapy

Lude Wang et al.

Summary: Current tumor diagnosis and therapy methods are slow, costly, and face difficulties in diagnosing tumors at their early stage. Efforts are focused on non-destructive, integrated, and multiple technologies for early and accurate diagnosis and personalized treatment. The development of advanced devices and smart technology is seen as the key to achieve these objectives.
Article Chemistry, Physical

Metal Ion-Induced Assembly of MXene Aerogels via Biomimetic Microtextures for Electromagnetic Interference Shielding, Capacitive Deionization, and Microsupercapacitors

Meng Ding et al.

Summary: The crumple-textured Ti3C2Tx MXene platform inspired by Phrynosoma cornutum's hierarchical scale textures enables the formation of large-area Mg2+-MXene aerogels without the need for polymeric binders. These highly conductive aerogels have diverse applications ranging from macroscale technologies such as electromagnetic interference shielding and capacitive deionization to on-chip electronics like quasi-solid-state microsupercapacitors with superior power density and energy density.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Physical

2D amorphous-MoO3_ x@Ti3C2-MXene non-van der Waals heterostructures as anode materials for lithium-ion batteries

Pengfei Yan et al.

Summary: The study found that a non-vdW heterostructure can strongly stabilize aMoO3_x while maintaining high electrical conductivity, optimizing lithium-ion storage kinetics and achieving high-performance energy storage materials. This work opens up a promising platform for boosting and understanding lithium-ion storage performance.

NANO ENERGY (2021)

Article Chemistry, Physical

Porous MXene monoliths with locally laminated structure for enhanced pseudo-capacitance and fast sodium-ion storage

Juan Zhao et al.

Summary: This study presents the fabrication of porous MXene monoliths with locally laminated structure through alkali-assisted self-assembly, which enhances the capacity and rate performance for sodium-ion storage. The balance of laminated and porous structures in MXene monoliths is crucial for providing sufficient storage sites and ion transport pathways simultaneously.

NANO ENERGY (2021)

Review Chemistry, Multidisciplinary

Application of MXenes in Perovskite Solar Cells: A Short Review

Syed Afaq Ali Shah et al.

Summary: The application of MXene materials in perovskite solar cells has attracted significant attention due to their outstanding properties. This article reviews the progress made in using Ti3C2Tx MXene materials in various components of PSCs and discusses the opportunities and challenges in incorporating MXene materials for improved performance and stability.

NANOMATERIALS (2021)

Article Chemistry, Multidisciplinary

Interlayer Structure Engineering of MXene-Based Capacitor-Type Electrode for Hybrid Micro-Supercapacitor toward Battery-Level Energy Density

Wenxiang Cheng et al.

Summary: By inserting 1D core-shell conductive BC@PPy nanofibers between MXene nanosheets, the interlayer structure engineering effectively enhances ion and electron transport within the MXene structure, significantly increasing the areal capacitance of the electrode and achieving a battery-level energy density in the ZHMSCs.

ADVANCED SCIENCE (2021)

Article Materials Science, Multidisciplinary

Ultrafast photonics applications of zirconium carbide as a novel mode-locker for fiber lasers

Sicong Liu et al.

Summary: This study deposited a ZrC film on a fiber using MSD technology to demonstrate its nonlinear optical properties, and implemented passive mode-locking in an EDFL by inserting the ZrC SA. The experiment achieved ultrashort and high-power pulse outputs, showcasing the potential applications of ZrC in lasers and photonics.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

Review Materials Science, Biomaterials

Recent development in graphdiyne and its derivative materials for novel biomedical applications

Karim Khan et al.

Summary: Graphdiyne (GDY) and its derivatives, with exceptional physical and chemical properties, have great potential for various applications in the biomedical field, such as biosensing, cancer therapy, and antibacterial agents, showing excellent biocompatibility and bio-safety.

JOURNAL OF MATERIALS CHEMISTRY B (2021)

Review Materials Science, Multidisciplinary

Application of two-dimensional materials in perovskite solar cells: recent progress, challenges, and prospective solutions

Syed Ossama Ali Ahmad et al.

Summary: Over the past decade, perovskite solar cells have attracted significant interest due to their high performance and cost-effective processing. Despite advancements in power conversion efficiencies, challenges such as stability and scaling remain. Recent exploration of 2D layered materials aims to address these challenges and enhance the potential applications of perovskite solar cells.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

Review Chemistry, Physical

The role of nitrogen in transition-metal nitrides in electrochemical water splitting

Rabia Jamil et al.

Summary: The study investigates the importance of transition-metal-based nitrides in catalyzing water splitting, focusing on active site engineering and the development of oxygen evolution reaction catalysts. Strategies for converting unifunctional TMNs to bifunctional catalysts are also discussed to achieve overall water splitting.

CHEM CATALYSIS (2021)

Article Materials Science, Multidisciplinary

High Breakdown Current Density in Monolayer Nb4C3Tx MXene

Alexey Lipatov et al.

Summary: The study found that Nb4C3Tx, a member of the MXene family, has a very high breakdown current density, comparable to that of Ti3C2Tx and highly conductive two-dimensional materials like graphene, making it promising for high current-carrying applications.

ACS MATERIALS LETTERS (2021)

Review Chemistry, Multidisciplinary

Novel synthesis, properties and applications of emerging group VA two-dimensional monoelemental materials (2D-Xenes)

Karim Khan et al.

Summary: The article introduces a sub-group of atomically thin 2D materials, Xenes, focusing on the 2D-Xenes of group V elements such as phosphorene, arsenene, antimonene, and bismuthene, and their potential applications as semiconductor-like materials in optoelectronic, biomedical, and sensing devices.

MATERIALS CHEMISTRY FRONTIERS (2021)

Article Chemistry, Multidisciplinary

A novel MnO-CrN nanocomposite based non-enzymatic hydrogen peroxide sensor

Ayesha Khan Tareen et al.

Summary: A MnO-CrN composite was synthesized via ammonolysis of nitride precursors and exhibited excellent electrochemical sensing performance towards H2O2, with a wide linear response range, low detection limit, and short response time.

RSC ADVANCES (2021)

Review Multidisciplinary Sciences

The world of two-dimensional carbides and nitrides (MXenes)

Armin Vahid Mohammadi et al.

Summary: MXenes, a family of two-dimensional materials, have diverse properties and wide-ranging applications in areas such as optics, catalysis, sensing, and medicine. Future research directions will focus on deepening the fundamental understanding of MXenes properties and exploring their potential for hybridization with other 2D materials.

SCIENCE (2021)

Article Chemistry, Multidisciplinary

High-throughput computational discovery of ternary-layered MAX phases and prediction of their exfoliation for formation of 2D MXenes

Rasoul Khaledialidusti et al.

Summary: The study aims to expand the MAX phase family, through systematic research on 1122 candidate materials, it is found that 466 MAX compounds can be synthesized, among which 136 can form MXenes.

NANOSCALE (2021)

Article Chemistry, Physical

Stretchable Ti3C2Tx MXene microsupercapacitors with high areal capacitance and quasi-solid-state multivalent neutral electrolyte

Shuo Li et al.

Summary: A two-step contraction process was developed to fabricate MXene SMSCs with high specific capacitance. The e-MXene SMSC with acidic gel electrolyte showed superior energy density and high rate performance, while ensuring user safety.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

Evolution of low-dimensional material-based field-effect transistors

Waqas Ahmad et al.

Summary: This review discusses the significance and development of field-effect transistors (FETs) in the electronics industry, emphasizing the role of low-dimensional materials in FETs and proposing potential solutions to current issues. It provides guidance for the future development of high-performance FETs based on low-dimensional materials.

NANOSCALE (2021)

Article Chemistry, Multidisciplinary

Improved synthesis of Ti3C2Tx MXenes resulting in exceptional electrical conductivity, high synthesis yield, and enhanced capacitance

Ali Shayesteh Zeraati et al.

Summary: The EN-MILD synthesis approach has successfully produced high quality MXene sheets with exceptional electrical conductivity, high yield of delaminated single layers, and high colloidal concentrations, significantly expanding the applications of MXenes.

NANOSCALE (2021)

Article Chemistry, Multidisciplinary

Activating the I0/I+ redox couple in an aqueous I2-Zn battery to achieve a high voltage plateau

Xinliang Li et al.

Summary: This study demonstrates the activation of reversible redox behavior in iodine conversion batteries through electrolyte adjustment, achieving significant performance enhancements.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Recent progress, challenges, and prospects in emerging group-VIA Xenes: synthesis, properties and novel applications

Ayesha Khan Tareen et al.

Summary: The discovery of graphene has led to the study of other novel two-dimensional materials, with Xenes being a particularly active area of research due to their potential for future nanodevices with high speed, low cost, and efficiency. Both theoretically predicted and experimentally synthesized Xene materials show promise for application in upcoming nanodevices, despite being in the early stages of investigation and device application.

NANOSCALE (2021)

Article Chemistry, Multidisciplinary

Perpendicular MXene Arrays with Periodic Interspaces toward Dendrite-Free Lithium Metal Anodes with High-Rate Capabilities

Zhenjiang Cao et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

Pristine Titanium Carbide MXene Films with Environmentally Stable Conductivity and Superior Mechanical Strength

Hongwu Chen et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

Ultrasound-Driven Two-Dimensional Ti3C2Tx MXene Hydrogel Generator

Kang Hyuck Lee et al.

ACS NANO (2020)

Article Materials Science, Multidisciplinary

Scalable Synthesis of Ti3C2Tx MXene

Christopher E. Shuck et al.

ADVANCED ENGINEERING MATERIALS (2020)

Article Chemistry, Multidisciplinary

MXene Composite and Coaxial Fibers with High Stretchability and Conductivity for Wearable Strain Sensing Textiles

Shayan Seyedin et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

How Much Oxygen Can a MXene Surface Take Before It Breaks?

Ingemar Persson et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Materials Science, Ceramics

Fabrication of a fibrous MnO2@MXene/CNT electrode for high-performance flexible supercapacitor

Qiang Liu et al.

CERAMICS INTERNATIONAL (2020)

Article Engineering, Environmental

MXene-decorated SnS2/Sn3S4 hybrid as anode material for high-rate lithium-ion batteries

Junfeng Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

Article Materials Science, Ceramics

Synthesis and formation mechanism of high-purity Ti3AlC2 powders by microwave sintering

Weihua Chen et al.

INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY (2020)

Article Environmental Sciences

Adsorption of Ba2+ and Sr2+ on Ti3C2Tx MXene in model fracking wastewater

Byung-Moon Jun et al.

JOURNAL OF ENVIRONMENTAL MANAGEMENT (2020)

Article Materials Science, Multidisciplinary

3D knitted energy storage textiles using MXene-coated yarns

Ariana Levitt et al.

MATERIALS TODAY (2020)

Review Physics, Multidisciplinary

Two-dimensional MXenes: From morphological to optical, electric, and magnetic properties and applications

Xiantao Jiang et al.

PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS (2020)

Article Chemistry, Multidisciplinary

Mechanical Exfoliation of Select MAX Phases and Mo4Ce4Al7C3 Single Crystals to Produce MAXenes

Athanasios Gkountaras et al.

Article Multidisciplinary Sciences

Realization of 2D crystalline metal nitrides via selective atomic substitution

Jun Cao et al.

SCIENCE ADVANCES (2020)

Article Chemistry, Multidisciplinary

Beyond Ti3C2Tx: MXenes for Electromagnetic Interference Shielding

Meikang Han et al.

ACS NANO (2020)

Article Chemistry, Multidisciplinary

i-MXenes for Energy Storage and Catalysis

Bilal Ahmed et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

2D Titanium Carbide (Ti3C2Tx) in Accommodating Intraocular Lens Design

Emma J. Ward et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Multidisciplinary

A 2D Titanium Carbide MXene Flexible Electrode for High-Efficiency Light-Emitting Diodes

Soyeong Ahn et al.

ADVANCED MATERIALS (2020)

Article Chemistry, Multidisciplinary

Scalable Manufacturing of Free-Standing, Strong Ti3C2Tx MXene Films with Outstanding Conductivity

Jizhen Zhang et al.

ADVANCED MATERIALS (2020)

Article Nanoscience & Nanotechnology

Dendritic Nanostructured Waste Copper Wires for High-Energy Alkaline Battery

Nilesh R. Chodankar et al.

NANO-MICRO LETTERS (2020)

Review Nanoscience & Nanotechnology

Recent Progress of Two-Dimensional Thermoelectric Materials

Delong Li et al.

NANO-MICRO LETTERS (2020)

Article Nanoscience & Nanotechnology

Electrical and Elastic Properties of Individual Single-Layer Nb4C3Tx MXene Flakes

Alexey Lipatov et al.

ADVANCED ELECTRONIC MATERIALS (2020)

Article Materials Science, Multidisciplinary

A Gel-Free Ti3C2Tx-Based Electrode Array for High-Density, High-Resolution Surface Electromyography

Brendan B. Murphy et al.

ADVANCED MATERIALS TECHNOLOGIES (2020)

Article Nanoscience & Nanotechnology

Self-Healing Ti3C2 MXene/PDMS Supramolecular Elastomers Based on Small Biomolecules Modification for Wearable Sensors

Kaiming Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Physical

Visible-Light-Induced Photocatalytic Activity of Stacked MXene Sheets of Y2CF2

Kazuhiko Maeda et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Review Chemistry, Inorganic & Nuclear

Synthesis, properties and novel electrocatalytic applications of the 2D-borophene Xenes

Karim Khan et al.

PROGRESS IN SOLID STATE CHEMISTRY (2020)

Article Multidisciplinary Sciences

Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes

Vladislav Kamysbayev et al.

SCIENCE (2020)

Article Multidisciplinary Sciences

Large-scale wet-spinning of highly electroconductive MXene fibers

Wonsik Eom et al.

NATURE COMMUNICATIONS (2020)

Article Multidisciplinary Sciences

Ion sieving by a two-dimensional Ti3C2Tx alginate lamellar membrane with stable interlayer spacing

Jin Wang et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Physical

Facile synthesis of α-Fe2O3/Nb2O5 heterostructure for advanced Li-Ion batteries

Rabia Khatoon et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2020)

Article Chemistry, Multidisciplinary

Bulk and Surface Chemistry of the Niobium MAX and MXene Phases from Multinuclear Solid-State NMR Spectroscopy

Kent J. Griffith et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Multidisciplinary Sciences

Chemical vapor deposition of layered two-dimensional MoSi2N4 materials

Yi-Lun Hong et al.

SCIENCE (2020)

Article Green & Sustainable Science & Technology

Two-dimensional fluorine-free mesoporous Mo2C MXene via UV-induced selective etching of Mo2Ga2C for energy storage

Jun Mei et al.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2020)

Article Materials Science, Multidisciplinary

Recent advances of low-dimensional materials in Mid- and Far-infrared photonics

Hualong Chen et al.

APPLIED MATERIALS TODAY (2020)

Article Chemistry, Multidisciplinary

Tailoring Electronic and Optical Properties of MXenes through Forming Solid Solutions

Meikang Han et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Nanoscience & Nanotechnology

Chromium Carbide Nanosheets Prepared by Selective Etching of Aluminum from Cr2AlC for Hydrazine Detection

Bhuvaneswari Soundiraraju et al.

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