4.7 Article

Facile synthesis of FeNi nanoparticle-loaded carbon nanocomposite fibers for enhanced microwave absorption performance

期刊

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 175, 期 -, 页码 141-152

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JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2023.07.053

关键词

FeNi alloy; Carbon nanofiber; Electrospinning; Microwave absorption

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In this study, FeNi/C nanofibers were prepared by combining the advantages of Fe, Ni metals and one-dimensional carbon materials for electromagnetic microwave absorption. The FeNi/C nanofibers exhibited excellent absorption performance under dielectric/magnetic synergistic effect. The unique microstructure and electromagnetic properties of FeNi/C nanofibers contributed to its superior absorption performance.
The advantages of Fe, Ni metals and one-dimensional (1D) carbon materials are combined in this study using a simple method to prepare FeNi/C nanofibers for electromagnetic microwave (EM) absorption. The prepared FeNi/C nanofibers exhibit excellent EM absorption performance under dielectric/magnetic synergistic effect. At a frequency of 13.3 GHz, the minimum reflection loss (RL min ) reaches -57.15 dB, and effective absorption bandwidth (EAB) is as high as 4.0 GHz (12.5-16.5 GHz), with a thickness and filling rate of only 1.6 mm and 30 wt.%, respectively. Analysis shows that the EM absorption performance of FeNi/C nanofibers far exceeds that of single-component nanofibers and pure carbon fibers, and the excellent EM absorption performance is due to its unique microstructure and excellent electromagnetic properties. The FeNi alloy loaded on carbon nanofibers forms rich heterogeneous interfaces, and the three-dimensional (3D) conductive network composed of 1D carbon fibers increases the migration path of electrons. In addition, FeNi alloy, as an impedance regulation factor, strengthens the dielectricity of the carbon matrix while providing multidimensional magnetism, achieving impedance matching. This work is thought to contribute to the promotion of emerging absorbers by providing a novel strategy for the development of new 1D magnetic carbon-based high-performance EM absorbing materials. (c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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