Facile synthesis of novel magnesium oxide nanoparticles for pesticide sorption from water

The quantum of pesticides in surface as well as drinking water has become a serious health hazard. In this experiment, magnesium oxide nanoparticles (MgO NPs) were synthesized using leaves of purple-colored rice variety ( Crossa) and utilized for simultaneous removal of three pesticides, namely, thiamethoxam, chlorpyriphos, and fenpropathrin from water. The biogenic MgO NPs were characterized using SEM-EDX, FTIR, XRD, DLS, etc. The optimum synthesis parameters (1 M NaOH, 80 degrees C, and 2 h) resulted in maximum yield of MgO NPs (87.7 mg), minimum hydrodynamic diameter (35.12 nm), poly dispersity index (0.14) and mean zeta potential (-11 mV). Sorption data of the three pesticides fitted well with nonlinear Langmuir and Freundlich isotherm models and non-linear pseudo-second-order kinetic model. The maximum adsorption capacity of MgO NPs for the three pesticides was 87.66 mu g/mg, as obtained from the Langmuir isotherm model. Under optimum conditions (initial concentration, 40 mg/L; dose, 30 mg/30 mL; and pH, 9), 60.13, 80.53, and 92.49% removal of thiamethoxam, chlorpyriphos, and fenpropathrin was achieved with a 100% desirability, respectively. Thus, the biogenic MgO NPs could be an efficient adsorbent of pesticides and could be recommended for pesticide decontamination in water treatment plants and domestic water purifier systems.

Automated summary

This experiment synthesized magnesium oxide nanoparticles using leaves of purple-colored rice variety and found that they could efficiently remove three pesticides from water. The nanoparticles were characterized and their maximum adsorption capacity for the pesticides was determined. Under optimal conditions, the nanoparticles achieved high removal rates for all three pesticides, suggesting their potential use in water treatment and purification systems.