期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 80, 页码 11923-11931出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc03820c
关键词
-
The aerobic oxidative cleavage of C-C bonds is an attractive and sustainable method for constructing valuable molecules. Traditional methods face thermodynamic and kinetic barriers, hence developing efficient, low-cost, and environmentally friendly cleavage methods is crucial.
The aerobic oxidative cleavage of C-C bonds is an attractive and sustainable route for constructing valuable molecules such as esters, nitriles, and amides. Traditionally homogeneous catalytic systems for C-C bond cleavage required harsh conditions, stoichiometric oxidants, and noble metal catalysts to overcome the thermodynamic and kinetic barriers of C-C bonds, imposing environmental concerns of the transformation. Therefore, developing efficient, low-cost, and environmentally benign methods for C-C bond cleavage is of great importance and a cutting-edge area in modern chemistry. This feature article summarizes the sustainable aerobic oxidative C-C bond cleavage method developed by our group in the past 5 years. Fundamental principles in catalyst design, substrate scope, and mechanism for C-C bond cleavage are also discussed. Aerobic oxidative cleavage of the C-C bond is summarized, focusing on reactions catalyzed by sustainable non-noble metal catalysts and carried out under mild conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据