4.7 Article

KMB4O6F3 (M = Co, Fe): two-dimensional magnetic fluorooxoborates with triangular lattices directed by triangular BO3 units

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DALTON TRANSACTIONS
卷 52, 期 38, 页码 13555-13564

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3dt02394j

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In this study, two novel layered magnetic fluorooxoborates with triangular lattices have been successfully synthesized and characterized. The compounds exhibit no magnetic long-range ordering transition at low temperatures and show high magnetic saturation values. Furthermore, the study suggests a promising method for experimentally realizing specific magnetic lattices using directed synthesis.
Frustrated magnetic systems are of great interest owing to their spin liquid state for application in quantum computing. However, experimentally, spin liquid has not been realized. Thus, experimental explorations of frustrated magnetic systems including triangular lattices are still urgent, particularly for directed synthesis compared to random exploration. Herein, for the first time, directed by the use of a triangular unit of the BO3 anion group, two novel layered magnetic fluorooxoborates KMB4O6F3 (M = Co 1, Fe 2) with triangular lattices have been hydrothermally synthesized and characterized. Compounds 1 and 2 are isostructural and crystallize in the P2(1)/c space group with layered magnetic triangular lattices, which are further separated by K+ ions. Magnetic susceptibility curves of both 1 and 2 show no lambda-anomaly peak down to a low temperature of 2 K in the absence of a magnetic long-range ordering transition, which are further confirmed by the heat capacity results. The magnetic-field dependence of magnetization at 2 K shows saturation of 2.20(mu B )for 1 and 4.24(mu B )for 2, respectively, at 7 T, after roughly subtracting the Van Vleck paramagnetic contribution. Further in-depth investigation of the underlying physics at a lower temperature below 2 K would be subsequently performed. Moreover, thermal stability and FT-IR and UV-vis-NIR spectroscopy with optical bandgap properties are also reported. Most importantly, our work provides a promising method to experimentally realize specific magnetic lattices (e.g. triangular lattices) directed by the use of triangular groups (e.g. BO3) as the functional unit.

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