4.7 Review

Multi-type heterostructures: Rational design anode materials for alkali-ion batteries

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Summary: This review provides an overview of the research progress on Si/C anodes in lithium-ion batteries. It highlights the lithiation mechanism, solid electrolyte interface formation, and various carbon sources used in Si/C anodes. The review also summarizes and prospects the selection of carbonaceous materials, structural design, and interface control of Si/C anodes, as well as their application in all-solid-state lithium-ion batteries and sodium-ion batteries.

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Summary: In this paper, homotype heterojunctions were designed on hard carbon (HC) anodes to improve their initial Coulombic efficiency (ICE) and cycling stability for sodium-ion batteries. By constructing a homotypic amorphous Al2O3 layer on the HC, the active sites were shielded, electrolyte decomposition and side effects were inhibited, and the interface resistance was decreased. The optimized HC anode exhibited outstanding reversible capacity and improved cycling stability, providing a new strategy for the application of hard carbon in sodium-ion batteries.

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Fabrication of CoSe@NC nanocubes for high performance potassium ion batteries

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Summary: The heterostructured CoSe@NC nanocubes, fabricated through a simple annealing and in-situ selenization process, show excellent potassium-ion storage performance with high initial charge capacity, superior cyclic stability, and exceptional rate capability. The use of ZIF-67 nanocubes as a template for porous structure formation facilitates the construction of a heterogeneous interface, effectively stabilizing CoSe and increasing diffusion mobility. The low-cost and facile production approach makes CoSe@NC a promising anode material for PIBs.

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Ping Gao et al.

Summary: The hetero-MoO3/MoO2@NC composite anodes exhibit impressive rate capability and long lifespan in both potassium and sodium ion batteries, with a balance of sustainable storage and durable structure stability. The architecture significantly improves electronic conductivity and offers abundant oxygen deficiencies, showing promise for potassium/sodium storage applications.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Chemistry, Physical

Rational design of carbon materials as anodes for potassium-ion batteries

Yuanming Wu et al.

Summary: This review summarizes the recent advances in rational design of carbon materials for developing anodes for potassium-ion batteries, including practical issues with various carbon materials as anodes, potassium storage mechanisms, and design methods for carbon materials. The ultimate goal is to develop next-generation carbon anodes with high energy density and excellent cycling stability.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Progress and perspectives of 2D materials as anodes for potassium-ion batteries

Chenchen Zhang et al.

Summary: Researchers are increasingly interested in the development of rechargeable batteries using potassium instead of lithium as the charge carrier, as this technology is considered a promising choice for large-scale energy storage. However, research on potassium ion batteries (PIBs) is still in its early stages, facing various challenges, including the need to find a suitable anode material. Two-dimensional materials show great potential in battery applications due to their unique properties.

ENERGY STORAGE MATERIALS (2021)

Review Materials Science, Ceramics

Garnet-type solid electrolyte: Advances of ionic transport performance and its application in all-solid-state batteries

P. M. Gonzalez Puente et al.

Summary: All-solid-state lithium batteries with garnet-type solid electrolyte LLZO show high energy density, electrochemical stability, and compatibility with various materials, making them an ideal solution for addressing battery safety issues and meeting the energy storage demands in electric vehicles and other applications.

JOURNAL OF ADVANCED CERAMICS (2021)

Article Electrochemistry

Fabrication of S,N-Doped Carbon-Coated SnS2/SnS Heterostructures Supported by Hollow Carbon Microspheres for Sodium-Ion Storage

Suning Gao et al.

Summary: A novel negative electrode material containing SnS2/SnS p-n heterostructures embedded in S,N-doped carbon layer supported by hollow carbon spheres has been developed for sodium ion batteries. This material shows promising initial reversible capacity, superior rate capability, and long cycle life, making it a potential candidate for future battery technologies.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Review Chemistry, Physical

Recent advances in anode materials for potassium-ion batteries: A review

Lianbo Ma et al.

Summary: Potassium-ion batteries (PIBs) have emerged as appealing alternatives to conventional lithium-ion batteries (LIBs) due to their wide potential window, fast ionic conductivity, and reduced cost. Despite facing challenges such as slow reaction kinetics and large volume expansion, various strategies, especially in electrode design, have been proposed to address these issues. Recent progress on advanced anode materials of PIBs has been systematically discussed, highlighting the design principles and structure-performance relationship to pave the way for practical applications.

NANO RESEARCH (2021)

Review Chemistry, Applied

Gallium-based anodes for alkali metal ion batteries

Wenjin Yang et al.

Summary: Alkali metal ion batteries are crucial in the energy revolution due to their large capacity/power density and abundance of alkali metal ions. Gallium-based materials with impressive capacity utilization and self-healing ability offer a potential solution to the inherent deficiencies of current anodes.

JOURNAL OF ENERGY CHEMISTRY (2021)

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The recent progress of pitch-based carbon anodes in sodium-ion batteries

Mingchi Jiang et al.

Summary: Sodium-ion batteries (SIBs) are gaining attention as alternatives to lithium-ion batteries for large-scale energy storage, with carbon materials considered competitive anodes due to their low cost and structural stability. Pitch, a raw material with high carbon content and low cost, is ideal for producing carbon materials. However, the ordered microstructures of pitch-based carbon negatively impact sodium ion storage. Efforts to improve sodium storage performance include morphology adjustments, heteroatoms doping, fabricating heterostructures, and increasing disorder. This review provides insight into developing low-cost, high-performance pitch-based carbon anodes for SIBs.

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Article Materials Science, Ceramics

Solvents adjusted pure phase CoCO3 as anodes for high cycle stability

Liming Liu et al.

Summary: By adjusting the solvents, CoCO3 particles with different particle and pore sizes were prepared in this study. Among them, CoCO3 synthesized with diethylene glycol as the solvent showed the best electrochemical performance, achieving high specific capacity, excellent capacity retention, and robust structural stability. These results provide important reference for the design and stable cycle performance of pure CoCO3.

JOURNAL OF ADVANCED CERAMICS (2021)

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Bimetallic Sulfide SnS2/FeS2 Nanosheets as High-Performance Anode Materials for Sodium-Ion Batteries

Yun Chen et al.

Summary: The SnS2/FeS2/rGO composite material shows superior electrochemical performance in sodium-ion batteries, with high cycle stability and rate performance.

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A Novel Tin-Bonded Silicon Anode for Lithium-Ion Batteries

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Summary: A novel Sn-bonded Si anode is proposed, showing superior cyclic stability and high rate performance by improving electronic conductivity and enhancing adhesive strength of the electrode.

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High-performance carbon by amorphization and prepotassiation for potassium-ion battery anodes

Ki-Hun Nam et al.

Summary: Rechargeable K-ion batteries have drawn much attention as a potential replacement for Li-ion batteries due to the abundance and low cost of potassium. By amorphizing and prepotassiating carbon black, a high-performance C-based anode was obtained, significantly improving the K storage properties and enhancing electrochemical performance. The prepotassiated/amorphized CB exhibited high reversible capacity, exceptional initial Coulombic efficiency, high rate capability, and remarkable cycling stability, making it a promising material for future KIB anodes.

CARBON (2021)

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Advances in multimetallic alloy-based anodes for alkali-ion and alkali-metal batteries

Xin Wang et al.

Summary: Alloying anodes are gaining interest for high-performance alkalimetal-ion batteries due to their high specific capacities, low working voltages, and natural abundance. However, challenges such as unsatisfactory cycle life due to violent volumetric and structural changes have led to the development of multimetallic anodes that can accommodate induced strain for high Coulomb efficiency and long cycle life. Efforts have also been made to understand structural changes and reaction mechanisms through in-situ characterization methodologies.

MATERIALS TODAY (2021)

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Conversion-Alloying Anode Materials for Sodium Ion Batteries

Libin Fang et al.

Summary: This article discusses the storage mechanisms, challenges, and improvement strategies of conversion-alloying anode materials in sodium ion batteries, and proposes a development roadmap for advanced materials for commercializable SIBs.
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Tunable electronic properties of free-standing Fe-doped GaN nanowires as high-capacity anode of lithium-ion batteries

Kefeng Xie et al.

Summary: The Fe doping strategy in GaN improved electrical conductivity and charge-transfer efficiency, providing abundant nanochannels for efficient ionic transfer and reduced Li diffusion barrier. Fe covalently doped GaN nanowires exhibited enhanced Li+ storage performance, demonstrating the potential for efficient Li+ storage electrodes.

ARABIAN JOURNAL OF CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Construction of Sb2S3@SnS@C Tubular Heterostructures as High-Performance Anode Materials for Sodium-Ion Batteries

Jian Lin et al.

Summary: The Sb2S3@SnS@C nanocomposites with a hollow-tube-heterostructure show improved performance for sodium-ion batteries, including cycling stability and rate capacity.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Materials Science, Ceramics

Pomegranate-type Si/C anode with SiC taped, well-dispersed tiny Si particles for lithium-ion batteries

Pengfei Wu et al.

Summary: The study introduced a pomegranate-type Si/C composite anode, which utilizes a combination of silicon and SiC to enhance the performance of the silicon anode, including promoting dual charge transfer and improving the tap density of the electrode.

JOURNAL OF ADVANCED CERAMICS (2021)

Article Chemistry, Physical

Quantum dot heterostructure with directional charge transfer channels for high sodium storage

Song Yang et al.

Summary: Transition metal carbides (TMCs) are considered promising anode materials for sodium ion batteries due to their high conductivity and chemical stability, but their practical applications have been hindered by slow kinetics and volume expansion. A universal strategy of loading high work-function metal quantum dots (QDs) to provide a directional charge transfer path by constructing the interfacial Mott-Schottky heterojunction has been proposed to address these issues and enhance the sodium storage capability of TMCs, leading to unprecedented capacity, rate performance, and cycling stability.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Multidisciplinary

Rational Design of Sulfur-Doped Three-Dimensional Ti3C2Tx MXene/ZnS Heterostructure as Multifunctional Protective Layer for Dendrite-Free Zinc-Ion Batteries

Yongling An et al.

Summary: By designing and constructing a protective heterogeneous layer composed of sulfur-doped three-dimensional (3D) MXene and ionic conductive ZnS on the zinc anode, the issues of dendrite growth and side reactions hindering the practical applications of zinc anode in aqueous batteries have been successfully addressed. This results in a stable and dendrite-free zinc anode with notable cycling stability and high-rate performance.

ACS NANO (2021)

Article Materials Science, Multidisciplinary

A flexible metallic TiC nanofiber/vertical graphene 1D/2D heterostructured as active electrocatalyst for advanced Li-S batteries

Yongshang Zhang et al.

Summary: This study developed a flexible Li-S battery architecture based on electrocatalyzed cathodes, which successfully improved the conversion kinetics between sulfur species by enhancing both ion and electron transportation as well as affinity to polysulfides, leading to homogeneous deposition of Li2S in the catalyzed cathodes. The highly active electro-electrocatalysts-based cells exhibited remarkable rate capability and high specific capacity, even under ultra-high sulfur loading and low electrolyte/sulfur ratio conditions.

INFOMAT (2021)

Article Chemistry, Physical

Structure-induced partial phase transformation endows hollow TiO2/TiN heterostructure fibers stacked with nanosheet arrays with extraordinary sodium storage performance

Pan Xue et al.

Summary: By utilizing a structure-induced partial phase transformation method, hierarchical hollow TiO2/TiN heterostructure fibers with a high specific surface area were successfully synthesized as an anode material. The interfacial effect of the heterostructures improved charge transfer capability for the anode materials.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Multidisciplinary

State-of-the-art anodes of potassium-ion batteries: synthesis, chemistry, and applications

Peng Li et al.

Summary: The growing demand for green energy has driven the exploration of sustainable and eco-friendly energy storage systems, with potassium-ion batteries (KIBs) emerging as a promising alternative to lithium-ion batteries. Key focus lies in the need to explore superior anode materials and overcome critical issues and challenges in KIB technology.

CHEMICAL SCIENCE (2021)

Article Chemistry, Physical

Heterojunction TiO2@TiOF2 nanosheets as superior anode materials for sodium-ion batteries

Shoujie Guan et al.

Summary: Anatase TiO2 is a promising anode material for sodium-ion batteries, but its shortcomings in semiconductor properties and sluggish Na+ diffusion kinetics hinder further development. A heterojunction TiO2@TiOF2 structure constructed with two-dimensional nanosheets shows stable cycling performance for up to 10,000 cycles at high current densities, attributed to its unique structure and the in situ formation of a NaF protective layer. Density functional theory calculations indicate that the heterostructure TiO2@TiOF2 nanosheets exhibit improved electrical conductivity and lower formation energies of Na+ ions compared to the separated TiO2 and TiOF2.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Physical

Constructing a hollow microflower-like ZnS/CuS@C heterojunction as an effective ion-transport booster for an ultrastable and high-rate sodium storage anode

Wenxi Zhao et al.

Summary: Hierarchical heterostructure coupling metal sulfides with carbonaceous functional support shows promising performance as anode candidates in sodium-ion batteries. The developed ZnS/CuS@C architecture exhibits impressive cycling life and competitive rate capability due to the synergistic coupling effect of heterostructures. Kinetics analysis and theoretical calculations suggest that the heterointerface induces large pseudocapacitive behaviors and ultrafast sodiation kinetics.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

Monolithic Nanoporous Zn Anode for Rechargeable Alkaline Batteries

Congcheng Wang et al.

ACS NANO (2020)

Article Engineering, Chemical

Recent progress of advanced anode materials of lithium-ion batteries

Hui Cheng et al.

Journal of Energy Chemistry (2020)

Article Chemistry, Physical

Dual-phase MoS2 as a high-performance sodium-ion battery anode

Junxiong Wu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Nanoscience & Nanotechnology

SnP3/Carbon Nanocomposite as an Anode Material for Potassium-Ion Batteries

Rakesh Verma et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Nanoscience & Nanotechnology

Interfacial Reaction Mechanisms on Graphite Anodes for K-Ion Batteries

Andrew J. Naylor et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Review Chemistry, Multidisciplinary

Alkali Metal Anodes for Rechargeable Batteries

Hua Wang et al.

Article Chemistry, Physical

Hierarchical Sb2MoO6 microspheres for high-performance sodium-ion battery anode

Xuan Lu et al.

ENERGY STORAGE MATERIALS (2019)

Article Astronomy & Astrophysics

Nonequilibrium Ionization in Mixed-morphology Supernova Remnants

Gao-Yuan Zhang et al.

ASTROPHYSICAL JOURNAL (2019)

Article Chemistry, Multidisciplinary

Electric field effect in a Co3O4/TiO2 p-n junction for superior lithium-ion storage

Huabin Kong et al.

MATERIALS CHEMISTRY FRONTIERS (2019)

Review Materials Science, Multidisciplinary

Gas sensing with heterostructures based on two-dimensional nanostructured materials: a review

Atanu Bag et al.

JOURNAL OF MATERIALS CHEMISTRY C (2019)

Article Nanoscience & Nanotechnology

Fe2O3/SnSSe Hexagonal Nanoplates as Lithium-Ion Batteries Anode

Yufei Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Engineering, Environmental

Carbon-encapsulated 1D SnO2/NiO heterojunction hollow nanotubes as high-performance anodes for sodium-ion batteries

Wenming Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2018)

Review Materials Science, Multidisciplinary

Recent progress of NiCo2O4-based anodes for high-performance lithium-ion batteries

Xiao Han et al.

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE (2018)

Review Chemistry, Physical

Two-dimensional nanostructures for sodium-ion battery anodes

Jianfeng Mao et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

SnP nanocrystals as anode materials for Na-ion batteries

Junfeng Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Review Chemistry, Physical

Structural design of anode materials for sodium-ion batteries

Wanlin Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Physical

MoSe2/N-Doped Carbon as Anodes for Potassium-Ion Batteries

JunMin Ge et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Physical

Sn-Bi-Sb alloys as anode materials for sodium ion batteries

Hezhen Xie et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Chemistry, Physical

rGO/SnS2/TiO2 heterostructured composite with dual-confinement for enhanced lithium-ion storage

Hong-En Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

Article Chemistry, Physical

Cu4SnP10 as a promising anode material for sodium ion batteries

Danni Lan et al.

NANO ENERGY (2017)

Article Chemistry, Physical

Phosphorus-Based Materials as the Anode for Sodium-Ion Batteries

Fuhua Yang et al.

SMALL METHODS (2017)

Review Chemistry, Multidisciplinary

Na-Ion Battery Anodes: Materials and Electrochemistry

Wei Luo et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Article Multidisciplinary Sciences

Freestanding three-dimensional core-shell nanoarrays for lithium-ion battery anodes

Guoqiang Tan et al.

NATURE COMMUNICATIONS (2016)

Article Chemistry, Multidisciplinary

Graphite-Encapsulated Li-Metal Hybrid Anodes for High-Capacity Li Batteries

Yongming Sun et al.