4.6 Article

Naphthylacetonitrile isomerism and donor conformational flexibility controlled molecular self-assembly and solid-state fluorescence properties

期刊

JOURNAL OF LUMINESCENCE
卷 264, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.jlumin.2023.120173

关键词

-

类别

向作者/读者索取更多资源

Organic fluorophores with propellor/partially planar donor unit and naphthylacetonitrile positional isomer were synthesized and their impact on solid-state structural assembly, fluorescence properties, and stimuli-induced fluorescence switching were investigated. The modulation of molecular conformation and packing contributed to fluorescence tuning, and the reversible phase transformation between crystalline and amorphous phase resulted in mechanical and heating induced fluorescence switching.
Organic fluorophores with propellor/partially planar donor unit and naphthylacetonitrile positional isomer were synthesized and explored their impact on the solid -state structural assembly, fluorescence properties and stimuli-induced fluorescence switching. Partially planar phenyl carbazole (Cz) and propeller shaped triphe-nylamine (TPA) donor units integrated with 1-naphthylacetonitrile/2-naphthylacetonitrile acceptors (Cz-1-Naph, Cz-2-Naph and TPA-2-Naph) by simple condensation reaction. All three compounds showed weak and tunable fluorescence in solution (lambda max = 452-520 nm, phi f = 0.24 compared to quinine sulphate standard). However, Cz-Naph isomers showed relatively strong solid-state fluorescence compared to TPA-Naph (phi f = 5.9% (Cz-1-Naph), 13.8% (Cz-2-Naph) and 1.2% (TPA-2-Naph)). Further, Cz-Naph isomers showed relatively blue shifted emission (lambda max = 517 (Cz-1-Naph) and 498 nm (Cz-2-Naph)) compared to TPA-2-Naph isomer (lambda max 543 nm). Solid-state structural analysis revealed varied molecular conformation and arrangement depending on the naphthyl isomerism and donor units. The modulation of molecular conformation and packing contributed for fluorescence tuning. Computational studies indicated a clear intramolecular electron transfer from TPA/Cz donor to naphthylacetonitrile acceptor unit. Interestingly, Cz-2-Naph exhibited reversible mechanical crushing and heating induced fluorescence switching that was attributed to the reversible phase transformation between crystalline and amorphous phase and vice versa.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据