Development and characterization of novel emulsified nanocomposite coatings incorporating different loadings of nanoclay and beeswax for paper packaging

Paper coated with poly (vinyl alcohol) (PVA)-based films incorporating varying amounts of halloysite nanotubes (HNTs) and/or beeswax (BW) were developed. The applied PVA/HNTs nanocomposite films, PVA/BW emulsified films, and PVA/HNTs/BW emulsified nanocomposite films were characterized in terms of FTIR, TGA, DSC, and XRD analyses. The effects of HNTs and/or BW at different loadings on the functional properties of coated paper were investigated. HNTs and BW co-incorporation significantly improved the water vapor permeability of the resulting PVA/HNTs/BW coated paper samples, and reduced their Cobb60 values, respectively, by more than 50, 24, and 18% as compared to the uncoated paper, paper coated with pristine PVA and paper coated with PVA/HNTs nanocomposite-based coatings. While increasing their contact angle values in the range of 10-20%. Likewise, HNTs and BW co-incorporation increased the mechanical strength of PVA/HNTs/BW coated paper in the range of 20.54-29.80% as compared to the uncoated paper, while increasing their flexibility up to 32.50%. Such enhancement in the functional properties of PVA/HNTs/BW coated paper is most likely due to the establishment of interactions between PVA, BW, and HNTs. Our results demonstrate the ability of PVA/HNTs/BW emulsified nanocomposite coatings to improve paper barrier and mechanical properties owing to the prominent reinforcement effects of HNTs and the good moisture-barrier properties of BW. Synthesis and characterization of novel poly(vinyl alcohol) (PVA) emulsified nanocomposite coated papers.

Automated summary

The functional properties of paper coated with poly(vinyl alcohol) (PVA) films incorporating halloysite nanotubes (HNTs) and/or beeswax (BW) were investigated. The results showed that the co-incorporation of HNTs and BW significantly improved the water vapor permeability and mechanical strength of the coated paper, while reducing the Cobb60 values. Additionally, the flexibility of the paper was enhanced.