☆ 4.6 Review

Reticular materials for wastewater treatment

JOURNAL OF MATERIALS CHEMISTRY A (2023)

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Review Chemistry, Physical

Recent advances in metal-free covalent organic frameworks for photocatalytic applications in energy and environmental fields

Zilong Zhou et al.

Summary: Covalent organic frameworks (COFs) are a type of emerging organic polymers with unique properties that make them suitable for various applications. This review focuses on metal-free COF photocatalysts and their potential in environmental fields such as water splitting, pollutant degradation, and CO2 reduction. The synthesis strategy, current development, and future challenges and outlooks are also discussed.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

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Article Engineering, Environmental

Olefin-linked cationic covalent organic frameworks for efficient extraction of ReO4-/99TcO4-

Wei-Rong Cui et al.

Summary: In this study, a novel olefin-linked cationic covalent organic framework (COF) BDBI-TMT was synthesized by integrating robust imidazolium salt-based linkers with triazine building blocks, which showed excellent stability in acid/base solutions and radiation. BDBI-TMT exhibited ultra-fast adsorption kinetics and high capture capacity for ReO4- (a non-radioactive surrogate of 99TcO4-), attributed to the abundance of precisely tailored imidazolium salt-based units and the hydrophobicity of the alkyl skeleton. The selective and reversible extraction of ReO4- under extreme conditions demonstrates the great potential of olefin-linked cationic COFs for radionuclide remediation.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Engineering, Environmental

Efficient adsorption and photocatalytic degradation of water emerging contaminants through nanoarchitectonics of pore sizes and optical properties of zirconium-based MOFs

Jia-Xuan Tan et al.

Summary: In recent decades, the high concentration of pharmaceutical emerging contaminants in water bodies from wastewater effluent has raised concerns. The presence of multiple components in water systems makes it challenging to remove pollutants. In this study, a Zr-based metal-organic framework (MOF) called VNU-1 was synthesized and applied to achieve selective photodegradation and enhance the photocatalytic activity of emerging contaminants. Compared to UiO-66 MOFs, VNU-1 exhibited higher adsorption and 100% photodegradation in 10 minutes. The tailored pore size of VNU-1 resulted in size-selective properties and maintained high photodegradation performance after multiple cycles.

JOURNAL OF HAZARDOUS MATERIALS (2023)

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Article Engineering, Environmental

Linker regulation of iron-based MOFs for highly effective Fenton-like degradation of refractory organic contaminants

Junying Chen et al.

Summary: Iron-based MOFs with tunable structure and large surface area have been used in heterogeneous Fenton-like reactions for the degradation of new pollutants. This study investigates how the linker substituents of MIL-101 with MTN-typed topology influence the catalytic efficiency. The results show that the substituents affect crystal morphology and the MIL-101-NH2 exhibits significantly faster antibiotics removal compared to MIL-101-H due to the change in active surface.

CHEMICAL ENGINEERING JOURNAL (2023)

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Review Chemistry, Inorganic & Nuclear

Covalent organic frameworks for photocatalysis: Synthesis, structural features, fundamentals and performance

Yun-Nan Gong et al.

Summary: This review summarizes the synthesis methods, structural features, and photocatalytic applications of covalent organic frameworks (COFs). Strategies for improving photocatalytic performance and future challenges and prospects are also discussed.

COORDINATION CHEMISTRY REVIEWS (2023)

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Article Engineering, Chemical

Highly efficient antibacterial adsorbent for recovering uranium from seawater based on molecular structure design of PCN-222 post-engineering

Changlong Bi et al.

Summary: In this study, a novel adsorbent PCN-222-AO was synthesized by grafting amidoxime groups on the surface of PCN-222. It exhibited outstanding U(VI) adsorption capacity, selectivity, and reusability. The adsorbent also showed excellent performance in simulated and real seawater. The presence of specific groups, such as C=N (H2TCPP), C=N-OH, and -NH(2), played a vital role in the U(VI) adsorption process. Additionally, PCN-222-AO demonstrated antibacterial property, anti-biofouling activity, and environmental safety. The design and construction of effective adsorbents are crucial for U(VI) resource recovery. PCN-222-AO is a promising adsorbent for U(VI) recovery from seawater, providing a new idea for the molecular structure design and construction of high-efficiency adsorbents.

DESALINATION (2023)

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Review Chemistry, Multidisciplinary

Green Synthesis of Reticular Materials

Aamod V. Desai et al.

Summary: To ensure a prosperous future on Earth, academia and industry must transform the synthesis of novel materials to be more environmentally sustainable. This review highlights the importance of choosing starting materials, solvents, and synthetic methodologies in line with Green Chemistry principles, and emphasizes the importance of considering circular economy strategies such as reuse, regeneration, and recycling. Furthermore, it explores the impact of Green Chemistry principles and life cycle assessment metrics on the rational sustainable design and discovery of materials.

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Engineering, Chemical

Progress reports of metal-phenolic network engineered membranes for water treatment

Yajie Wen et al.

Summary: This paper focuses on the formation mechanism and characteristics of metal-phenolic network (MPN) and its applications in constructing multifunctional MPN-engineered membranes. The application of MPN-engineered membranes in water treatment, including separation, catalysis, and adsorption, is introduced. The prospects for developing ultra-thin and durable MPN-engineered functional membranes are discussed.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

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Article Multidisciplinary Sciences

Dual donor-acceptor covalent organic frameworks for hydrogen peroxide photosynthesis

Chencheng Qin et al.

Summary: This study designs benzotrithiophene-based covalent organic frameworks with spatially separated redox centers for the photocatalytic production of hydrogen peroxide. The triazine-containing framework demonstrates high selectivity for H2O2 photogeneration, with a yield rate of 2111μMh(-1) and a solar-to-chemical conversion efficiency of 0.296%.

NATURE COMMUNICATIONS (2023)

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Article Chemistry, Physical

Blue light photocatalytic oxidation of sulfides to sulfoxides with oxygen over a thiazole-linked 2D covalent organic framework

Yuexin Wang et al.

Summary: With permanent porosity and intrinsic crystallinity, covalent organic frameworks (COFs) have great potential for solar energy conversions. However, the crystallinity of COFs necessitates reversible linkages like imine, leading to inadequate chemical stability. To overcome this, post-synthetic modifications (PSMs) transformed an imine-linked COF into a thiazole-linked COF, which exhibited improved stability and optoelectronic properties for photocatalytic oxidation reactions of organic sulfides under visible light irradiation. This work highlights the transformative power of PSMs for tailoring COFs in visible light photocatalysis.

APPLIED CATALYSIS B-ENVIRONMENTAL (2023)

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Correction Multidisciplinary Sciences

14-3-3 sigma is required to prevent mitotic catastrophe after DNA damage (vol 41, 616, 1999)

Timothy A. Chan et al.

NATURE (2023)

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Article Chemistry, Multidisciplinary

Covalent Organic Framework Membrane with Turing Structures for Deacidification of Highly Acidic Solutions

Lihong Zhou et al.

Summary: A novel COF membrane with bidirectional anisotropic Turing structures was synthesized for deacidification of highly acidic industrial wastewater, demonstrating excellent water permeability and metal ion interception capabilities. The membrane allows for efficient deacidification of high acidic solutions, providing a new solution for the treatment of industrial wastewater.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Engineering, Environmental

Amidoxime-functionalized covalent organic framework as simultaneous luminescent sensor and adsorbent for organic arsenic from water

Hui Chen et al.

Summary: Covalent organic frameworks (COFs) have been investigated as fluorescence sensors and adsorbents for the detection and removal of organic arsenic from water. The synthesized sp2 carbon-conjugated COFs with amidoxime functionalization exhibit high fluorescence quenching efficiencies for detecting roxarsone (ROX) and high adsorption capacities for organic arsenic compounds. The results demonstrate the great potential of these COFs for practical applications in wastewater treatment.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Peroxymonosulfate enhanced photocatalytic degradation of serial bisphenols by metal-free covalent organic frameworks under visible light irradiation: mechanisms, degradation pathway and DFT calculation

Fuyang Liu et al.

Summary: Metal-free photocatalysts in the form of covalent organic frameworks (COF-PRD) were utilized to activate PMS for the degradation of bisphenols under visible light irradiation. The degradation process was dominated by O-2(-), h(+), and O-1(2), and showed effectiveness in both aerobic and anaerobic conditions while reducing bioaccumulation effects and exhibiting excellent reusability.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Environmental Sciences

Adsorption behavior and mechanism of sulfonamides on controllably synthesized covalent organic frameworks

Wenjing Sun et al.

Summary: In this study, four types of COF materials were synthesized by an ultrasonic method for adsorption of five sulfonamides. Optimization and kinetic experiments revealed main adsorption mechanisms such as pore filling, hydrogen bond interactions, and electrostatic attraction.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2022)

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Review Chemistry, Multidisciplinary

Macroscopic MOF Architectures: Effective Strategies for Practical Application in Water Treatment

Yiyuan Yao et al.

Summary: This article discusses successful strategies for fabricating macroscopic materials from MOFs and their applications in removing pollutants from water; the macroscopic performance of MOFs ranging from 0D to 3D can be utilized for water treatment through adsorption, separation, and advanced oxidation processes.

SMALL (2022)

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Article Chemistry, Physical

Superhydrophobic MOFs decorated on hierarchically micro/nanofibrous membranes for high-performance emulsified oily wastewater separation and cationic dyes adsorption

Ting Ying et al.

Summary: A hierarchically micro-patterned porous nanofibrous membrane with superhydrophobic metal-organic frameworks was successfully prepared for efficient separation of emulsified oily wastewater and cationic dye adsorption.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Physical

Intramolecular modulation of iron-based metal organic framework with energy level adjusting for efficient photocatalytic activity

Haoyun Chen et al.

Summary: By introducing sulfur particles into iron-based metal organic framework, the photocatalytic activity can be significantly enhanced, leading to a photocatalyst with higher apparent quantum efficiency. Computational studies reveal the electronic structure changes and charge transfer induced by sulfur modulation.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Review Engineering, Environmental

Efficient persistent organic pollutant removal in water using MIL-metal-organic framework driven Fenton-like reactions: A critical review

Malcom Frimpong Dapaah et al.

Summary: This review focuses on the application of metal-organic frameworks (MOFs) in the degradation of water pollutants, particularly the higher Fenton-like activity of MIL-MOFs towards persistent organic pollutants (POPs). The review examines the structural modification of MIL-MOF catalysts, the influence of reaction parameters, and discusses the practical applications and current situation of Fenton-like reactions. Challenges and future prospects are also provided to guide researchers in wastewater treatment and crystalline material application.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

Tuning the Sb(V) adsorption performance of La-MOFs via ligand engineering effect: Combined experiments with theoretical calculations

Deng You et al.

Summary: This study investigates the effect of ligand structure on the adsorption of Sb(V) by MOFs-based adsorbents. By synthesizing five different adsorbents with different ligands, the authors find that the adsorption performance is directly correlated with the utilization of accessible adsorption sites. The results show that La-MGs, with meta-substituted -COOH coordination and imidazole ring, achieve a site utilization rate of almost 92% and a state-of-the-art value of 896.5 mg/g for Sb(V) removal.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Environmental Sciences

Evaluation of the occurrence of antibiotics at different treatment stages of decentralised and conventional sewage treatment plants

C. X. Chen et al.

Summary: This study monitored and compared the fate of antibiotics in several sewage treatment plants in Johor Bahru, Malaysia, revealing that different treatment processes have varying effectiveness in removing different antibiotics, with biodegradation being the major route for removal.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2022)

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Article Engineering, Environmental

Understanding the mechanism of interfacial interaction enhancing photodegradation rate of pollutants at molecular level: Intermolecular π-π interactions favor electrons delivery

Qiang Zhang et al.

Summary: Uncovering the interaction between photocatalyst and reaction substrate, as well as the subsequent electron transfer process, is crucial for achieving effective photodegradation of pollutants. In this study, using the reduced density gradient (RDG) method, we simulated the pi-pi interactions between the photocatalyst g-C3N4 and the pollutant molecule FLU. The results showed that the pi-pi interactions between g-C3N4 and FLU facilitated electron delivery, leading to improved charge separation efficiency and direct oxidation of FLU. Furthermore, we found that the charge transfer rate was determined by the valence band level of g-C3N4 and the EHOMO of FLU, with a deeper valence band position favoring faster charge transfer and enhancing the photocatalytic degradation rate of FLU. Additionally, we proposed the possible degradation pathways of FLU through theoretical calculations and identified intermediates. Our work provides new insights into the degradation of pollutants and the rational design of highly efficient photocatalysts.

JOURNAL OF HAZARDOUS MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Tripolycyanamide-2,4,6-triformyl pyrogallol covalent organic frameworks with many coordination sites for detection and removal of heavy metal ions

Jiajia Han et al.

Summary: In this study, a highly crystalline covalent-organic framework based on imine linkages, COFTDBA-TPA, was prepared using TPA and TDBA for heavy metal ions (HMIs) detection and removal. The COFTDBA-TPA material had a large specific surface area and a mesoporous structure, allowing for selective and efficient adsorption of HMIs. The electrochemical sensor based on COFTDBA-TPA showed high sensitivity and low detection limits for Cd2+, Cu2+, Pb2+, Hg2+, and Zn2+ in drinking water. The COFTDBA-TPA adsorbent exhibited high adsorption capacity and fast kinetics, making it a reliable platform for wastewater treatment and suggesting potential applications in the electrochemical field.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2022)

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Article Materials Science, Multidisciplinary

Structure-performance correlation guided applications of covalent organic frameworks

Hou Wang et al.

Summary: This review provides an insightful understanding of COFs from a structural perspective and correlates them with their performance in practical applications. It addresses the synthesis challenges of COFs and discusses their structural and physicochemical properties in relation to different functions. Furthermore, it presents discussions on the correlation between structural characteristics of COFs and their performance in various fields, as well as future directions for function-oriented design and scalable production of COFs.

MATERIALS TODAY (2022)

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Review Materials Science, Multidisciplinary

UiO-66 metal-organic frameworks in water treatment: A critical review

Farhad Ahmadijokani et al.

Summary: Metal-organic frameworks (MOFs), particularly the UiO-66 family, have attracted attention for their potential applications in wastewater treatment due to their fascinating properties. This review focuses on the latest efforts in using UiO-66 MOFs as water-stable MOFs for efficient removal of various water pollutants, and addresses the possible mechanisms for adsorption/separation and degradation/reduction of water pollutants by UiO-66 and its modified derivatives.

PROGRESS IN MATERIALS SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Au3+-Functionalized UiO-67 Metal-Organic Framework Nanoparticles: O2•- and •OH Generating Nanozymes and Their Antibacterial Functions

Meng-Meng Pan et al.

Summary: In this study, the synthesis and characterization of Au3+-modified UiO-67 metal-organic framework nanoparticles were described. The Au3+-NMOFs showed dual oxidase-like and peroxidase-like activities, and acted as an effective catalyst for the generation of ROS agents for antibacterial and wound healing applications.

SMALL (2022)

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Article Chemistry, Multidisciplinary

Fabricating Industry-Compatible Olefin-Linked COF Resins for Oxoanion Pollutant Scavenging

Penghui Zhang et al.

Summary: This research successfully synthesized a series of highly crystalline covalent organic frameworks (COFs) using a melt polymerization method and demonstrated the kilogram-scale fabrication of robust foams. The resulting COFs are low-cost and can be conveniently transformed into ionic COFs, exhibiting highly efficient ion-exchange adsorption capacity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

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Article Chemistry, Physical

In-depth insight into the mechanism on photocatalytic synergistic removal of antibiotics and Cr (VI): The decisive effect of antibiotic molecular structure

Qiang Zhang et al.

Summary: In this study, a synergistic effect on the photocatalytic removal of antibiotics and hexavalent chromium (Cr (VI)) is achieved using ultra-thin g-C3N4. The mechanism of this synergistic effect is deeply studied at the molecular level through experiments and theoretical calculations. Antibiotics molecules are found to act as electron donors, accelerating the separation of photo-generated electron-hole pairs and increasing the participation of electrons/holes in the redox reaction. Another important finding is the linear relationship between the electron-donating capacity and the synergistic efficiency.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Chemistry, Physical

Rational design of donor-acceptor conjugated polymers with high performance on peroxydisulfate activation for pollutants degradation

Huinan Che et al.

Summary: This study successfully improved the activation ability of PDS by synthesizing a novel PCN/4-MI D-A conjugated polymer, providing a new design concept for highly efficient PDS activation.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Environmental

Tailoring delicate pore environment of 2D Covalent organic frameworks for selective palladium recovery

Yuling Zhao et al.

Summary: In this study, a series of bipyridine-based two-dimensional (2D) covalent organic frameworks (COFs) were constructed, and by tailoring the pore environment, TFBBPY-OMe-COF showed highly efficient adsorption and excellent selectivity for palladium recovery. Furthermore, it was successfully employed to capture Pd(II) in a simulated solution derived from waste printed circuit boards.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Engineering, Environmental

FeCo bimetallic metal organic framework nanosheets as peroxymonosulfate activator for selective oxidation of organic pollutants

Qiao Wang et al.

Summary: A FeCo-based bimetallic metal organic framework nanosheet was designed for selective oxidation of organics in water. The nanosheet exhibited high degradation efficiency and resistance to interference from co-existing dissolved species.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Insights into dual-functional modification for water stability enhancement of mesoporous zirconium metal-organic frameworks

Jian Liu et al.

Summary: This study examines the water stability of four node-modified variants of NU-1000, with Facac-NU-1000 showing the greatest water stability and ability for multiple water adsorption/desorption cycles. Computational studies reveal the dual functions of Facac ligands in enhancing mechanical stability and shielding hydrophilic nodes.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Multidisciplinary

Benchmark uranium extraction from seawater using an ionic macroporous metal-organic framework

Samraj Mollick et al.

Summary: Researchers have developed an efficient and selective adsorbent for extracting uranium from seawater, achieving high capacity and fast kinetics. This breakthrough has significant implications for large-scale uranium extraction from seawater.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

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Article Green & Sustainable Science & Technology

Impact of metal ions and organic ligands on uranium removal properties by zeolitic imidazolate framework materials

Yue Liu et al.

Summary: Highly porous zeolitic imidazolate frameworks were prepared for the elimination of U(VI) radionuclide, with ZIF-8 showing the best removal capacity due to its specific metal center and organic ligand. Batch experiments and DFT calculation provided insights into the interaction mechanisms of U(VI) onto ZIF-8.

JOURNAL OF CLEANER PRODUCTION (2021)

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Article Chemistry, Multidisciplinary

Tuning of Delicate Host-Guest Interactions in Hydrated MIL-53 and Functional Variants for Furfural Capture from Aqueous Solution

Na Cao et al.

Summary: By controlling the microenvironment and modifying hydrated MIL-53 with diversified terephthalic acid linkers, efficient capture of high-boiling-point furfural was achieved with high capture ratio and recovery rate.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Engineering, Environmental

Facile synthesis of sulfhydryl modified covalent organic frameworks for high efficient Hg(II) removal from water

Zhiyao Ma et al.

Summary: In this study, sulfhydryl modified covalent organic frameworks (COF--SH) were fabricated for efficient removal of Hg(II) from water. The COF--SH showed high adsorption capacity, fast adsorption kinetics, high selectivity and stability, as well as high Hg(II) removal efficiency under multiple coexisting ions conditions. The results suggest great potential for COF--SH in Hg(II) removal from water under complex conditions.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Applied

Hierarchically porous covalent organic framework for adsorption and removal of triphenylmethane dyes

Jichao Liu et al.

Summary: In this study, a hierarchically porous covalent organic framework foam (TbBd-foam) was fabricated using a simple gas-foaming technique to adsorb and remove two typical TPM dyes from aqueous solution. The foam showed efficient adsorption capacities for removing malachite green (MG) and crystal violet (CV) within 30 minutes, with high maximum adsorption capacities. Additionally, TbBd-foam could be easily recycled by treatment with an ethanol solution containing HCl (0.1%), making it a potential adsorbent for contaminated water remediation.

MICROPOROUS AND MESOPOROUS MATERIALS (2021)

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Review Engineering, Environmental

Designing clay-polymer nanocomposite sorbents for water treatment: A review and meta-analysis of the past decade

Itamar A. Shabtai et al.

Summary: This review presents the latest progress in CPN research through a meta-analysis approach, highlighting the correlation between CPN and pollutant properties. Results indicate that CPNs have higher adsorption capacities for different classes of pollutants, with adsorption being influenced by CPN fabrication method, polymer functional groups, and pollutant properties.

WATER RESEARCH (2021)

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Article Nanoscience & Nanotechnology

Rapid Removal of Perfluoroalkanesulfonates from Water by β-Cyclodextrin Covalent Organic Frameworks

Wei Wang et al.

Summary: In this study, four beta-cyclodextrin covalent organic frameworks (beta-CD-COFs) were developed as highly effective adsorbents for the removal of perfluoroalkanesulfonates (PFSAs) from water. These beta-CD-COFs exhibited rapid adsorption rates and high capacities for PFSAs, outperforming traditional materials. Density functional theory calculations showed high selectivity of beta-CD-COFs for PFSAs, highlighting their potential application as PFAS adsorbents with good reusability in water or wastewater treatment.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Review Chemistry, Multidisciplinary

Chemical Conversion and Locking of the Imine Linkage: Enhancing the Functionality of Covalent Organic Frameworks

Luca Cusin et al.

Summary: Imine-based COFs are functional, crystalline, and porous nanostructures with relatively easy crystallization, but the stability of the imine bond is limited, making it unsuitable for harsh conditions. Solutions are needed to increase the potential of these materials, potentially through chemical conversion and locking of the imine bond to enhance framework robustness and functionality.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Rational design of covalent organic frameworks as a groundbreaking uranium capture platform through three synergistic mechanisms

Wei-Rong Cui et al.

Summary: This study presents a method using covalent organic framework for the selective capture and reduction of uranium, achieving a high uranium capture capacity. DHBD-TMT shows efficient uranium adsorption in both dark and light conditions, with excellent photocatalytic activity.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

Accelerating Fe(III)/Fe(II) cycle via Fe(II) substitution for enhancing Fenton-like performance of Fe-MOFs

Taoyu Yang et al.

Summary: The Fenton-like performance of Fe-MOFs was improved by manipulating the structure of iron-oxo nodes with Fe(II) substitution, resulting in a material with stronger active sites and higher density of Fe(III) coordinatively unsaturated iron centers. This enhancement facilitated the rapid activation of H2O2 and efficient degradation of pollutants.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Review Chemistry, Applied

Starch, cellulose, pectin, gum, alginate, chitin and chitosan derived (nano) materials for sustainable water treatment: A review

Mahmoud Nasrollahzadeh et al.

Summary: Natural biopolymers, such as cellulose, chitin/chitosan, and starch, are considered greener, sustainable, and eco-friendly materials due to their outstanding structural features, abundant availability, nontoxicity, and biocompatibility. In recent years, polysaccharides have been widely used for making various catalysts, with polysaccharides-supported metal/metal oxide materials being an effective strategy in nanotechnology. Polysaccharides adorned with nanomaterials have shown promising potential as efficient catalysts or sorbents in removing a variety of aqueous pollutants and contaminants.

CARBOHYDRATE POLYMERS (2021)

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Article Engineering, Environmental

Covalent organic framework nanorods bearing single Cu sites for efficient photocatalysis

Zhiyue Dong et al.

Summary: By rationally designing novel Cu-coordinated COF nanostructures, this research has achieved efficient visible light absorption, complete electrons-holes separation, and enrichment of toxic organic compounds. The COF-909(Cu) nanorods demonstrated excellent performance in photocatalytic degradation, surpassing current state-of-the-art photocatalysts. Density functional theory calculations confirmed the structure-function relationship between the single Cu sites and the separation of electrons-holes, as well as the strong binding sites for target molecules.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

Recent advances in process engineering and upcoming applications of metal-organic frameworks

UnJin Ryu et al.

Summary: Progress in metal-organic frameworks (MOFs) has advanced to commercialization, but the diversity of individual goals has led to a variety of research approaches. This review examines the issues, demands, and recent advances in MOF commercialization, including criteria such as stability, producibility, regulations, and production cost.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Food Science & Technology

Effect of metal atom in zeolitic imidazolate frameworks (ZIF-8 & 67) for removal of Pb2+ & Hg2+ from water

Khalil Ahmad et al.

Summary: Heavy metals, such as lead and mercury, pose a major threat to underground water, and the construction of effective materials is crucial to mitigating water pollution. The synthesized MOFs in the study displayed excellent ability to remove lead and mercury, with high environmental remediation performance.

FOOD AND CHEMICAL TOXICOLOGY (2021)

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Article Chemistry, Multidisciplinary

Low Band Gap Benzoxazole-Linked Covalent Organic Frameworks for Photo-Enhanced Targeted Uranium Recovery

Wei-Rong Cui et al.

Summary: A series of robust and hydrophilic benzoxazole-based COFs have been developed as efficient adsorbents for targeted uranium recovery from seawater with improved stability, chemical reduction properties, and high uranium adsorption capacity compared to interfering metals like vanadium.

SMALL (2021)

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Review Environmental Sciences

Applications of chitosan in environmental remediation: A review

Preeti Pal et al.

Summary: Chitosan is a globally available biomaterial with advantages of availability, low cost, high biocompatibility, and biodegradability. Modifications have been made to expand its applications. It is widely used in environmental remediation and the demand for it is growing in the global industrial market.

CHEMOSPHERE (2021)

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Article Environmental Sciences

Ethylenediamine-functionalized Zr-based MOF for efficient removal of heavy metal ions from water

Farhad Ahmadijokani et al.

Summary: Ethylenediamine-functionalized Zr-based metal-organic framework (UiO-66-EDA) showed excellent adsorption capability for Pb(II), Cd(II), and Cu(II) metal ions, with adsorption behavior governed by pseudo-second-order kinetic and Langmuir isotherm models. The adsorption process depended on interactions between metal ions and the abundant functional groups on the UiO-66-EDA surface.

CHEMOSPHERE (2021)

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Article Materials Science, Multidisciplinary

Tunable molecular transport and sieving enabled by covalent organic framework with programmable surface charge

Weiwen Xin et al.

Summary: Researchers have fabricated a series of nanochannel membranes composed of uniform spherical COFs, which have different diameters and surface charge distribution, allowing for tunable water permeation and efficient separation of charged dyes.

MATERIALS TODAY (2021)

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Article Chemistry, Physical

Enhanced removal of pefloxacin from aqueous solution by adsorption and Fenton-like oxidation using NH2-MIL-88B

Huijing Ma et al.

Summary: The study used NH2-MIL-88B MOF to successfully remove ciprofloxacin from aqueous solution through adsorption and Fenton-like oxidation, suggesting the potential of NH2-MIL-88B in integrated adsorption and Fenton oxidation processes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Engineering, Environmental

Reuse of Predesigned Dual-Functional Metal Organic Frameworks (DF-MOFs) after Heavy Metal Removal

Leili Esrafili et al.

Summary: The systematic design of dual-functionalized metal organic frameworks for the removal of heavy metal ions from wastewater is crucial in environmental science. The creation of strong host-guest interactions between cations and donor sites significantly enhances heavy metals uptake. The engineered pore surface of MOFs provides a potential for multifunctional nanoparticles design to meet specific application requirements.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Engineering, Environmental

Thio-groups decorated covalent triazine frameworks for selective mercury removal

Zhenlian Yang et al.

Summary: In this study, three Covalent Triazine Frameworks (CTFs) decorated with S-groups were developed for selective removal of Hg2+ from aqueous solutions. Among them, MSCTF-2 showed the highest Hg2+ adsorption capacity, while MSCTF-1 exhibited exceptional efficiency for reducing Hg2+ concentration. The adsorption process followed pseudo-second-order kinetics and Langmuir isotherm, with adsorption capacities dependent on binding site density and distribution coefficient being essential to removal efficiency.

JOURNAL OF HAZARDOUS MATERIALS (2021)

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Article Chemistry, Physical

Synthesis and characterization of 1D-Co/Zn MOFs having potential for efficient dye adsorption from wastewater

Kirandeep et al.

Summary: Two stable Metal-organic frameworks, Co-MOF and Zn-MOF, were successfully synthesized by solvothermal method. Characterized by Single Crystal X-ray, thermogravimetric analysis and morphological studies, Co-MOF exhibited significantly good adsorption results for RB5 and MO under optimized conditions.

JOURNAL OF MOLECULAR STRUCTURE (2021)

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Article Engineering, Environmental

Tunable Covalent Organic Frameworks with Different Heterocyclic Nitrogen Locations for Efficient Cr(VI) Reduction, Escherichia coli Disinfection, and Paracetamol Degradation under Visible-Light Irradiation

Fuyang Liu et al.

Summary: This study synthesized five types of COFs with different nitrogen positions and found that the photocatalytic performance for Cr(VI) photoreduction, Escherichia coli inactivation, and paracetamol degradation varied depending on the nitrogen locations. COF-PDZ showed the best performance due to improved quantum efficiency, lower energy barriers, larger energy gaps, and stronger affinity to Cr(VI). COF-PDZ also demonstrated great stability through multiple regeneration and reuse cycles.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2021)

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Article Materials Science, Multidisciplinary

Novel sulfhydryl functionalized covalent organic frameworks for ultra-trace Hg2+ removal from aqueous solution

Fei Pan et al.

Summary: Two novel sulfhydryl functionalized covalent organic frameworks, COF-SH-1 and COF-SH-2, were successfully fabricated for the efficient removal of Hg(2+) from water, showing excellent performance even at ultra-trace concentrations. The high sulfur content in the material structure is crucial for the selective binding of Hg(2+), indicating promising potential for environmental detection of heavy metals.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

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Article Multidisciplinary Sciences

Molecularly soldered covalent organic frameworks for ultrafast precision sieving

Yanqiu Zhang et al.

Summary: Defect-free ultrathin COF membranes with precise sieving abilities were fabricated using an in situ molecularly soldered strategy, in which dopamine was utilized to repair defects in stacked COF crystals, enhancing the mechanical properties. The COF membranes exhibited ultrafast precision sieving for molecular separation and ion removal in both aqueous and organic solvents, surpassing state-of-the-art membranes.

SCIENCE ADVANCES (2021)

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Review Chemistry, Multidisciplinary

A Review of MOFs and Their Composites-Based Photocatalysts: Synthesis and Applications

Yongteng Qian et al.

Summary: MOFs-based photocatalysts have unique morphology, high performance, stability, easy synthesis, and low cost. This review introduces synthetic strategies, summarizes various types of MOFs composite photocatalysts, and highlights different applications of MOFs-based photocatalysts.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Review Biochemistry & Molecular Biology

The Surge of Metal-Organic-Framework (MOFs)-Based Electrodes as Key Elements in Electrochemically Driven Processes for the Environment

Abdoulaye Thiam et al.

Summary: This review highlights the use of Metal-organic-frameworks (MOFs) in environmental electrochemistry, showcasing their superior performance compared to traditional materials in various water remediation technologies. It discusses the synthesis of MOFs and their application in different degradation reactions, as well as provides perspectives for the future development of MOF-derived materials in electrified water treatment.

MOLECULES (2021)

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Article Chemistry, Physical

Hydrophilicity gradient in covalent organic frameworks for membrane distillation

Shuang Zhao et al.

Summary: The study proposes a strategy to modify covalent organic framework membranes by engineering defects to create vertically aligned channels with a hydrophilicity gradient, allowing for high flux membrane distillation membranes. This method offers advantages in increasing membrane permeance and anti-fouling and anti-wetting properties.

NATURE MATERIALS (2021)

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Review Engineering, Environmental

Emerging graphitic carbon nitride-based membranes for water purification

Yuqi Cui et al.

Summary: Membrane separation is a promising technology for removing water contaminants with low energy consumption and small carbon footprint. Graphitic carbon nitride (g-C3N4) has emerged as a promising membrane material due to its unique structure and catalytic activity. The integration of physical separation, catalysis, and energy conversion during water purification using g-C3N4-based membranes is essential for sustainability. Challenges and future research directions for g-C3N4-based membranes were also discussed in the review.

WATER RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Highly Efficient Degradation of Linear Alkylbenzene Sulfonate Surfactant by MIL-53 (Fe) Metal Organic Framework Derived Electro-Fenton Applicable in Water Treatments

Javad Ghodsi et al.

Summary: The study demonstrates that MIL-53 (Fe) metal-organic framework has efficient catalytic action in the Electro-Fenton degradation of LAS surfactant, with significantly improved degradation rate in the presence of Fe MOF. By optimizing experimental parameters, MOF efficiently removes LAS in a short period of time, meeting the removal requirements for LAS.

CHEMISTRYSELECT (2021)

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Review Chemistry, Inorganic & Nuclear

Post-synthetic modifications (PSM) on metal-organic frameworks (MOFs) for visible-light-initiated photocatalysis

Yuhuan Qin et al.

Summary: Utilizing solar energy through photocatalysis is a promising strategy for addressing energy shortages and environmental issues. Metal-organic frameworks (MOFs) are emerging as a new type of photocatalytic material, with post-synthetic modifications (PSM) being a powerful strategy for fabricating photoactive MOFs based on existing MOFs. Various PSM strategies, including coordination on unsaturated metal sites, metalation on open coordinated sites, and ligand exchange, have been summarized for the development of photoactive MOFs.

DALTON TRANSACTIONS (2021)

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Review Environmental Sciences

Review of organic and inorganic pollutants removal by biochar and biochar-based composites

Liping Liang et al.

Summary: This article reviewed the application of biochar (BC) and BC-based composite materials in water treatment, including preparation methods, properties, pollutant removal efficiency, and adsorption mechanisms. BC and BC-based composite materials show good performance in removing inorganic and organic pollutants, but also face potential risks such as stability and biological toxicity.

BIOCHAR (2021)

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Review Environmental Sciences

Hotpots and trends of covalent organic frameworks (COFs) in the environmental and energy field: Bibliometric analysis

Lin Niu et al.

Summary: Covalent organic frameworks (COFs) have garnered extensive attention in the environmental and energy fields due to their low density, adjustable structure, functionalization, and stability. Research on COFs shows rapid growth, with active countries including USA, Germany, Japan, China, and India. Research hotspots include synthesis, adsorption, catalysis, membrane, sensor, and energy storage, with challenges such as improving preparation methods for mass production and addressing the imbalance in environmental applications.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Article Materials Science, Multidisciplinary

Machine learning the quantum-chemical properties of metal-organic frameworks for accelerated materials discovery

Andrew S. Rosen et al.

Summary: This study introduces a Quantum MOF (QMOF) database, which contains computed quantum-chemical properties for over 14,000 experimentally synthesized MOFs. Machine learning models trained on this database can efficiently discover MOFs with targeted properties, with the successful prediction of MOFs with low band gaps being highlighted.

MATTER (2021)

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Article Chemistry, Multidisciplinary

Tetrathiafulvalene-based covalent organic frameworks for ultrahigh iodine capture

Jianhong Chang et al.

Summary: The study reports the synergistic effect of physical and chemical adsorption of iodine in tetrathiafulvalene-based covalent organic frameworks (COFs), achieving significant improvement in iodine adsorption capacity and kinetics. These functionalized COFs with high specific surface areas and abundant tetrathiafulvalene functional groups demonstrate excellent iodine adsorption performance, surpassing other reported materials. The research provides insight into the strong chemical interaction between iodine and the COFs, offering a promising approach for constructing COFs for critical environmental applications.

CHEMICAL SCIENCE (2021)

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Article Materials Science, Multidisciplinary

Robust Hilly Polyamide Membrane for Fast Desalination

Shasha Liu et al.

Summary: A highly porous thin-film composite (TFC) polyamide (PA) membrane was developed by integrating water-stable, highly crystalline submicrometer-sized MOF crystals with CNFs, showing excellent water permeance and NaCl rejection, demonstrating great potential for enhanced flux and mechanical stability in polyamide desalination membranes.

ACS APPLIED POLYMER MATERIALS (2021)

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Article Chemistry, Inorganic & Nuclear

A two-year water-stable 2D MOF with aqueous NIR photothermal conversion ability

Xiang Xue et al.

Summary: Improving water stability of MOFs by using three-dimensional rigid shielding ligands is a promising strategy. The synthesized CuCP-MOF shows high stability in water, strong NIR absorption, and efficient NIR photothermal conversion in aqueous dispersions.

DALTON TRANSACTIONS (2021)

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Article Chemistry, Multidisciplinary

Predicting the bulk modulus of single-layer covalent organic frameworks with square-lattice topology from molecular building-block properties

Antonios Raptakis et al.

Summary: In this study, the elasticity of different single-layer tetrabenzoporphyrin (H2-TBPor) and phthalocyanine (H2-Pc) based 2D COFs was numerically investigated using a density-functional based tight-binding approach. By calculating the 2D bulk modulus and equivalent spring constants of the molecular building blocks, the researchers were able to predict the 2D bulk modulus based on the properties of the isolated molecules, offering a pathway to optimize the elastic properties of 2D COFs.

NANOSCALE (2021)

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Review Chemistry, Multidisciplinary

The rise of metal-organic polyhedra

Soochan Lee et al.

Summary: Metal-organic polyhedra, as a type of metal-organic material, are emerging porous platforms used in energy and bio-related sciences, but have been less explored compared to their framework counterparts. This review covers the topologies and classification of metal-organic polyhedra and provides suggestions for future directions in this rapidly growing field that may benefit synthetic chemists.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Computer Science, Artificial Intelligence

Inverse design of nanoporous crystalline reticular materials with deep generative models

Zhenpeng Yao et al.

Summary: Reticular frameworks are crystalline porous materials that have desirable properties for various applications, but the diversity of building blocks presents challenges for materials design. An automated nanoporous materials discovery platform powered by a supramolecular variational autoencoder is proposed for generative design of reticular materials, showing high fidelity in capturing structural features and promising optimization capability for gas separation.

NATURE MACHINE INTELLIGENCE (2021)

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Article Nanoscience & Nanotechnology

Superhydrophobic Covalent Organic Frameworks Prepared via Pore Surface Modifications for Functional Coatings under Harsh Conditions

Na Han et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Environmental

Interfacial polymerized and pore-variable covalent organic framework composite membrane for dye separation

Ting Wang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Environmental

Construction of highly water-stable metal-organic framework UiO-66 thin-film composite membrane for dyes and antibiotics separation

Si-Yuan Fang et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Nanoscience & Nanotechnology

Machine Learning Enabled Tailor-Made Design of Application-Specific Metal-Organic Frameworks

Xiangyu Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

A Water-Stable Ionic MOF for the Selective Capture of Toxic Oxoanions of SeVI and AsV and Crystallographic Insight into the Ion-Exchange Mechanism

Shivani Sharma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Engineering, Environmental

A metal organic framework-ultrafiltration hybrid system for removing selected pharmaceuticals and natural organic matter

Sewoon Kim et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Environmental Sciences

Iron-copper bimetallic metal-organic frameworks for efficient Fenton-like degradation of sulfamethoxazole under mild conditions

Juntao Tang et al.

CHEMOSPHERE (2020)

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Article Engineering, Environmental

Covalent organic frameworks as efficient adsorbent for sulfamerazine removal from aqueous solution

Shuting Zhuang et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Engineering, Chemical

Multifunctional thin-film nanocomposite membranes comprising covalent organic nanosheets with high crystallinity for efficient reverse osmosis desalination

Lina Xu et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Rapid, Scalable Construction of Highly Crystalline Acylhydrazone Two-Dimensional Covalent Organic Frameworks via Dipole-Induced Antiparallel Stacking

Xing Li et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Materials Science, Multidisciplinary

Robust natural nanocomposites realizing unprecedented ultrafast precise molecular separations

Yanqiu Zhang et al.

MATERIALS TODAY (2020)

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Article Engineering, Chemical

Highly efficient adsorption of iodine under ultrahigh pressure from aqueous solution

Rong Liu et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2020)

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Article Chemistry, Physical

Fe-based metal-organic frameworks as Fenton-like catalysts for highly efficient degradation of tetracycline hydrochloride over a wide pH range: Acceleration of Fe(II)/Fe(III) cycle under visible light irradiation

Qiangshun Wu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Engineering, Chemical

Novel Triazine-Based Covalent Organic Framework as a Superadsorbent for the Removal of Mercury(II) from Aqueous Solutions

Mohaddeseh Afshari et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Engineering, Environmental

In situ photoreduction of structural Fe(III) in a metal-organic framework for peroxydisulfate activation and efficient removal of antibiotics in real wastewater

Renli Yin et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Nanoscience & Nanotechnology

In Situ Ag-MOF Growth on Pre-Grafted Zwitterions Imparts Outstanding Antifouling Properties to Forward Osmosis Membranes

Mehdi Pejman et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Environmental

In-situ growing of metal-organic frameworks on three-dimensional iron network as an efficient adsorbent for antibiotics removal

Weixiang Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Review Chemistry, Multidisciplinary

Big-Data Science in Porous Materials: Materials Genomics and Machine Learning

Kevin Maik Jablonka et al.

CHEMICAL REVIEWS (2020)

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Article Engineering, Environmental

Rapid degradation of tetracycline hydrochloride by heterogeneous photocatalysis coupling persulfate oxidation with MIL-53(Fe) under visible light irradiation

Ying Zhang et al.

JOURNAL OF HAZARDOUS MATERIALS (2020)

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Article Nanoscience & Nanotechnology

Effects of Phase Purity and Pore Reinforcement on Mechanical Behavior of NU-1000 and Silica-Infiltrated NU-1000 Metal-Organic Frameworks

Zhao Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Chemical

Secondary growth of covalent organic frameworks (COFs) on porous substrates for fast desalination

Rui Wang et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Article Engineering, Chemical

Thin-film nanocomposite membranes incorporated with UiO-66-NH2 nanoparticles for brackish water and seawater desalination

Die Ling Zhao et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Article Materials Science, Ceramics

Enhanced sonocatalytic degradation of recalcitrant organic contaminants using a magnetically recoverable Ag/Fe-loaded activated biochar composite

Byung-Moon Jun et al.

CERAMICS INTERNATIONAL (2020)

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Article Engineering, Environmental

A remarkable adsorbent for removal of bisphenol S from water: Aminated metal-organic framework, MIL-101-NH2

Jong Min Park et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Highly efficient and selective removal of Cr(VI) by covalent organic frameworks: Structure, performance and mechanism

Donghai Zhu et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

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Article Engineering, Chemical

Thin-film nanocomposite membrane doped with carboxylated covalent organic frameworks for efficient forward osmosis desalination

Lina Xu et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Article Engineering, Chemical

Improved antifouling and antibacterial properties of forward osmosis membranes through surface modification with zwitterions and silver-based metal organic frameworks

Mehdi Pejman et al.

JOURNAL OF MEMBRANE SCIENCE (2020)

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Review Engineering, Environmental

Recent advances in application of graphitic carbon nitride-based catalysts for degrading organic contaminants in water through advanced oxidation processes beyond photocatalysis: A critical review

Yang Yang et al.

WATER RESEARCH (2020)

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Review Chemistry, Multidisciplinary

Digital Reticular Chemistry

Hao Lyu et al.

CHEM (2020)

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Article Chemistry, Multidisciplinary

Easily Constructed Imine-Bonded COFs for Iodine Capture at Ambient Temperature

Yonghe Sun et al.

ACS OMEGA (2020)

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Review Chemistry, Multidisciplinary

The Role of Machine Learning in the Understanding and Design of Materials

Seyed Mohamad Moosavi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Construction of covalent organic framework with unique double-ring pore for size-matching adsorption of uranium

Jie Zhang et al.

NANOSCALE (2020)

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Article Computer Science, Artificial Intelligence

Prediction of water stability of metal-organic frameworks using machine learning

Rohit Batra et al.

NATURE MACHINE INTELLIGENCE (2020)

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Article Chemistry, Multidisciplinary

Syntheses of two- and three-dimensional covalent organic frameworks in deep eutectic solvents

Jikuan Qiu et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Intramolecular hydrogen bond-induced high chemical stability of metal-organic frameworks

Keke Wang et al.

INORGANIC CHEMISTRY FRONTIERS (2020)

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Article Engineering, Chemical

Incorporation of lysine-modified UiO-66 for the construction of thin-film nanocomposite nanofiltration membrane with enhanced water flux and salt selectivity

Zhengyang Gu et al.

DESALINATION (2020)

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Article Chemistry, Multidisciplinary

Water stability of cobalt doped ZIF-8: a quantitative study using optical analyses

M. Taheri et al.

MATERIALS TODAY CHEMISTRY (2020)

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Article Chemistry, Physical

A knot-linker planarity control strategy for constructing highly crystalline cationic covalent organic frameworks: decoding the effect of crystallinity on adsorption performance

Hong-Ju Da et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Multidisciplinary Sciences

Postsynthetic functionalization of covalent organic frameworks

Yusran Yusran et al.

NATIONAL SCIENCE REVIEW (2020)

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Article Biodiversity Conservation

Blending antibiotic resistance into environmental risk assessment of antibiotics: A case study in coastal waters of the Bohai Bay, China

Yongpeng Zhang et al.

HUMAN AND ECOLOGICAL RISK ASSESSMENT (2019)

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Article Chemistry, Physical

Understanding the adsorption of sulfonamide antibiotics on MIL-53s: Metal dependence of breathing effect and adsorptive performance in aqueous solution

Yanxin Gao et al.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2019)

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Article Engineering, Environmental

Hormones and Pharmaceuticals in Groundwater Used As a Source of Drinking Water Across the United States

Laura M. Bexfield et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2019)

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Article Engineering, Environmental

MIL-PVDF blend ultrafiltration membranes with ultrahigh MOF loading for simultaneous adsorption and catalytic oxidation of methylene blue

Yi Ren et al.

JOURNAL OF HAZARDOUS MATERIALS (2019)

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Article Multidisciplinary Sciences

Capturing chemical intuition in synthesis of metal-organic frameworks

Seyed Mohamad Moosavi et al.

NATURE COMMUNICATIONS (2019)

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Review Chemistry, Multidisciplinary

Detection and removal of heavy metal ions: a review

Lateef Ahmad Malik et al.

ENVIRONMENTAL CHEMISTRY LETTERS (2019)

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Article Chemistry, Multidisciplinary

2D sp2 Carbon-Conjugated Covalent Organic Frameworks for Photocatalytic Hydrogen Production from Water

Enquan Jin et al.

CHEM (2019)

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Article Engineering, Chemical

In-situ grown covalent organic framework nanosheets on graphene for membrane-based dye/salt separation

Xuke Zhang et al.

JOURNAL OF MEMBRANE SCIENCE (2019)

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Article Chemistry, Multidisciplinary

Ligand Rigidification for Enhancing the Stability of Metal-Organic Frameworks

Xiu-Liang Lv et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Engineering, Environmental

Coupling of heterogeneous advanced oxidation processes and photocatalysis in efficient degradation of tetracycline hydrochloride by Fe-based MOFs: Synergistic effect and degradation pathway

Ying Zhang et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Engineering, Environmental

Removal of contaminants of emerging concern by metal-organic framework nanoadsorbents: A review

Lesley Joseph et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Environmental Sciences

Comprehensive evaluation on removal of lead by graphene oxide and metal organic framework

Byung-Moon Jun et al.

CHEMOSPHERE (2019)

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Review Chemistry, Inorganic & Nuclear

Hybrid materials for heterogeneous photocatalytic degradation of antibiotics

Mario J. F. Calvete et al.

COORDINATION CHEMISTRY REVIEWS (2019)

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Review Environmental Sciences

Carbon-based magnetic nanocomposite as catalyst for persulfate activation: a critical review

Ya Pang et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2019)

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Article Engineering, Chemical

Unidirectional diffusion synthesis of covalent organic frameworks (COFs) on polymeric substrates for dye separation

Rui Wang et al.

JOURNAL OF MEMBRANE SCIENCE (2019)

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Article Chemistry, Applied

Exploration of functional MOFs for efficient removal of fluoroquinolone antibiotics from water

Xiangyu Guo et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2019)

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Review Environmental Sciences

Occurrence, fate and risk assessment of BPA and its substituents in wastewater treatment plant: A review

Yu Hu et al.

ENVIRONMENTAL RESEARCH (2019)

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Article Engineering, Environmental

Hydrophilic Selective Nanochannels Created by Metal Organic Frameworks in Nanofiltration Membranes Enhance Rejection of Hydrophobic Endocrine-Disrupting Compounds

Ruobin Dai et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2019)

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Article Engineering, Chemical

Aluminum fumarate MOF/PVDF hollow fiber membrane for enhancement of water flux and thermal efficiency in direct contact membrane distillation

Dongjian Cheng et al.

JOURNAL OF MEMBRANE SCIENCE (2019)

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Article Multidisciplinary Sciences

Microbial reduction of metal-organic frameworks enables synergistic chromium removal

Sarah K. Springthorpe et al.

NATURE COMMUNICATIONS (2019)

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Article Engineering, Environmental

Robust photocatalytic reduction of Cr(VI) on UiO-66-NH2(Zr/Hf) metal-organic framework membrane under sunlight irradiation

Xue-Dong Du et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Review Chemistry, Inorganic & Nuclear

Covalent organic frameworks (COFs) for environmental applications

Jianlong Wang et al.

COORDINATION CHEMISTRY REVIEWS (2019)

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Article Materials Science, Multidisciplinary

Common but differentiated flexible MIL-53(Al): role of metal sources in synthetic protocol for tuning the adsorption characteristics

Lingyu Feng et al.

JOURNAL OF MATERIALS SCIENCE (2019)

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Article Green & Sustainable Science & Technology

Green development performance of water resources and its economic-related determinants

Wei Li et al.

JOURNAL OF CLEANER PRODUCTION (2019)

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Review Environmental Sciences

A review on novel composites of MWCNTs mediated semiconducting materials as photocatalysts in water treatment

Kranthi Kumar Gangu et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2019)

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Article Chemistry, Physical

Post-synthesis of a covalent organic framework nanofiltration membrane for highly efficient water treatment

Chuanyao Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Solvent- and catalyst-free synthesis of an azine-linked covalent organic framework and the induced tautomerization in the adsorption of U(vi) and Hg(II)

Xing Li et al.

GREEN CHEMISTRY (2019)

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Article Materials Science, Multidisciplinary

Structure-Mechanical Stability Relations of Metal-Organic Frameworks via Machine Learning

Peyman Z. Moghadam et al.

MATTER (2019)

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Article Chemistry, Physical

Covalent organic framework-modulated interfacial polymerization for ultrathin desalination membranes

Jinqiu Yuan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Multidisciplinary

Post-synthetic modification of covalent organic frameworks

Jose L. Segura et al.

CHEMICAL SOCIETY REVIEWS (2019)

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Article Chemistry, Physical

MOF-positioned polyamide membranes with a fishnet-like structure for elevated nanofiltration performance

Junyong Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Review Chemistry, Multidisciplinary

Covalent Organic Frameworks and Cage Compounds: Design and Applications of Polymeric and Discrete Organic Scaffolds

Florian Beuerle et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Applied

Regulation of the surface area and surface charge property of MOFs by multivariate strategy: Synthesis, characterization, selective dye adsorption and separation

Tian-Tian Li et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2018)

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Article Engineering, Chemical

TMU-5 metal-organic frameworks (MOFs) as a novel nanofiller for flux increment and fouling mitigation in PES ultrafiltration membrane

F. Gholami et al.

SEPARATION AND PURIFICATION TECHNOLOGY (2018)

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Article Nanoscience & Nanotechnology

Stable Covalent Organic Frameworks as Efficient Adsorbents for High and Selective Removal of an Aryl-Organophosphorus Flame Retardant from Water

Wei Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Article Engineering, Environmental

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Postsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Exposure to pesticides and the associated human health effects

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SCIENCE OF THE TOTAL ENVIRONMENT (2017)

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Internal pore decoration with polydopamine nanoparticle on polymeric ultrafiltration membrane for enhanced heavy metal removal

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CHEMICAL ENGINEERING JOURNAL (2017)

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Development of a Cambridge Structural Database Subset: A Collection of Metal-Organic Frameworks for Past, Present, and Future

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Selective and Efficient Removal of Mercury from Aqueous Media with the Highly Flexible Arms of a BioMOF

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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A polycationic covalent organic framework: a robust adsorbent for anionic dye pollutants

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POLYMER CHEMISTRY (2016)

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Review Chemistry, Inorganic & Nuclear

Synthesis of metal-organic frameworks (MOFs) with microwave or ultrasound: Rapid reaction, phase-selectivity, and size reduction

Nazmul Abedin Khan et al.

COORDINATION CHEMISTRY REVIEWS (2015)

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Review Engineering, Chemical

A comprehensive review on surface modified polymer membranes for biofouling mitigation

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DESALINATION (2015)

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Self-templated chemically stable hollow spherical covalent organic framework

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NATURE COMMUNICATIONS (2015)

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Review Chemistry, Multidisciplinary

Water Stability and Adsorption in Metal-Organic Frameworks

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Article Engineering, Environmental

Comparison of Halide Impacts on the Efficiency of Contaminant Degradation by Sulfate and Hydroxyl Radical-Based Advanced Oxidation Processes (AOPs)

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ENVIRONMENTAL SCIENCE & TECHNOLOGY (2014)

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Large-Scale Quantitative Structure-Property Relationship (QSPR) Analysis of Methane Storage in Metal-Organic Frameworks

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JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Imidazoles as Promising Scaffolds for Antibacterial Activity: A Review

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MINI-REVIEWS IN MEDICINAL CHEMISTRY (2013)

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Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates

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JOURNAL OF HAZARDOUS MATERIALS (2010)

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Characterization of metal-organic frameworks by water adsorption

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MICROPOROUS AND MESOPOROUS MATERIALS (2009)

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Semiconductor behavior of a metal-organic framework (MOF)

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Porous, crystalline, covalent organic frameworks

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SCIENCE (2005)

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Development of a high performance electrochemical wastewater treatment system

C Feng et al.

JOURNAL OF HAZARDOUS MATERIALS (2003)

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Review Chemistry, Inorganic & Nuclear

Monomeric and extended oxo-centered triruthenium clusters

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Highly porous and stable metal-organic frameworks: Structure design and sorption properties

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