4.6 Article

Preparation of SiO2/rGO/CNTs composite and application for lithium-ion- battery anodes

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MATERIALS LETTERS
卷 353, 期 -, 页码 -

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ELSEVIER
DOI: 10.1016/j.matlet.2023.135300

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SiO2; Carbon materials; Carbon nanotubes; Lithium-ion batteries; Energy storage and conversion

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SiO2/rGO/CNTs composite was fabricated to mitigate the volume expansion of SiO2 during charging and discharging processes, resulting in significant improvement of electrochemical performances.
To mitigate the volume expansion of SiO2 during the processes of charging and discharging, SiO2/rGO/CNTs composite was fabricated as lithium-ion-battery anode. Within this composite, CNTs are dispersed on the flexible rGO, serving as the supporting framework and conductive bridge of SiO2/rGO. This unique arrangement effectively mitigates the volume expansion of SiO2 as well as concurrently enhances its conductivity, resulting in significant improvement of electrochemical performances. As a result, the SiO2/rGO/CNTs anode exhibits an initial discharge capacity of 1521 mA h g-1, with a sustained capacity of 612 mA h g-1 after 200 cycles at 1 A g-1.

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