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Sterically demanding binaphthol-based chiral diboranes for metal-free and isotactic poly(propylene oxide)

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CHEMICAL COMMUNICATIONS
卷 59, 期 74, 页码 11069-11072

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02889e

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This article presents chiral diborane polymerization catalysts with 3,30-disubstituted binaphthol-backbones. These compounds deliver isotactic poly(propylene oxide) with high isotactic diad (m) and triad (mm) placements of up to 92% and 480%, respectively, from racemic monomer.
Chiral diborane polymerization catalysts with 3,30-disubstituted binaphthol-backbones are presented. These compounds deliver isotactic poly(propylene oxide) from racemic monomer with isotactoc diad (m) and triad (mm) placements of up to 92% and 480%, respectively. The resulting polyether is well-defined, of high molar mass and semi-crystalline.

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