Photoinduced large magnetic change at room temperature and radical-quenched spin glass in a cyanide-bridged MnII-FeIII compound

By the coordination assembly of a redox photoactive functional motif and a cyanide-bridged moiety, a cyanide-bridged Mn-II-Fe-III compound with large photoinduced magnetic change at room-temperature due to photoinduced electron transfer was obtanied. This compound also shows unprecedented radical-quenched spin glass in molecule based magnets.

Automated summary

By coordinating a redox photoactive functional motif with a cyanide-bridged moiety, a cyanide-bridged Mn-II-Fe-III compound with significant photoinduced magnetic change at room temperature has been obtained. This compound also exhibits an unprecedented radical-quenched spin glass behavior in molecule based magnets.