One-step floating conversion of biomass into highly graphitized and continuous carbon nanotube yarns

The rapid growth of the demand for carbon nanotubes (CNTs) has greatly promoted their large-scale synthesis and development. However, the continuous production of CNT fibers by floating catalyst chemical vapor deposition (FCCVD) requires a large amount of non-renewable carbon sources. Here, the continuous production of highly graphitized CNT yarns from biomass tannic acid (TA) is reported. The chelation of TA and catalyst promotes the rapid cracking of biomass into carbon source gas, and the pyrolysis cracking produces the reducing gas, which solves the problems of the continuous production of CNT yarns using biomass. Through simple twisting, the mechanical strength of CNT yarn can reach 886 +/- 46 MPa, and the electrical conductivity and graphitization (IG/ID) can reach 2 x 105 S m-1 and 6.3, respectively. This work presents a promising solution for the continuous preparation of CNT yarns based on green raw material.(c) 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communi-cations Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

This study presents a promising solution for the continuous production of highly graphitized CNT yarns using biomass tannic acid, solving the problem of continuous production and showcasing the excellent performance of CNT yarns.