4.2 Review

Response surface methodology: a powerful tool for optimizing the synthesis of metal sulfide nanoparticles for dye degradation

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The effect of PEGylation on optical and structural properties of ZnO nanostructures for photocatalyst and photodynamic applications

Somayeh Sheikhi et al.

Summary: In this study, bare and pegylated ZnO nanoparticles were successfully synthesized using the sol-gel method. The effects of pegylation on the optical and structural properties of the ZnO nanoparticles were investigated. The results showed that pegylation changed the morphology of the nanoparticles and significantly reduced their size. It also affected the optical properties, leading to higher reflectance and a blue shift in the bandgap energies. The photocatalytic activities of the nanoparticles were studied, and it was found that pegylated ZnO nanoparticles exhibited better photodegradation of methylene blue dye compared to bare ZnO nanoparticles, especially in acidic solutions. The kinetics of the photocatalytic degradation were also examined.

MATERIALS TODAY COMMUNICATIONS (2023)

Article Materials Science, Ceramics

Development of highly efficient cost-effective CdS/Ag nanocomposite for removal of azo dyes under UV and solar light

S. Ravikumar et al.

Summary: Water pollution by toxic dyes is a serious environmental problem. A new green technology using CdS/Ag nanocomposite as a photocatalyst has shown outstanding efficiency in degrading toxic dyes under ultraviolet and direct solar light.

CERAMICS INTERNATIONAL (2023)

Article Engineering, Environmental

ZnInGaS4 heterojunction with sulfide vacancies for efficient solar-light photocatalytic water splitting and Cr(VI) reduction

Hao Peng et al.

Summary: A ZnInGaS4 heterojunction with S vacancies was prepared to enhance solar-light photocatalytic activity for water splitting and Cr(VI) reduction. The optimized ZnInGaS4 exhibited higher H2 evolution rate and better efficiency for Cr(VI) reduction compared to ZnIn2S4 and ZnGa2S4.

CHEMICAL ENGINEERING JOURNAL (2023)

Review Chemistry, Multidisciplinary

Recent Advances of Core-Shell Cu-Based Catalysts for the Reduction of CO2 to C2+ Products

Lamei Li et al.

Summary: This review focuses on the application of Cu-based core-shell catalysts in CO2 reduction. The unique electronic structure and interface environment of the core-shell structure can effectively promote the C-C coupling process. The design of efficient Cu-based core-shell catalysts is of great significance for electrocatalytic CO2 reduction (CO2RR).

CHEMISTRY-AN ASIAN JOURNAL (2023)

Article Environmental Sciences

Comparative studies of RSM Box-Behnken and ANN-Anfis fuzzy statistical analysis for seawater biodegradability using TiO2 photocatalyst

Nayeemuddin Mohammed et al.

Summary: In this study, the degradation of pollutants under natural sunlight using TiO2 as a photocatalyst was investigated in a batch reactor. The effects of photocatalyst dosage, reaction time, and pH on the removal of pollutants were evaluated. Design Expert-Response Surface Methodology Box Behnken Design (RSM-BBD) and MATLAB Artificial Neural Network - Adaptive Neuro Fuzzy Inference System (ANN-ANFIS) methods were used for statistical modeling. Both models showed good prediction compared to experimental values, with R2 values of 0.920 for RSM-BBD and 0.990 for ANN-ANFIS.

CHEMOSPHERE (2023)

Article Chemistry, Physical

Construction of step-scheme g-C3N4/Co/ZnO heterojunction photocatalyst for aerobic photocatalytic degradation of synthetic wastewater

Harikrishnan Leelavathi et al.

Summary: This study presents the utilization of ternary g-C3N4/Co/ZnO heterojunction photocatalyst for dye degradation. g-C3N4/Co/ZnO nanocomposite was synthesized using a simple ultrasonic and sol-gel method. The physico-chemical characteristics were analyzed to determine the structural properties and the efficiency of photogenerated electron-holes. The S-scheme g-C3N4/Co/ZnO photocatalyst showed high efficiency in the degradation of cationic dyes under visible light irradiation. The presence of metallic Cobalt nanoparticles enhanced the electron transport and the responsiveness of the photocatalyst to sunlight.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2023)

Article Electrochemistry

FeCoS2/Co4S3/N-doped graphene composite as efficient electrocatalysts for overall water splitting

Shuliang Wang et al.

Summary: In this study, FeCoS2/Co4S3 nanoparticles were synthesized and loaded on nitrogen-doped graphene foam to form a 3D network structure. The resulting hybrid catalyst exhibited outstanding electrocatalytic performance and has great potential for large-scale water electrolysis.

ELECTROCHIMICA ACTA (2023)

Article Chemistry, Inorganic & Nuclear

Synthesis and characterization of GA-AgNPs for highly sensitive and selective dual colorimetric detection of thiourea and thiophenol with DFT approach

Maga Nana Kaka et al.

Summary: This work presents a simple and cost-effective method of synthesizing gallic acid-based silver nanoparticles for the detection of soil pollutants. The nanoparticles were characterized using various techniques and used as a colorimetric sensor for thiourea (TU) and thiophenol (TP) in real soil samples. The colorimetric detection showed a good linear relationship and a low limit of detection. A smartphone application was also utilized to track color intensity changes. The synthesized nanoparticles demonstrated excellent selectivity and were validated using HPLC.

INORGANIC CHEMISTRY COMMUNICATIONS (2023)

Article Chemistry, Physical

Synthesize and characterization of copper doped nickel ferrite nanoparticles effect on magnetic properties and visible light catalysis for rhodamine dye degradation mechanism

M. Sukumar et al.

Summary: Copper doped NiFe2O4 spinel nanoparticles were prepared by a facile microwave combustion method. The addition of Cu induced the formation of secondary alpha-Fe2O3 phase and resulted in changes in the surface properties. The Cu-doping significantly enhanced the photocatalytic performance of the NiFe2O4 spinel nanoparticles.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Boosting photocatalytic degradation of estrone hormone by silica-supported g-C3N4/WO3 using response surface methodology coupled with Box-Behnken design

Hassan Ali et al.

Summary: In this article, a silica-supported g-C3N4/WO3 nanocomposite was prepared and characterized for enhanced photocatalytic performance in the degradation of estrone hormone. Response surface methodology (RSM) coupled with the Box-Behnken model was used to determine the synergistic effects of three independent experimental parameters. The optimized experimental conditions resulted in high hormone photodegradation efficiencies.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2023)

Article Chemistry, Physical

Construction of 3D flower-like Bi5O7I/Bi/Bi2WO6 heterostructure decorated NiFe2O4 nanoparticles for photocatalytic destruction of Levofloxacin in aqueous solution: Synergistic effect between S-scheme and SPR action

Zaid H. Jabbar et al.

Summary: Promoting the separation activity of photo-induced carriers via the design of heterostructure photocatalysts remains a vital challenge. In this study, a multistep strategy was developed to construct a Bi5O7I/Bi/Bi2WO6/NiFe2O4 heterojunction using in situ growth of Bi/Bi2WO6 and NiFe2O4 species on the surface of Bi5O7I microspheres, leading to a superior photodegradation activity of levofloxacin.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2023)

Review Engineering, Multidisciplinary

Response surface methodology (RSM) for optimizing engine performance and emissions fueled with biofuel: Review of RSM for sustainability energy transition

Ibham Veza et al.

Summary: Response Surface Methodology (RSM) is a statistical method based on design of experiments (DOE) to optimize process variables. A comprehensive review on RSM for biofuels and internal combustion engines (ICEs) is difficult to find, thus this article aims to provide a fresh perspective on the application of RSM for biofuel in ICE and critically review its optimization of engine performance and emissions. Despite drawbacks, RSM has advantages in designing and optimizing biofuel for ICE with satisfactory accuracy, contributing to the development of sustainable energy transition.

RESULTS IN ENGINEERING (2023)

Article Engineering, Multidisciplinary

Photocatalytic degradation of hazardous Rhodamine B dye using sol-gel mediated ultrasonic hydrothermal synthesized of ZnO nanoparticles

Manmohan Lal et al.

Summary: The study focused on synthesizing zinc oxide (ZnO) nanoparticles through sol-gel ultrasonic hydrothermal method at different temperatures (90 degrees C, 190 degrees C and 550 degrees C) and investigating their application in the degradation of Rhodamine B (RhB) dye. The crystallinity, surface morphology, and band gap of the ZnO nanoparticles were examined using XRD, FESEM, and DRS, respectively. The results showed that the synthesized ZnO nanoparticles had a hexagonal structure with crystalline sizes ranging from 21.1-32.41 nm. The crystalline size of ZnO increased with temperature, and FESEM revealed variations in surface morphology. DRS analysis indicated band gaps of 3.26 eV at 90 degrees C, 3.25 eV at 190 degrees C, and 3.23 eV at 550 degrees C. The optimal condition was determined using RSM and BBD, and the ZnO material synthesized at 90 degrees C exhibited a smaller size, providing a larger surface area for photocatalytic degradation of RhB dye. The maximum removal efficiency of RhB dye (25 mg/L) reached 95% under optimized conditions (pH 7, 2 g/L catalyst dose, 70 min of ultraviolet photocatalytic treatment).

RESULTS IN ENGINEERING (2023)

Article Engineering, Environmental

Current status of the direct detection of microplastics in environments and implications for toxicological effects

Eliasu Issaka et al.

Summary: Microplastics (MPs) have gained attention as a new type of pollutant due to their small size and resistance to degradation. They are produced from primary sources like resin pellets and secondary sources like debris breakdown and the release of dust from artificial garments, tires, and brake pads. Rivers play a crucial role in the contamination of MPs in the land environment. Detecting MPs in natural environments remains challenging due to limitations in sensing approaches. This study focuses on current analysis methods, direct detection methods in water and sedimentary environments, and the toxicological impacts of MPs on aquatic life and other organisms.

CHEMICAL ENGINEERING JOURNAL ADVANCES (2023)

Review Chemistry, Applied

Metal-sulfide-based heterojunction photocatalysts: Principles, impact, applications, and in-situ characterization

Haibo Zhang et al.

Summary: Semiconductor photocatalysis is a new sustainable development technology with remarkable potential in energy production and environmental protection. Heterojunction photocatalysts, such as metal sulfides, can effectively overcome the limitations of single photocatalysts and elevate the efficiency of photocatalysis to a new level.

CHINESE JOURNAL OF CATALYSIS (2023)

Article Urology & Nephrology

Inner surface modification of polyurethane ureteral stents using plasma-enhanced chemical vapor deposition to improve the resistance to encrustation in a pig model

Jae Hoon Chung et al.

Summary: This study evaluated the safety and efficacy of a ureteral stent with a non-fouling inner surface developed using plasma micro-surface modification technology in an animal model. Results showed no bacterial growth and stent-related complications in the urinary tract, and a significant reduction in biofilm formation on the surface of the modified stent, with a higher surface integrity compared to the bare stent.

INVESTIGATIVE AND CLINICAL UROLOGY (2023)

Article Chemistry, Physical

Design and synthesis of a covalent organic framework bridging CdS nanoparticles and a homogeneous cobalt-bipyridine cocatalyst for a highly efficient photocatalytic CO2 reduction

Khai H. Do et al.

Summary: In this study, a 2,2'-bipyridine-based ketoenamine covalent organic framework (TpBpy) was used to promote CO2 photoreduction processes by bridging CdS nanoparticles and a [Co(bpy)(3)](2+) cocatalyst. This system showed strong solar light harvesting ability, high CO2 adsorption capacity, efficient charge carrier transfer, and rapid photoelectron injection. This study provides insights for the development of solar-driven CO2 reduction.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Chemistry, Multidisciplinary

Preparation of CdS-Ag2S nanocomposites by ultrasound-assisted UV photolysis treatment and its visible light photocatalysis activity

Chao Han et al.

Summary: This article proposes a novel method for the synthesis of CdS-Ag2S nanocomposites from a solution of relevant ion complexes via ultrasound-assisted UV photolysis. The CdS-Ag2S nanocomposites were synthesized under UV-C irradiation through photochemical reactions. The prepared nanocomposites were analyzed for their microstructure, chemical composition, optical and electrochemical properties, and their photocatalytic activity was determined through the photodegradation of methyl orange (MO) under a xenon lamp.

NANOTECHNOLOGY REVIEWS (2023)

Review Environmental Sciences

Impact of textile dyes on health and ecosystem: a review of structure, causes, and potential solutions

Tarekul Islam et al.

Summary: The rapid growth of population and industrialization has led to a global problem of water pollution. Among various industries, the textile industry plays a prominent role in water pollution due to the large consumption of water and discharge of coloring materials in the effluent. This review evaluates the catastrophic effects of textile dyes on human health and the environment and provides an overview of treatment processes for their removal from industrial wastewaters, including chemical, biological, physical, and hybrid techniques.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Chemistry, Inorganic & Nuclear

A hybrid electrocatalyst derived from Co-MOF by doping molybdenum for efficient hydrogen generation

Xian-Xian Ji et al.

Summary: The synergistic effect of graphene and doping elements is crucial for improving the electrocatalytic performance. In this study, a highly efficient electrocatalyst, CoMoO4/Co2Mo3O8@C, was prepared through a carburization process and doping molybdenum. The electrocatalyst exhibited excellent performance for the hydrogen evolution reaction (HER) with low overpotential and small Tafel slope. The outstanding performance can be attributed to the synergistic effect between CoMoO4/Co2Mo3O8 and graphene coating, which facilitates charge transfer.

INORGANICA CHIMICA ACTA (2023)

Article Chemistry, Multidisciplinary

Electrochemical Approaches to CO2 Conversion on Copper-Based Catalysts

Gong Zhang et al.

Summary: As one of the pathways to carbon neutrality or carbon negativity, electrochemical reduction of CO2 using copper-based materials offers prospects for platform chemicals and fuel production. However, there are challenges in understanding the CO2 reduction mechanisms, designing efficient catalysts, identifying active sites, and developing practical synthesis techniques. High-performance copper-based electrocatalysts alone are not enough to meet commercialization requirements, calling for reactor design research. This Account describes research on active site identification and mass transfer enhancement in CO2 electrolysis using copper-based materials, including catalyst synthesis, mechanism investigation, and reaction system engineering, providing insights into the commercial application of this technology.

ACCOUNTS OF MATERIALS RESEARCH (2023)

Article Biochemistry & Molecular Biology

Visible light-driven degradation of Acid Orange 7 by light modulation techniques

Diana Sannino et al.

Summary: The impact of light modulation on the decolorization of AO7 was investigated, and four different modulation techniques were compared. The results showed that sinusoidal modulation had the highest decolorization efficiency under the same total transmitted photons.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2023)

Article Chemistry, Analytical

Photocatalytic degradation of microcystin-LR using BiVO4photocatalysts under visible light irradiation: modelling by response surface methodology (RSM)

Afshin Ebrahimi et al.

Summary: The synthesis of bismuth vanadate (BiVO4) through hydrothermal method effectively removes microcystin-LR (MC-LR) under visible light. Response Surface Methodology (RSM) analysis reveals that increased contact time and catalyst dose positively enhance the removal efficiency, while pH has a negative effect.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

Super-Hybrid Transition Metal Sulfide Nanoarrays of Co3S4 Nanosheet/P-Doped WS2 Nanosheet/Co9S8 Nanoparticle with Pt-Like Activities for Robust All-pH Hydrogen Evolution

Haiqing Wang et al.

Summary: This paper reports a highly active and multifunctional non-precious metal-based hydrogen evolution reaction (HER) eletcrocatalyst, which exhibits excellent performance in all-pH HER with fast reaction kinetics and high long-term stability. The active heterostructure in the nanoarray facilitates the reaction kinetics and the nanoarray morphology enhances the electron transfer and mass transport in electrocatalysis. This interesting strategy could inspire the design of advanced metal sulfide-based heterostructures for energy storage and conversion.

ADVANCED FUNCTIONAL MATERIALS (2022)

Review Chemistry, Physical

Synthesis of nanomaterials using various top-down and bottom-up approaches, influencing factors, advantages, and disadvantages: A review

Namra Abid et al.

Summary: This article discusses the synthesis and growth mechanisms of nanomaterials and their effects on their structure and morphology. The top-down and bottom-up synthesis methods are reviewed, compared, and analyzed, along with their advantages, disadvantages, and suitability for specific applications.

ADVANCES IN COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Analytical

A green analytical approach for the direct non-destructive compositional analysis of (Th, U)O-2 fuel pellets by the X-Ray Fluorescence technique using single universal calibration

Buddhadev Kanrar et al.

Summary: A green analytical methodology utilizing micro-X-Ray Fluorescence (micro-XRF) technique has been developed for the compositional analysis of (Th, U)O-2-based mixed oxide (MOX) fuel pellets. Two sample preparation methods were proposed, both of which do not require a dissolution process in corrosive acids and only a small amount of sample. The accuracy and precision of these methods were compared with a previously established total reflection X-ray fluorescence (TXRF) technique.

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2022)

Article Chemistry, Physical

Cadmium sulfide modified zinc oxide heterojunction harvesting ultrasonic mechanical energy for efficient decomposition of dye wastewater

Xiaojing Li et al.

Summary: The CdS/ZnO nano heterojunction demonstrated high efficiency and stability in the piezocatalytic degradation of Rhodamine B under ultrasonic vibration. The composite achieved a significantly higher degradation rate compared to pure CdS and ZnO, attributed to the tight loading of CdS nanoparticles onto the ZnO surface and the formation of a heterojunction structure with suitable band potentials. The enhanced piezocatalytic performance was a result of improved separation efficiency of charge carriers, driven by the piezoelectric properties of the CdS/ZnO composites.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

ZnO/CdS/CuS heterostructure: A suitable candidate for applications in visible-light photocatalysis

Prami Nandi et al.

Summary: ZnO-based photocatalysts with ternary heterostructures play a crucial role in reducing the optical band gap, increasing reactive sites, and enhancing electron-hole separation for efficient dye degradation in wastewater treatment, which results in superior photocatalytic activity with high degradation rate constants.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2022)

Article Engineering, Environmental

Investigation of environmental and therapeutic applications of holmium doped titanium dioxide (Ho-TiO2) nanocatalysts. Kinetic and thermodynamic study of the photocatalytic degradation of Safranin O dye

F. Akbar Jan et al.

Summary: In this study, titanium dioxide (TiO2) and holmium doped titanium dioxide (Ho-TiO2) nanoparticles were synthesized using the sol-gel method and characterized using various techniques. The doping of Ho into TiO2 was found to reduce the band gap and improve the morphology of the particles, leading to enhanced catalytic activity. The nanoparticles showed promising results in DNA binding, antibacterial activity, hemolysis assays, antioxidant activity, and degradation of Safranin O dye, with Ho-TiO2 exhibiting superior performance in most aspects compared to pure TiO2.

WATER SCIENCE AND TECHNOLOGY (2022)

Article Environmental Sciences

Wastewater in the food industry: Treatment technologies and reuse potential

Vaibhav Shrivastava et al.

Summary: Water consumption and wastewater reuse are important for the food and beverage industry. This review focuses on the relevant issues and analyzes the performance of adopted wastewater treatment technologies. Future research should also consider the application of other innovative technologies and take into account local government policies, social acceptance, and legal regulations.

CHEMOSPHERE (2022)

Review Energy & Fuels

Recent Advances in Nanoscale Engineering of Ternary Metal Sulfide-Based Heterostructures for Photocatalytic Water SplittingApplications

Wei-Kean Chong et al.

Summary: This review briefly summarizes the recent advances in TMS-based heterostructures, discussing the mechanistic insights and water splitting application prospects of indium-based TMSs and their heterostructures. It also explores other emerging TMS-based heterostructures and provides recommendations for future prospects and challenges in practical water splitting.

ENERGY & FUELS (2022)

Review Materials Science, Multidisciplinary

Metal sulfides based composites as promising efficient microwave absorption materials: A review

Bin Li et al.

Summary: The increasingly severe electromagnetic microwave pollution poses higher requirements for efficient microwave absorption (MA) materials. Metal sulfides are considered potential robust MA materials due to their unique properties and controllable microstructures. However, the MA performances of unary metal sulfides are limited, and morphology regulations and foreign materials hybridizations are adopted to improve their performances. This review systematically summarizes the research progress, synthetic methods, and performance improvement strategies of metal sulfides based MA materials, analyzes the influence of dimensionality and morphology on MA properties, reveals the influence of foreign materials hybridizations on the loss mechanisms and impedance matching conditions, and presents the challenges and development prospects of metal sulfides based MA materials.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

Article Materials Science, Multidisciplinary

Regulating interfacial morphology and charge-carrier utilization of Ti3C2 modified all-sulfide CdS/ZnIn2S4 S-scheme heterojunctions for effective photocatalytic H2 evolution

Junxian Bai et al.

Summary: The control of interface morphology and charge-carrier utilization in metal sulfide photocatalysts is crucial for improving the separation efficiency of electrons and holes and increasing the surface reaction active sites. In this study, a Ti3C2/ZIS/CdS composite material was synthesized, which showed improved electron-hole separation efficiency and enhanced charge transfer due to the formation of an all-sulfide S-scheme heterojunction. The addition of Ti3C2 further reduced the recombination of electrons and holes, leading to a high hydrogen production rate.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2022)

Article Chemistry, Inorganic & Nuclear

Ni(II) dithiocarbamate: Synthesis, crystal structures, DFT studies and applications as precursors for nickel sulfide and nickel oxide nanoparticles

P. Lakshmanan et al.

Summary: In this study, four nickel(II) complexes based on dithiocarbamates were synthesized and characterized. The structures and electronic properties of these complexes were calculated using density functional theory. Additionally, nanoparticles were synthesized and characterized, and were used for photocatalytic degradation experiments.

POLYHEDRON (2022)

Article Chemistry, Multidisciplinary

Sustainable Synthesis of Cadmium Sulfide, with Applicability in Photocatalysis, Hydrogen Production, and as an Antibacterial Agent, Using Two Mechanochemical Protocols

Zhandos Shalabayev et al.

Summary: CdS nanoparticles were synthesized using cadmium acetate and sodium sulfide precursors. The addition of sodium thiosulfate as an additional sulfur precursor was investigated. The samples were characterized and tested for photocatalytic activity and antibacterial potential. The results showed that CdS prepared by combined milling had superior photocatalytic activity and inhibitory effect on bacterial growth.

NANOMATERIALS (2022)

Article Materials Science, Multidisciplinary

Fabrication of a heterostructure composite with CuO and FeS2 as efficient photocatalyst for decolourisation of brilliant green

Allu Ganga Raju et al.

Summary: This study reports a simple and efficient method to fabricate a mixed composite of metal oxide and metal sulphide, which exhibits significant catalytic degradation activity towards Brilliant green dye.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2022)

Article Materials Science, Multidisciplinary

Facile fabrication of SnO2/MoS2/rGO ternary composite for solar light-mediated photocatalysis for water remediation

Philips O. Agboola et al.

Summary: Tin oxide (SnO2) nanostructure has potential application for the removal of organic contaminants from industrial effluents. However, higher bandgap value and fast recombination of charge carriers have limited its applications. To overcome these limitations, a double Z-scheme strategy was proposed, where SnO2 surface sensitization with MoS2 nanofibers and its composite with reduced graphene oxide (rGO) significantly improved the photocatalytic efficiency for methylene blue (MB) degradation under solar light.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2022)

Review Biotechnology & Applied Microbiology

Green Metallic Nanoparticles: Biosynthesis to Applications

Hitesh Chopra et al.

Summary: Advancements in nanotechnology have led to the development of new nanomaterials, but they also bring potential health and environmental risks. Researchers are working to optimize eco-friendly procedures for creating metal and metal oxide nanoparticles. Using biomaterials for nanoparticle preparation is a beneficial approach in green nanotechnology. However, there are unresolved issues that require further research and understanding.

FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY (2022)

Review Engineering, Environmental

A comprehensive review of Design of experiment (DOE) for water and wastewater treatment application-Key concepts, methodology and contextualized application

B. C. Y. Lee et al.

Summary: The study fills the gap in the literature by providing a unique perspective on the application of Design of Experiment (DOE) in the context of water chemistry. The selection of DOE protocol depends on contextualized application, with a trade-off between modeling accuracy and the number of experiments required. The study emphasizes experimental design type, model analysis, and up-to-date applications of DOE.

JOURNAL OF WATER PROCESS ENGINEERING (2022)

Article Chemistry, Inorganic & Nuclear

Chemometric study in plasmonic photocatalytic efficiency of gold nanoparticles loaded mesoporous TiO2 for mineralization of ibuprofen pharmaceutical pollutant: Box Behnken Design conception

Alaa Eddine Attar et al.

Summary: This study investigates the mineralization of ibuprofen pharmaceutical pollutant using gold nanoparticles loaded mesoporous TiO2 photocatalyst. The results show that the optimum efficiency of 98.50% can be achieved under optimized experimental conditions.

INORGANIC CHEMISTRY COMMUNICATIONS (2022)

Article Biochemistry & Molecular Biology

Hydrothermal Synthesis of Cadmium Sulfide Photocatalyst for Detoxification of Azo Dyes and Ofloxacin Antibiotic in Wastewater

Teeradech Senasu et al.

Summary: This study presents a facile hydrothermal synthesis of a CdS photocatalyst using thioacetamide as a sulfur source. The synthesized CdS showed a hexagonal phase with promising visible-light-responsive semiconducting photocatalytic activity. It effectively degraded various organic pollutants, such as dyes and antibiotics, under solar light illumination. The CdS photocatalyst exhibited excellent cycling ability and chemical stability.

MOLECULES (2022)

Article Materials Science, Ceramics

Solvothermal synthesis and characterization of ytterbium/iron mixed oxide nanoparticles with potential functionalities for applications as multiplatform contrast agent in medical image techniques

M. P. Yeste et al.

Summary: A solvothermal route to prepare glutathione capped hybrid ytterbium/iron oxide nanoparticles has been developed and their structural and morphological characteristics were extensively studied. The functionalized nanoparticles show promising potential as a dual contrast agent in medical image techniques.

CERAMICS INTERNATIONAL (2022)

Article Green & Sustainable Science & Technology

Eco-Friendly Gelatin-Cerium-Copper Sulphide Nanoparticles for Enhanced Sunlight Photocatalytic Activity

Kannaiyan Meena et al.

Summary: The study demonstrates the efficient photocatalytic degradation of pollutants using a semiconductor catalyst and sunlight, highlighting its reusability for sustainable applications.

SUSTAINABILITY (2022)

Article Green & Sustainable Science & Technology

Nickel-Cadmium-Sulfide Anchored on rGO Nanocomposite for Removal of Textile Industry Dyes

Narthana Kandhasamy et al.

Summary: The design and development of efficient photocatalysts for treating polluted water is crucial. The Ni-Cd-S/rGO nanocomposite showed excellent photodegradation performance for textile-based dyes and could be recycled effectively.

SUSTAINABILITY (2022)

Article Chemistry, Multidisciplinary

Process optimization and kinetics study for photocatalytic ciprofloxacin degradation using TiO2 nanoparticle: A comparative study of Artificial Neural Network and Surface Response Methodology

Nitesh Parmar et al.

Summary: This study investigated the photocatalytic degradation of ciprofloxacin using response surface methodology and an artificial neural network. The results showed that the photocatalysis method achieved a high degradation efficiency of ciprofloxacin under specific conditions.

JOURNAL OF THE INDIAN CHEMICAL SOCIETY (2022)

Review Chemistry, Multidisciplinary

Modulation of Nano-superstructures and Their Optical Properties

Fenglian Qi et al.

Summary: Self-assembly plays a crucial role in the research of nanomaterials, allowing for the spontaneous arrangement of nanoparticles. By balancing nanoscale interactions, highly controllable and efficient nanoparticle superstructures have been successfully built. Proper arrangement of nanoparticles inside the superstructures is essential for showcasing their functionalities. Constructing superstructures from optical nano units, such as noble metal nanostructures and semiconductor nanoparticles, is critical for achieving unique optical properties and exploring practical applications. This article provides guidelines for self-assembly strategies and discusses the optical properties of superstructures, as well as future directions in this field.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

Article Chemistry, Physical

In situ self-assembly of mesoporous Zn-Cd-Mo-S quaternary metal sulfides with double heterojunction synergistic charge transfer for boosting photocatalytic hydrogen production

Pengyu Guo et al.

Summary: The construction of semiconductor heterojunctions and in-situ self-assembly of catalysts are effective strategies to enhance photocatalytic performance. In this study, Zn-Cd-Mo-S quaternary metal sulfide mesoporous nanospheres were synthesized via a one-step hydrothermal method. The resulting photocatalyst exhibited a double-heterojunction synergetic structure, large specific surface area, and high-speed charge transfer, leading to significantly improved photocatalytic hydrogen production. The best quaternary catalyst, ZCM(5)S, showed superior hydrogen evolution yield, stability, and apparent quantum efficiency compared to binary and ternary metal sulfides. The enhanced performance can be attributed to the synergistic effect of the heterojunctions and efficient charge separation and transfer enabled by the molybdenum sulfide cocatalyst. The results highlight the importance of in-situ construction methods for the design and synthesis of high-performance heterojunction quaternary catalysts for green energy conversion.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Review Biochemistry & Molecular Biology

MoS2 and MoS2 Nanocomposites for Adsorption and Photodegradation of Water Pollutants: A Review

Leonardo O. Amaral et al.

Summary: The need for fresh and conveniently treated water has raised concerns in recent years. Molybdenum disulfide (MoS2) nanomaterials have gained attention in various fields, including energy, hydrogen production, and water decontamination. This review provides an overview of recent developments in MoS2-based nanomaterials for water treatment via adsorption and photodegradation. The combination of MoS2 with other components creates nanocomposites with enhanced properties. The review also summarizes the performance of MoS2-based materials in adsorption and photocatalytic degradation of heavy metal ions and organic contaminants. However, further studies are needed to evaluate the ecotoxicity of MoS2 in water treatment.

MOLECULES (2022)

Article Multidisciplinary Sciences

Copper sulfide and zinc oxide hybrid nanocomposite for wastewater decontamination of pharmaceuticals and pesticides

Reem Mohammed et al.

Summary: In this study, CuS QDs @ ZnO hybrid nanocomposites were successfully synthesized using a green preparation process. The prepared photocatalysts showed excellent photocatalytic performance for wastewater treatment under simulated sunlight.

SCIENTIFIC REPORTS (2022)

Review Chemistry, Physical

CuS-Based Nanostructures as Catalysts for Organic Pollutants Photodegradation

Luminita Isac et al.

Summary: The direct or indirect discharge of toxic and non-biodegradable organic pollutants into water poses a significant threat to human health and the environment. Hence, the utilization of sustainable technologies for wastewater treatment is crucial for reuse. Photocatalysis, a highly innovative advanced technique, is regarded as an effective method for pollutant removal from wastewater due to its efficiency, simplicity, affordability, and environmentally friendly byproducts. Photocatalysis relies on carefully selecting catalysts, typically semiconductor materials with high solar light absorption capacity and conductivity for photogenerated charge carriers. Among copper sulfides, CuS (covellite), as a semiconductor with diverse morphologies and bandgap values, stands out as an essential photocatalyst for eliminating various organic pollutants (e.g., dyes, pesticides, pharmaceuticals) from wastewater. This review explores recent advancements in the photodegradation of organic pollutants using various CuS nanostructures, including CuS NPs, CuS QDs, and heterojunctions (CuS/carbon-based materials, CuS/organic semiconductors, CuS/metal oxides). The impacts of different synthesis parameters (Cu:S molar ratios, surfactant concentration, etc.) and properties (particle size, morphology, bandgap energy, surface properties) on the photocatalytic performance of CuS-based catalysts for degrading different organic pollutants are extensively discussed.

CATALYSTS (2022)

Article Chemistry, Physical

Synthesis of Fe2O3/Mn2O3 Nanocomposites and Impregnated Porous Silicates for Dye Removal: Insights into Treatment Mechanisms

Soyoung Baek et al.

Summary: Fe2O3/Mn2O3@SiO2 nanocomposites and impregnated porous silicates (FMS) were prepared and investigated as catalytic adsorbents for cationic and anionic dye pollutants. FMS showed significant adsorption effect for cationic pollutants and had high removal rates. However, the adsorption reaction did not occur for anionic pollutants, but the photocatalysis reaction had certain removal rate. Bi-metal-bonded nanoparticles facilitated the photocatalytic reaction, reducing the recombination of electron-hole pairs.

CATALYSTS (2022)

Review Chemistry, Multidisciplinary

Microflow chemistry and its electrification for sustainable chemical manufacturing

Tai-Ying Chen et al.

Summary: Sustainability is crucial for solving global societal problems, and microflow chemistry plays a significant role in sustainable manufacturing by offering advantages such as new operating windows, precise residence time control, improved yield and inherent safety.

CHEMICAL SCIENCE (2022)

Review Biochemistry & Molecular Biology

Green Synthesis of Metallic Nanoparticles and Their Prospective Biotechnological Applications: an Overview

Salem S. Salem et al.

Summary: Green synthesis of nanoparticles using biological methods offers advantages such as avoiding high pressure, temperature, toxic substances, and improving productivity and purity, making it environmentally friendly, clean, safe, cost-effective, and easy to use.

BIOLOGICAL TRACE ELEMENT RESEARCH (2021)

Review Chemistry, Multidisciplinary

Photocatalysis Enhanced by External Fields

Cheng Hu et al.

Summary: The efficient conversion of solar energy through photocatalysis has great potential to address the energy crisis and environmental pollution. However, unsatisfactory conversion efficiency remains a challenge. Introducing external fields can significantly enhance the photocatalytic performance of semiconductors, leading to various applications.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Environmental Sciences

Synthesis of Fe3O4/ZnO nanoparticles and their application for the photodegradation of anionic and cationic dyes

O. Dlugosz et al.

Summary: The study investigated the preparation and application of multifunctional materials with zinc oxide nanoparticles deposited on iron oxide in dye photodegradation. The use of magnetic material allows for the recovery of photocatalysts, enhancing the sustainability of the material. Results showed that increasing the surface area of the catalyst and the presence of different pores sizes had a positive effect on the degradation of larger dye molecules.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY (2021)

Review Chemistry, Multidisciplinary

Tailored Mesoporous Inorganic Biomaterials: Assembly, Functionalization, and Drug Delivery Engineering

Yidong Zou et al.

Summary: Mesoporous biomaterials as nanocarriers show great potential in drug-targeted therapy, becoming a hot topic in interdisciplinary research. Understanding assembly mechanisms, functionalization methods, and the impact of physicochemical parameters on DDS application will contribute to significant advancements in disease therapeutics.

ADVANCED MATERIALS (2021)

Article Materials Science, Ceramics

Facile synthesis of highly efficient Co@ZnSQDs/g-C3N4/MWCNT nanocomposites and their photocatalytic potential for the degradation of RhB dye: Efficiency, degradation kinetics, and mechanism pathway

Mohtaram Danish et al.

Summary: The modification of graphitic carbon nitride with Co-doped zinc sulfide quantum dots and multiwalled carbon nanotubes significantly enhanced the photodegradation performance of rhodamine B in aqueous suspension under visible light. The novel ternary nanocomposites Co@ZnSQDs/g-C3N4/MWCNT with different mass ratios were successfully synthesized, showing improved photocatalytic activity due to the formation of strong heterojunction, proficient absorption of visible light, enlarged specific surface area, and efficient separation of electron-hole pairs. Additionally, the enhanced photo mineralization of paracetamol was observed over the most active Co-ZGM nanocomposite, highlighting the potential of these materials for environmental pollutant degradation.

CERAMICS INTERNATIONAL (2021)

Article Chemistry, Physical

Ultrasound assisted synthesis of magnetic Fe3O4/α-MnO2 nanocomposite for photodegradation of organic dye

Monika Dubey et al.

Summary: An ultrasound assisted method was used to synthesize magnetic Fe3O4/alpha-MnO2 nanocomposite, which was characterized by various analytical techniques. The nanocomposite exhibited excellent photocatalytic degradation of crystal violet dye under solar and UV-vis irradiation, and showed good reusability under certain conditions.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Chemistry, Physical

P-n Heterostructured design of decahedral NiS/BiVO4 with efficient charge separation for enhanced photodegradation of organic dyes

Yan Li et al.

Summary: The study developed a NiS/BiVO4 heterostructured photocatalyst with high efficiency for dyeing wastewater treatment, showing excellent catalytic stability and high degradation rate.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Chemistry, Physical

FeO-Clinoptilolite nanoparticles: Brief characterization and its photocatalytic kinetics towards 2,4-dichloroaniline

Fereshteh Iazdani et al.

Summary: By coupling FeO onto clinoptilolite nanoparticles, a catalyst with enhanced photocatalytic activity was prepared for efficient degradation of DCA. The highest degradation rate was achieved when the FeO loading reached 13%, indicating the optimal conditions for the photodegradation process.

CHEMICAL PHYSICS (2021)

Article Materials Science, Multidisciplinary

Synthesis and visible-light photocatalytic properties of BiOBr/CdS nanomaterials

Junhua You et al.

Summary: The synthesis of BiOBr/CdS composite materials with different mass ratios can enhance the photocatalytic activity. Experimental results show that the composite photocatalyst containing 60% BiOBr exhibits the highest photocatalytic activity. Free radical capture experiments further confirm that holes are the main active species in the photocatalytic process of composite samples.

JOURNAL OF MATERIALS SCIENCE (2021)

Article Chemistry, Multidisciplinary

CuS-ZnS decorated graphene nanocomposites: Synthesis and photocatalytic properties

Jini Varghese

Summary: Porous nanocomposites containing CuS-ZnS nanospheres and graphene layers were synthesized via a simple method, demonstrating efficient photocatalytic performance over a wide pH range. The nanocomposites showed excellent dye degradation efficiency due to enhanced surface area, porosity, better UV light harvesting capacity, and fast electron-hole transfer.CuS-ZnS decorated graphene is a promising photocatalyst for the degradation of dye mixtures in industrial applications.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2021)

Article Engineering, Electrical & Electronic

Tailoring the optical and magnetic properties of ZnS nanoparticles via 3d and 4f elements co-doping

B. Poornaprakash et al.

Summary: Impurity-free cobalt and erbium co-doped ZnS nanoparticles were synthesized using a chemical reflux technique, exhibiting high crystallinity and a narrow particle-size distribution. The co-doped nanoparticles showed strong magnetization and enhanced coercivity compared to cobalt-doped ZnS nanoparticles, due to exchange interaction between cobalt electrons and localized carriers induced by erbium co-doping. This approach opens up new possibilities for advanced applications in optoelectronics and spintronic devices.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2021)

Review Energy & Fuels

Preparation, Functionalization, Modification, and Applications of Nanostructured Gold: A Critical Review

Muhammad Yaseen et al.

Summary: Gold nanoparticles play a significant role in science and technology due to their unique properties and potential applications. Various approaches for synthesis, modification and functionalization of nanostructured gold have been discussed in detail in this review. Modification and functionalization of nanostructured gold have shown to enhance catalytic performance, summarizing various methods for better catalytic outcomes.

ENERGIES (2021)

Article Chemistry, Physical

Enhanced photocatalytic activities of NiS decorated reduced graphene oxide for hydrogen production and toxic dye degradation under visible light irradiation

Suresh Muninathan et al.

Summary: Semiconductor nanoparticles have been extensively studied for a decade for photocatalytic hydrogen production and remediation of toxic pollutants due to their better activities at nano regime and quantum efficiency. The present study reports the synthesis of NiS nanoparticles decorated reduced-graphene oxide nanocomposite as an effective visible photo-catalyst for H2 production and toxic organic dye degradation. The nanocomposite shows good structural and optical properties, with high photocatalytic activities in dye degradation and hydrogen production.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Green & Sustainable Science & Technology

Fundamentals and photocatalysis of methylene blue dye using various nanocatalytic assemblies- a critical review

Muhammad Imran Din et al.

Summary: This study presents the fundamentals and factors involved in the degradation of methylene blue, as well as the detailed kinetics and mechanistic description of the light-mediated reaction. The classification and discussion of nanomaterials based photocatalysts and the comparative analysis of stabilization mediums provide essential insights into the advancement of scientific research in this field. Future prospects for further extending the research are also discussed.

JOURNAL OF CLEANER PRODUCTION (2021)

Article Optics

Green synthesis of Cadmium Sulphide nanoparticles for the photodegradation of Malachite green dye, Sulfisoxazole and removal of bacteria

S. Munyai et al.

Summary: The use of S. frutescens leaf extract in synthesizing CdS nanostructures showed high photocatalytic efficiency in degrading dyes and antibiotics pollutants, as well as excellent antibacterial activity.
Review Engineering, Environmental

Heterogeneous Fenton catalysts: A review of recent advances

Nishanth Thomas et al.

Summary: 1. Heterogeneous Fenton catalysts show excellent performance in water purification applications. 2. Increasing complexity in cell wall leads to higher resistance of microorganisms towards disinfectants. 3. Introduction of plasmonic materials can enhance the visible light absorption efficiency of the hybrid Fenton catalysts.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Physics, Condensed Matter

Iron oxide nanoparticles synthesized using garlic and onion peel extracts rapidly degrade methylene blue dye

Muslim A. Abid et al.

Summary: The combination of garlic and onion peel extracts with iron chloride salt in a green treatment method played a crucial role in the rapid degradation of toxic dyes. Through various physical techniques, the characteristics of the synthesized iron oxide nanoparticles were analyzed, indicating their effectiveness in dye removal. The results showcased high degradation efficiency of methylene blue by the biosynthesized iron oxide nanoparticles, with significant photocatalytic activity observed.

PHYSICA B-CONDENSED MATTER (2021)

Article Engineering, Electrical & Electronic

Visible-light-responsive photocatalyst based on ZnO/CdS nanocomposite for photodegradation of reactive red azo dye and ofloxacin antibiotic

Teeradech Senasu et al.

Summary: In this study, a ZnO/CdS nanocomposite was successfully synthesized with high efficiency in degrading reactive red 141 azo dye and ofloxacin antibiotic. The composite showed great potential for environmental protection.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2021)

Article Chemistry, Multidisciplinary

Metal Sulfide Nanoparticle Synthesis with Ionic Liquids State of the Art and Future Perspectives

Christian Balischewski et al.

Summary: Metal sulfides are promising materials for various technological applications. This article discusses the synthesis of metal sulfides using ionic liquids, highlighting their advantages over traditional methods.

CHEMISTRYOPEN (2021)

Article Engineering, Chemical

Evaluation of photocatalysis of Au supported ZnO prepared by the spray pyrolysis method

Youngjun Lee et al.

Summary: This study investigates the control of electron-hole recombination of a photocatalyst by loading gold on zinc oxide. The optimal photocatalytic activity occurs with 0.1 mass% gold supported on zinc oxide particles, showing faster decomposition rate of organic dye. The findings suggest that Au/ZnO particles hold promising potential for environmentally friendly treatment methods in reducing environmental pollution caused by organic dyes.

ADVANCED POWDER TECHNOLOGY (2021)

Article Engineering, Chemical

A statistical modeling-optimization approach for efficiency photocatalytic degradation of textile azo dye using cerium-doped mesoporous ZnO: A central composite design in response surface methodology

Hanane Chaker et al.

Summary: This study focuses on optimizing the photodegradation of methyl orange (MO) using a central composite design (CCD) coupled with Response Surface Methodology (RSM). The results show that cerium nanoparticles (CeNPs) enhance the photocatalytic performance of ZnO at 2% Ce content. The optimum conditions were found to be pH of solution at 5.58, MO concentration at 20.72 mg L-1, and catalyst dosage at 0.63 g L-1.

CHEMICAL ENGINEERING RESEARCH & DESIGN (2021)

Article Energy & Fuels

Relative study of Ni sulfides synthesized from single and multisource precursors for photocatalytic and battery applications

Maroof Ahmad Khan et al.

Summary: Chalcogenide nanoparticles play a significant role in nanochemistry due to their ease of fabrication and diverse applicability. Different pathways of fabrication can lead to variations in the morphologies and properties of the resulting nanomaterials. Photocatalytic activity and battery performance were evaluated for materials obtained from single and multisource precursors, with the former showing superior photocatalytic activity.

ENERGY REPORTS (2021)

Article Chemistry, Physical

Hierarchical nickel sulphide microstructures for controlled water disinfection and cold cathode emission

Rimpa Khan et al.

Summary: This study presents the preparation of hierarchical nickel sulphide microtubes using a cost-effective sol-gel technique, applied for photo-induced dye separation and cold electron emission. The nickel sulphide microstructures showed efficient dye degradation under UV irradiation, with removal efficiency influenced by both dimension and composition parameters. The study also investigated active radicals involved in the catalysis process and explored the recyclability of the catalyst sample for long-term action. Additionally, the nickel sulphide microstructures exhibited field emission behavior, which is reported for the first time.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2021)

Article Chemistry, Physical

Design and structural of Sm-doped SbFeO3 nanopowders and immobilized on poly(ethylene oxide) for efficient photocatalysis and hydrogen generation under visible light irradiation

Ye Liu et al.

Summary: In this study, samarium doped SbFeO3 nanoparticles/poly (ethylene oxide) composite materials were successfully prepared and exhibited high photocatalytic degradation efficiency and hydrogen production performance under sunlight irradiation.

SURFACES AND INTERFACES (2021)

Article Engineering, Electrical & Electronic

Nickel sulfide impregnated on natural phosphate: characterization and applications in photocatalytic degradation of indigocarmine dye

Houyem Hafdi et al.

Summary: NiS2 impregnated on NP via a simple method showed efficient photocatalytic performance for Indigo Carmin dye removal under visible light irradiation. The possible photocatalytic mechanism was proposed, and the catalyst exhibited good adequacy with the Langmuir-Hinshelwood kinetic model and excellent reusability.

OPTICAL AND QUANTUM ELECTRONICS (2021)

Article Physics, Condensed Matter

Promising photocatalytic degradation of methyl orange dye via sol-gel synthesized Ag-CdS@Pr-TiO2 core/shell nanoparticles

Anoop Singh et al.

Summary: The study prepared core-shell structured Ag-CdS@Pr-TiO2 nanoparticles and investigated their photocatalytic activity for degrading methyl orange under visible light. Various techniques confirmed the composition, morphology, and optical properties of the synthesized core/shell nanoparticles. The synthesized material showed potential for efficiently degrading methyl orange based on the discoloration of dye within 30 minutes.

PHYSICA B-CONDENSED MATTER (2021)

Article Engineering, Multidisciplinary

Facile synthesis of novel zinc sulfide/chitosan composite for efficient photocatalytic degradation of acid brown 5G and acid black 2BNG dyes

Ahmed Alharbi et al.

Summary: A novel ZnS/chitosan composite was successfully synthesized and used as an effective catalyst for the photodegradation of carcinogenic azo dyes in the presence of UV irradiations. The composite showed a degradation efficiency of over 97% for both dyes, followed a pseudo-first-order degradation process, and exhibited good recyclability.

ALEXANDRIA ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Preparation of plasmonic CoS/Ag2WO4 nanocomposites: Efficient visible light driven photocatalysts and enhanced anti-microbial activity

S. Kokilavani et al.

Summary: Novel CoS/Ag2WO4 photocatalysts were successfully synthesized by a facile chemical precipitation method, exhibiting enhanced photocatalytic and antimicrobial activity, broad-spectrum antibacterial properties, and good photostability and reusability. The scavenging test confirmed hydroxyl radicals as the major species involved in the photocatalytic degradation process under visible light irradiation. These results suggest practical applications in the field of photocatalysis and antimicrobial applications.

COLLOID AND INTERFACE SCIENCE COMMUNICATIONS (2021)

Article Materials Science, Ceramics

Design of NiS/CNTs nanocomposites for visible light driven catalysis and antibacterial activity studies

Sajjad Haider et al.

Summary: In this study, NiS and NiS/CNTs nanocomposites were synthesized using a hydrothermal technique. Structural characterization using XRD and FTIR, along with Scherer formula for crystallite size examination, confirmed the formation and purity of the samples. The improved bandgap energy of NiS/CNTs resulted in excellent photocatalytic degradation of methylene blue and enhanced antibacterial activity against various bacteria. The incorporation of carbon nanotubes in metal sulphide nanocomposites shows promising potential for wastewater treatment.

CERAMICS INTERNATIONAL (2021)

Review Environmental Sciences

Recent trends in microbial nanoparticle synthesis and potential application in environmental technology: a comprehensive review

Jayshree Annamalai et al.

Summary: The review extensively examines the applications of microbial synthesis of nanoparticles in various fields, emphasizing its advantages in environmental protection and resource recycling.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

Article Pharmacology & Pharmacy

Design of experiments (DoE) to develop and to optimize nanoparticles as drug delivery systems

Marcela Tavares Luiz et al.

Summary: Nanotechnology is widely utilized in drug delivery systems, where the biological responses are closely related to the physicochemical properties of the systems. Quality-oriented manufacturing of nanoparticles is crucial to optimize product quality.

EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS (2021)

Article Engineering, Environmental

Molybdenum sulfide-modified metal-free graphitic carbon nitride/black phosphorus photocatalyst synthesized via high-energy ball-milling for efficient hydrogen evolution and hexavalent chromium reduction

Alan Meng et al.

Summary: The study synthesized a novel high-efficiency molybdenum sulfide-modified metal-free photocatalyst via high-energy ball milling. This photocatalyst exhibited excellent photocatalytic activity due to its matched band structure, enhanced light absorption, intense interface contact, and specific charge transfer mechanism.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Nanoscience & Nanotechnology

Novel NiS/Ag2MoO4 heterostructure nanocomposite: Synthesis, characterization and superior antibacterial and enhanced photocatalytic activity

S. Kokilavani et al.

Summary: NiS/Ag2MoO4 heterostructured nanocomposite exhibited enhanced photocatalytic activity in degrading organic dye compounds and excellent antibacterial property, demonstrating great potential in environmental remediation and antimicrobial applications.

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES (2021)

Article Chemistry, Physical

Adsorption performance of boron nitride nanomaterials as effective drug delivery carriers for anticancer drugs based on density functional theory

Xianxian Tu et al.

Summary: The drug delivery properties of boron nitride nanomaterials as anticancer drug carriers were investigated using density functional theory. The study included analysis of binding energy, solubility energy, thermodynamic properties, and UV-Vis spectra of drug adsorption on BN nanomaterials. The research also simulated the drug release process and how the drug delivery system is affected by internal biological environments.

COMPUTATIONAL AND THEORETICAL CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Enhanced Photocatalytic Degradation of Ternary Dyes by Copper Sulfide Nanoparticles

Peter A. Ajibade et al.

Summary: This study investigates the effect of thermolysis time on the morphological and optical properties of CuS nanoparticles and finds that CuS3 shows the highest photocatalytic degradation efficiency. The CuS nanoparticles exhibit good stability and recyclability, effectively degrading a mixture of different dyes.

NANOMATERIALS (2021)

Article Nanoscience & Nanotechnology

Synthesis of cerium oxide/cadmium sulfide nanocomposites using inverse microemulsion methodology for photocatalytic degradation of methylene blue

Muhammad Danish et al.

Summary: This research study successfully synthesized CeO2/CdS nanocomposites using the inverse microemulsion methodology and demonstrated their potential in photocatalytic applications. The results of photocatalytic degradation experiments showed that the RSM optimization method was more effective than the conventional kinetic model-based optimization.

APPLIED NANOSCIENCE (2021)

Article Biotechnology & Applied Microbiology

Process optimization and kinetics analysis for photocatalytic degradation of emerging contaminant using N-doped TiO2-SiO2 nanoparticle: Artificial Neural Network and Surface Response Methodology approach

Shimelis Kebede Kassahun et al.

Summary: In this study, visible light active N-doped TiO2-SiO2 nanoparticles were synthesized for the photodegradation and mineralization of ciprofloxacin. The maximum CIP degradation efficiency of 88.45% and TOC removal efficiency of 75.18% were achieved under the optimum operating parameters. The adsorption isotherm and chemical kinetic studies were best fitted by Langmuir isotherm and pseudo-second-order kinetic models, respectively.

ENVIRONMENTAL TECHNOLOGY & INNOVATION (2021)

Review Chemistry, Physical

Stability challenges of electrocatalytic oxygen evolution reaction: From mechanistic understanding to reactor design

Feng-Yang Chen et al.

Summary: This review summarizes critical mechanisms that could influence the stability of the oxygen evolution reaction (OER) and discusses the importance of stability in large-scale electrolysis industrialization. Additionally, it provides catalyst and reactor design principles for overcoming OER stability challenges.
Article Engineering, Environmental

Optimization and modeling of efficient photocatalytic TiO2-ZnO composite preparation parameters by response surface methodology

Kabuyaya Kighuta et al.

Summary: This study focused on the design and optimization of TiO2-ZnO composite using response surface methodology, with evaluation of photocatalytic NOx removal efficiency. Experimental results validated the RSM predictions, showing different efficiencies for NOx removal based on calcination temperature and ZnO weight percent. The best photocatalytic performance was observed in the composite with 2.1 wt % of ZnO calcined at 558°C.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Article Engineering, Environmental

MoS2 based nanocomposites: An excellent material for energy and environmental applications

Md Ahmaruzzaman et al.

Summary: Molybdenum disulphide (MoS2) is widely studied as a heterogeneous catalyst for its outstanding properties, and its 2D form has gained attention for environmental and energy applications. As a structural analogue of graphene, MoS2 offers similar properties but at a lower cost and greater abundance, with potential for enhanced catalytic efficiency when coupled with graphene.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Review Chemistry, Multidisciplinary

Transition metal sulfides meet electrospinning: versatile synthesis, distinct properties and prospective applications

Wendong Zhu et al.

Summary: The integration of one-dimensional electrospun nanomaterials with metal sulfides has attracted significant attention for their unique properties and potential applications in various fields. Challenges and further research opportunities in the preparation and application of these novel functional materials are also discussed in this review.

NANOSCALE (2021)

Article Chemistry, Multidisciplinary

Efficient catalytic reduction of hazardous hexavalent chromium by cobalt sulfide nanoparticles

K. Arathi et al.

Summary: Cobalt sulfide nanoparticles show effective catalytic reduction capability for hexavalent chromium, converting it to non-toxic trivalent chromium. Under pH 2 in sulfuric acid, the reduction of 50 ppm Cr(VI) with 1.5 g/L catalyst is completed within 16 minutes with an efficiency of around 99.63%. However, the activity of the catalyst decreases after 17 cycles of use.

CHEMICAL PAPERS (2021)

Article Multidisciplinary Sciences

Simple synthesis of gold-decorated silica nanoparticles by in situ precipitation method with new plasmonic properties

Lizbet Leon Felix et al.

Summary: This method involves using BH4- ions for the reduction of gold ions onto PEI-functionalized SiO2 NPs, resulting in 3-nm gold nanoshell NPs attached to SiO2 core with a significant red-shift in UV-Vis absorption. The gold-decorated SiO2 NPs have potential applications in biosensors and photothermal therapy.

SN APPLIED SCIENCES (2021)

Review Chemistry, Physical

Advances on Photocatalytic CO2 Reduction Based on CdS and CdSe Nano-Semiconductors

Jin Wu et al.

Summary: Carbon dioxide (CO2) is a major greenhouse gas in the atmosphere. Utilizing artificial photosynthetic systems to convert CO2 into solar fuels is an ideal way to both utilize CO2 as a resource and reduce CO2 emissions. Nano-semiconductors such as CdS and CdSe have been widely used for their photophysical and photochemical properties in photocatalytic CO2 reduction systems.

ACTA PHYSICO-CHIMICA SINICA (2021)

Review Chemistry, Physical

Local-interaction-field-coupled semiconductor photocatalysis: recent progress and future challenges

Qin Lei et al.

Summary: This review summarizes recent progress in rational design and construction of local interaction fields in the photocatalysis community, including electric, thermal, magnetic, ultrasonic, and multifield coupling, to improve solar-energy conversion efficiency and address environmental issues.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Engineering, Environmental

Modeling and Box-Behnken design optimization of photocatalytic parameters for efficient removal of dye by lanthanum-doped mesoporous TiO2

Hanane Chaker et al.

Summary: In this study, the Box-Behnken design in the response surface methodology was used to investigate the modelization and optimization of Methyl Orange mineralization parameters with La doped mesoporous TiO2. The effects of irradiation light wavelength, catalyst weight, and MO concentration on the yield of MO mineralization were studied. The optimized conditions were determined to be 310 nm light wavelength, 80 mg catalyst weight, and 20 ppm MO concentration, achieving a mineralization rate of 99.89%.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Article Engineering, Electrical & Electronic

Photocatalytic Activity of Nickel Sulfide Composite Powders Synthesized by Solution Combustion Method

N. Ardebilchi Marand et al.

JOURNAL OF ELECTRONIC MATERIALS (2020)

Article Physics, Condensed Matter

Wet chemical route synthesis of spinel oxide nano-catalysts for photocatalytic applications

Nusrat Shaheen et al.

PHYSICA B-CONDENSED MATTER (2020)

Article Environmental Sciences

Synthesis of zeolite NaY supported Mn-doped ZnS quantum dots and investigation of their photodegradation ability towards organic dyes

Zahra Ahmadi et al.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020)

Review Materials Science, Multidisciplinary

A review of graphene synthesis by indirect and direct deposition methods

Yanxia Wu et al.

JOURNAL OF MATERIALS RESEARCH (2020)

Article Biochemistry & Molecular Biology

Green synthesis of iron oxide nanorods using Withania coagulans extract improved photocatalytic degradation and antimicrobial activity

Shaheen Qasim et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY (2020)

Article Chemistry, Multidisciplinary

Increasing the Efficiency of Photocatalytic Reactions via Surface Microenvironment Engineering

Hang Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Materials Science, Multidisciplinary

Novel carbon nanotube supported Co@Ag@Pd formic acid electrooxidation catalysts prepared via sodium borohydride sequential reduction method

Omer Faruk Er et al.

MATERIALS CHEMISTRY AND PHYSICS (2020)

Article Chemistry, Physical

Investigation of growth-induced strain in monolayer MoS2 grown by chemical vapor deposition

Siwei Luo et al.

APPLIED SURFACE SCIENCE (2020)

Article Chemistry, Physical

Impact of CdS/SnO2 heterostructured nanoparticle as visible light active photocatalyst for the removal methylene blue dye

Emad E. El-Katori et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2020)

Article Nanoscience & Nanotechnology

MOF-Derived Sulfide-Based Electrocatalyst and Scaffold for Boosted Hydrogen Production

Kelong Ao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Nanoscience & Nanotechnology

Novel NiCl2 Nanosheets Synthesized via Chemical Vapor Deposition with High Specific Energy for Thermal Battery

Zeshunji Luo et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Nanoscience & Nanotechnology

New hydrothermal synthesis strategy of nano-sized BiFeO3 for high-efficient photocatalytic applications

Yan Li et al.

PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES (2020)

Article Chemistry, Physical

Simultaneous photodegradation of dyes by NiS/CuS-CdS composites in visible light region

Xiaogang Zheng et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Article Engineering, Chemical

Photocatalytic membrane filtration and its advantages over conventional approaches in the treatment of oily wastewater: A review

Erika Nascimben Santos et al.

ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING (2020)

Article Polymer Science

Synthesis of Flower-Like Co9S8/Reduced Graphene Oxide Nanocomposites and Their Photocatalytic Performance

Muhammad Sohail et al.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2020)

Article Materials Science, Multidisciplinary

Efficient photocatalytic degradation of crystal violet by using graphene oxide/nickel sulphide nanocomposites

Venkatachalam Manikandan et al.

BULLETIN OF MATERIALS SCIENCE (2020)

Article Chemistry, Physical

All-solid-state Z-scheme BiOX(Cl, Br)-Au-CdS heterostructure: Photocatalytic activity and degradation pathway

Min Zhang et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Review Chemistry, Analytical

Recent advances in two-dimensional layered materials for photoelectrochemical sensing

Juan Wang et al.

TRAC-TRENDS IN ANALYTICAL CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Detail review on chemical, physical and green synthesis, classification, characterizations and applications of nanoparticles

Irfan Ijaz et al.

GREEN CHEMISTRY LETTERS AND REVIEWS (2020)

Review Chemistry, Multidisciplinary

Nano-Sized Iron Sulfide: Structure, Synthesis, Properties, and Biomedical Applications

Ye Yuan et al.

FRONTIERS IN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Effect of reaction temperature and reaction time on the structure and properties of MoS2 synthesized by hydrothermal method

Tran Thanh Xuan et al.

VIETNAM JOURNAL OF CHEMISTRY (2020)

Article Chemistry, Physical

Synthesis and photocatalytic performance of copper sulfide by a simple solvothermal method

Shuang-long Zhou et al.

CHEMICAL PHYSICS LETTERS (2020)

Review Engineering, Environmental

Review of the Process Optimization in Microbial Fuel Cell using Design of Experiment Methodology

Aryama Raychaudhuri et al.

JOURNAL OF HAZARDOUS TOXIC AND RADIOACTIVE WASTE (2020)

Review Chemistry, Physical

Challenges and opportunities in the bottom-up mechanochemical synthesis of noble metal nanoparticles

Paulo F. M. de Oliveira et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Physical

Polyimide-based photocatalysts: rational design for energy and environmental applications

Sheng Chu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Engineering, Environmental

NaFeS2 as a new photocatalytic material for the degradation of industrial dyes

V. G. Dileepkumar et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Facile synthesis and enhanced photocatalytic activity of Ag-SnS nanocomposites

Chandini Behera et al.

NEW JOURNAL OF CHEMISTRY (2020)

Article Multidisciplinary Sciences

Kinetics and Optimization Studies of Photocatalytic Degradation of Methylene Blue over Cr-Doped TiO2 using Response Surface Methodology

P. W. Koh et al.

IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A-SCIENCE (2019)

Article Biochemistry & Molecular Biology

Preparation, and structural of new NiS-SiO2 and Cr2S3-TiO2 nano-catalyst: Photocatalytic and antimicrobial studies

Mojgan Hosseini et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY (2019)

Article Automation & Control Systems

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Confined-interface-directed synthesis of Palladium single-atom catalysts on graphene/amorphous carbon

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CERAMICS INTERNATIONAL (2018)

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