4.7 Review

Review of efficient recycling and resource utilization for rare earth molten salt electrolytic slag

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Effect of roasting activation of rare earth molten salt slag on extraction of rare earth, lithium and fluorine

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Summary: A new process of synergistic roasting and acid leaching was proposed to extract rare earth elements (REEs), Li and F from electrolytic slag of rare earth molten salt. The effects of roasting factors on leaching REEs, Li, and F in slag were investigated, and the migration mechanism of minerals in the roasting and leaching process was analyzed. The results showed that the synergistic roasting and activation of molten salt slag were feasible, leading to high leaching rates of Nd, Pr, Gd, Li, and F.

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Recovery of rare earths, lithium, and fluorine from rare earth molten salt electrolytic slag by mineral phase reconstruction combined with vacuum distillation

Yaobin Lai et al.

Summary: A novel green method for the recovery of rare earths (REs), fluorine (F), and lithium (Li) from rare earth molten salt electrolytic slag (REMSES) was proposed and demonstrated by mineral phase reconstruction combined with vacuum distillation. The optimized conditions for the roasting process were found to be a temperature of 600 degrees C, LiOH center dot H2O dosage coefficient of 1.1 times, and roasting time of 4 h. Vacuum distillation was shown to effectively remove F, with a removal rate of 99.98% and a recovery rate of LiF of 98.96%.

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Peng Xing et al.

Summary: The separation of rare earth elements (REEs) from rare earth molten salt slag has been a challenge due to the high fluorine content. This study presents a clean process for recycling REEs from the slag using fluorine fixation roasting and hydrometallurgical leaching. The leaching efficiencies of REEs were above 97% under optimal conditions.

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Preparation of enstatite-spinel based glass-ceramics by co-utilization of ferronickel slag and coal fly ash

Wenxing Shang et al.

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Selective extraction of rare earths and lithium from rare earth fluoride molten-salt electrolytic slag by nitration

Huazhou Hu et al.

Summary: This study utilized a selective nitration method to extract rare earth elements (REEs) and Li from electrolytic slag, successfully separating Fe and Al oxides. The fluorine volatilized as HF during nitration and was absorbed by an alkaline solution, effectively removing impurities and achieving high purity REE oxalates.

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Harmless disposal and resource utilization for secondary aluminum dross: A review

Hanlin Shen et al.

Summary: Secondary aluminum dross (SAD) is a solid waste containing alumina, aluminum nitride, salts, etc. It can be utilized as a resource or pollutant. The main methods for utilization are pyrometallurgy and hydrometallurgy, with the former showing lower resource consumption and emissions compared to the latter.

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Extraction and optimization of neodymium from molten fluoride electrolysis

Prince Sarfo et al.

Summary: The paper discusses the extraction of neodymium from rare earth oxides using pyrometallurgical approaches and electrolysis, with a focus on the establishment of conditions for producing pure Nd metal from REOs. It also expands on the use and verification of diagrams through experimental studies, leading to statistical recovery models based on molten salt electrolysis for extracting neodymium from fluoride solutions.

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Zhiyong Gao et al.

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Comprehensive review on metallurgical recycling and cleaning of copper slag

Hongyu Tian et al.

Summary: Copper slag, a potentially harmful waste generated during copper smelting, contains valuable metals like Cu, Fe, Zn, Co, and Ni as well as hazardous elements such as Pb and As. It is important to subject copper slag to further metallurgical recycling and cleaning for economic and environmental benefits. Improved processes focusing on high recycling efficiency, low energy consumption, and low secondary environmental pollution are needed for sustainable waste utilization of copper slag.

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