A core-shell copper oxides-cobalt oxides heterostructure nanowire arrays for nitrate reduction to ammonia with high yield rate

Electrochemical nitrate reduction to ammonia (NRA) can realize the green synthesis of ammonia (NH3) at ambient conditions, and also remove nitrate contamination in water. However, the current catalysts for NRA still face relatively low NH3 yield rate and poor stability. We present here a core-shell heterostructure comprising cobalt oxide anchored on copper oxide nanowire arrays (CuO NWAs@Co3O4) for efficient NRA. The CuO NWAs@Co3O4 demonstrates significantly enhanced NRA performance in alkaline media in comparison with plain CuO NWAs and Co3O4 flocs. Especially, at -0.23 V vs. RHE, NH3 yield rate of the CuO NWAs@Co3O4 reaches 1.915 mmol h-1 cm -2, much higher than those of CuO NWAs (1.472 mmol h-1 cm -2), Co3O4 flocs (1.222 mmol h-1 cm -2) and recent reported Cu-based catalysts. It is proposed that the synergetic effects of the heterostructure combing atom hydrogen adsorption and nitrate reduction lead to the enhanced NRA performance.(c) 2022 Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Commu-nications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Automated summary

In this study, a CuO NWAs@Co3O4 core-shell heterostructure catalyst was proposed for efficient electrochemical nitrate reduction to ammonia (NRA). Compared with pure CuO NWAs and Co3O4 flocs, CuO NWAs@Co3O4 exhibited significantly enhanced NRA performance.