☆ 4.7 Article

Poly(ferrocenylene iminoborane): an inorganic-organic hybrid polymer comprising a backbone of moderately interacting ferrocenes

CHEMICAL COMMUNICATIONS (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Polymer Science

Poly(thiophene iminoborane): A Poly(thiophene vinylene) (PTV) Analogue with a Fully B(sic)N-Doped Backbone

Johannes Chorbacher et al.

Summary: This article presents an unprecedented polymer (poly(thiophene iminoborane)) which is a boron-nitrogen analogue of the well-established conjugated organic polymer poly(thiophene vinylene). The polymer is synthesized through a selective Si/B exchange polycondensation reaction using a 2,5-diborylthiophene and a 2,5-diaminothiophene derivative. A facile synthetic strategy is devised for the latter, making it easily accessible. The novel polymer and a series of monodisperse thiophene iminoborane oligomers show systematic bathochromic shifts in their absorption spectra with increasing chain length, indicating extended π-conjugation over the B-N units along the backbone, which is further supported by TD-DFT calculations.

MACROMOLECULAR RAPID COMMUNICATIONS (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Diradical B/N-Doped Polycyclic Hydrocarbons

Jiaxiang Guo et al.

Summary: We report the synthesis of B/N-type organic diradicaloids with atom-precise control over open-shell nature through quinoidal pi-extension of a B/N-heterocycle. These diradicaloids exhibit modulated (anti)aromaticity and enhanced diradical characters compared with all-carbon analogues, and display intriguing properties such as magnetic activities and highly red-shifted absorptions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Poly(arylene iminoborane)s, Analogues of Poly(arylene vinylene) with a BN-Doped Backbone: A Comprehensive Study

Matthias Maier et al.

Summary: This study focuses on oligo- and poly(arylene iminoborane)s with a backbone of phenylene or thiophene moieties linked via B=N units. The researchers successfully prepared various polymers and oligomers with tailored electronic properties using a modular synthetic approach. The compounds exhibited effective pi-conjugation, solid-state emission, and aggregation-induced emission behavior.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

添加到收藏夹

Article Chemistry, Multidisciplinary

Bright Luminescence by Combining Chiral [2.2]Paracyclophane with a Boron-Nitrogen-Doped Polyaromatic Hydrocarbon Building Block

Mario R. Rapp et al.

Summary: Novel BN-doped compounds based on chiral, tetrasubstituted [2.2]paracyclophane and NBN-benzo[f,g]tetracene were synthesized via Sonogashira-Hagihara coupling. These compounds exhibit excellent optical and chiroptical properties and show both oxidation and reduction reactions in electroanalytical studies.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

BN-Anthracene for High-Mobility Organic Optoelectronic Materials through Periphery Engineering

Wanhui Li et al.

Summary: We have successfully developed high-mobility organic semiconductors based on BN-PAHs through the periphery engineering strategy. One particular BN-PAH, DPBNA, showed remarkable performance in organic field-effect transistors with a hole mobility of 1.3 cm(2) V-1 s(-1), surpassing TPBNA and all previously reported BN-PAHs. Remarkably, this is the first BN-PAH with a mobility exceeding 1 cm(2) V(-1) s(-1), making it a benchmark for practical applications comparable to amorphous silicon. Additionally, high-performance phototransistors based on DPBNA were demonstrated, indicating the high potential of BN-PAHs for optoelectronic applications when the periphery engineering strategy is implemented.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Oligomerization of an ansa-ferrocene with pyrazabole bridge

Jonas Dorr et al.

Summary: Ferrocenes with pyrazabole bridges are chemically robust entities, suitable for synthesizing rigid-rod polymers with redox-active Fe(II) centers and beltene-like n-faces. Oligomers with a number-average molecular weight of Mn = 7.6 kDa and dispersity of = 1.55 were successfully obtained by condensation reaction and Sonogashira-Hagihara-type protocol, indicating an average chain length of about 14 repeating units.

CANADIAN JOURNAL OF CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

peri-Acenoacene Ribbons with Zigzag BN-Doped Peripheries

Marco Franceschini et al.

Summary: In this study, we synthesized BN-doped graphenoid nanoribbons and confirmed their structure and topology through experimental methods. Additionally, we discovered that these nanoribbons exhibit unique luminescence properties and excellent electrochemical performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Periphery-Core Strategy to Access a Bowl-Shaped Molecule Bearing Multiple Heteroatoms

Jianrong Wu et al.

Summary: A bowl-shaped compound containing multiple heteroatoms was synthesized through a periphery-core strategy, with a low ratio of carbon atom to heteroatom. Crystallographic analysis confirmed the formation of the bowl-shaped structure, and the presence of heteroatoms resulted in distinct aromaticity compared to its all-carbon congener. The electron-rich buckybowl showed a strong interaction with the electron-deficient fullerene C-60.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Fusion of Aza- and Oxadiborepins with Furans in a Reversible Ring-Opening Process Furnishes Versatile Building Blocks for Extended π-Conjugated Materials

Jonas Bachmann et al.

Summary: This study demonstrates a modular synthesis of difurooxa- and difuroazadiborepins from a common precursor. The resulting bifuran-fused diborepins exhibit stability, highly planar tricyclic structures, and intense blue light emission. The deprotection and transformation into dibrominated building blocks can be achieved in one step and these compounds can be incorporated into pi-extended materials.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

添加到收藏夹

Review Materials Science, Multidisciplinary

Multiple-boron-nitrogen (multi-BN) doped π-conjugated systems for optoelectronics

Xiaobin Chen et al.

Summary: Boron-nitrogen-doped pi-conjugated systems are promising for optoelectronic devices, with multiple-boron-nitrogen (multi-BN) doped systems showing great potential due to their structural uniqueness in applications such as organic light emitting diodes (OLEDs), organic photovoltaics (OPVs), and organic field-effect transistors (OFETs).

JOURNAL OF MATERIALS CHEMISTRY C (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

A BN-Doped Cycloparaphenylene Debuts

Min Chen et al.

Summary: The BN-doped cycloparaphenylene BN-[10]CPP has been synthesized and characterized, showing unique reactivity for selective reduction of the BN heterocycle and producing a macrocyclic paraphenylene 6 with versatile ketone functionality.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dithiophene-Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics

Merian Crumbach et al.

Summary: Access to dithiophene-fused oxadiborepins and the first azadiborepins via a modular synthesis route has been achieved. These new compounds emit intense blue light, some demonstrating fluorescence quantum yields close to unity. The weak aromatic character of the novel 1,2,7-azadiborepin ring was demonstrated through in-depth theoretical investigations using nucleus-independent chemical shift (NICS) scans and anisotropy of the induced current density (ACID) calculations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Facile Synthesized Polymer Featuring B-N Covalent Bond and Small Singlet-Triplet Gap for High-Performance Organic Solar Cells

Shuting Pang et al.

Summary: The new organic solar cell material PBNT-BDD, featuring B-N covalent bond, is synthesized easily and shows high efficiency when blended with a nonfullerene acceptor, with a low nonradiative recombination energy loss of 0.19 eV.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Quadruply BN-Fused Tetrathia[8]circulenes with Flexible Frameworks: Synthesis, Structures and Properties

Shuhei Akahori et al.

Summary: The quadruply BN-fused tetrathia[8]circulenes were synthesized through four-fold electrophilic borylation, exhibiting crystal polymorphism in the solid state with both planar and saddle conformations. Experimental and theoretical studies show that the weaker aromaticity of azaborine compared with benzene results in increased flexibility of the BN-fused tetrathia[8]circulenes.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Design, Synthesis and Hydrogen Bonding of B3N6-[4]Triangulene

Mengna Zhao et al.

Summary: The B3N6-[4]triangulene, a key structural unit of BC4N, was successfully synthesized through nitrogen-directed borylation, showing hydrogen-bonding properties. Its slightly bent triangular polycyclic framework consists of 4 pi-electron N-B-N units and forms hydrogen bonds with other molecules like halide or carboxylate anions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Platinum-Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene

Carina Brunecker et al.

Summary: The study demonstrates the preparation of unsymmetrical aminoboryl Pt-2(I) complexes through B-N coupling, leading to the formation of a unique cyclization product. In contrast, a similar reaction results in the formation of a complex bridged by a linear BNBN isostere of butatriene. Structural and computational data confirm pi electron delocalization over the entire BNBN unit.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Crystalline B4N2 Dewar Benzene as a Building Block for Conjugated B,N-Chains

Kei Ota et al.

Summary: Research has been done on Dewar benzene and its inorganic congeners since its first synthesis in 1962. The development of an isolable B4N2 Dewar benzene has been reported, showing potential for constructing conjugated B,N chains. Structural and computational studies confirmed the unique characteristics of this compound and its potential applications in organic chemistry.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Organic

Synthesis, structure and properties of semi-internally BN-substituted annulated thiophenes

Dawei Tian et al.

Summary: This study presents the synthesis of a novel series of semi-internally BN-substituted annulated thiophenes and explores their structural properties, as well as their potential applications in organic synthesis. The reactivity of these compounds towards organolithium compounds and Br-2 has been investigated, along with the further functionalization through Suzuki couplings. The photophysical properties of these BN-substituted annulated thiophenes were also analyzed using UV-vis and fluorescence spectroscopy techniques.

ORGANIC CHEMISTRY FRONTIERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

BNB-doped phenalenyls - aromaticity switch upon one-electron reduction

Merian Crumbach et al.

Summary: The synthesis of fully aromatic, luminescent, and highly robust BNB-doped phenalenyls, isoelectronic to the phenalenyl cation, was successfully achieved. B-Fluoromesityl-substitution resulted in fluorescence within a narrow range and a significant increase in reduction potential. Detailed theoretical investigations unveiled an intramolecular aromaticity switch upon one-electron reduction.

CHEMICAL COMMUNICATIONS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

BN-Embedded Polycyclic Aromatic Hydrocarbon Oligomers: Synthesis, Aromaticity, and Reactivity

Yijing Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Polymer Science

Hybrid 2D nanofibers based on poly(ethylene oxide)/polystyrene matrix and poly(ferrocenylphosphinoboranes) as functional agents

Viraj P. Nirwan et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tailored self-assembled photocatalytic nanofibres for visible-light-driven hydrogen production

Jia Tian et al.

NATURE CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Introducing Perylene as a New Member to the Azaborine Family

Tanja Kaehler et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

BN- and BO-Doped Inorganic-Organic Hybrid Polymers with Sulfoximine Core Units

Felix Brosge et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Late-stage functionalization of BN-heterocycles

Cameron R. McConnell et al.

CHEMICAL SOCIETY REVIEWS (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Boron-based stimuli responsive materials

Soren K. Mellerup et al.

CHEMICAL SOCIETY REVIEWS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

One-Shot Multiple Borylation toward BN-Doped Nanographenes

Kohei Matsui et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

From Monodisperse Thienyl- and Furylborane Oligomers to Polymers: Modulating the Optical Properties through the Hetarene Ratio

Artur Lik et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cyclolinear Oligo- and Poly(iminoborane)s: The Missing Link in Inorganic Main-Group Macromolecular Chemistry

Ozan Ayhan et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

添加到收藏夹

Review Chemistry, Multidisciplinary

The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications

Zachary X. Giustra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

9,10-Azaboraphenanthrene-containing small molecules and conjugated polymers: synthesis and their application in chemodosimeters for the ratiometric detection of fluoride ions

Weidong Zhang et al.

CHEMICAL SCIENCE (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic B-C Coupling by Si/B Exchange: A Versatile Route to π-Conjugated Organoborane Molecules, Oligomers, and Polymers

Artur Lik et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Scalable and uniform 1D nanoparticles by synchronous polymerization, crystallization and self-assembly

Charlotte E. Boott et al.

NATURE CHEMISTRY (2017)

添加到收藏夹

Article Polymer Science

Borazine-based inorganic-organic hybrid cyclomatrix microspheres by silicon/boron exchange precipitation polycondensation

Nicolas A. Riensch et al.

POLYMER CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Poly(p-phenylene iminoborane): A Boron-Nitrogen Analogue of Poly(p-phenylene vinylene)

Thomas Lorenz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Article Polymer Science

Stimulus-Responsive Release from Poly(ferrocenylsilane) Nanocontainers

Laura Thomi et al.

MACROMOLECULES (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Poly(iminoborane)s: An Elusive Class of Main-Group Polymers?

Ozan Ayhan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Dehydrocoupling and Silazane Cleavage Routes to Organic-Inorganic Hybrid Polymers with NBN Units in the Main Chain

Thomas Lorenz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Multifunctional polymetallaynes: properties, functions and applications

Cheuk-Lam Ho et al.

CHEMICAL SOCIETY REVIEWS (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Polymers with pendant ferrocenes

Rudolf Pietschnig

CHEMICAL SOCIETY REVIEWS (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Polyferrocenylsilanes: synthesis, properties, and applications

Rebekah L. N. Hailes et al.

CHEMICAL SOCIETY REVIEWS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

B=N Units as Part of Extended π-Conjugated Oligomers and Polymers

Holger Helten

CHEMISTRY-A EUROPEAN JOURNAL (2016)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Efficient synthetic methods for the installation of boron-nitrogen bonds in conjugated organic molecules

Matthew M. Morgan et al.

DALTON TRANSACTIONS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Regioregular Synthesis of Azaborine Oligomers and a Polymer with a syn Conformation Stabilized by N-H•••π Interactions

Andrew W. Baggett et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Incorporation of polycyclic azaborine compounds into polythiophene-type conjugated polymers for organic field-effect transistors

Xiao-Ye Wang et al.

CHEMICAL COMMUNICATIONS (2015)

添加到收藏夹

Article Multidisciplinary Sciences

Multidimensional hierarchical self-assembly of amphiphilic cylindrical block comicelles

Huibin Qiu et al.

SCIENCE (2015)

添加到收藏夹

Article Polymer Science

Metallopolymer-Based Shape Anisotropic Nanoparticles

Bernhard V. K. J. Schmidt et al.

ACS MACRO LETTERS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Breathing Pores on Command: Redox-Responsive Spongy Membranes from Poly(ferrocenylsilane)s

Kaihuan Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chiral Bora[1]ferrocenophanes: Syntheses, Mechanistic Insights, and Ring-Opening Polymerizations

Saeid Sadeh et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

添加到收藏夹

Article Polymer Science

The Renaissance of Side-Chain Ferrocene-Containing Polymers: Scope and Limitations of Vinylferrocene and Ferrocenyl Methacrylates

Markus Gallei

MACROMOLECULAR CHEMISTRY AND PHYSICS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Large-Area Nanosquare Arrays from Shear-Aligned Block Copolymer Thin Films

So Youn Kim et al.

NANO LETTERS (2014)

添加到收藏夹

Article Polymer Science

Enlarging the Toolbox: Epoxide Termination of Polyferrocenylsilane (PFS) as a Key Step for the Synthesis of Amphiphilic PFS-Polyether Block Copolymers

Adrian Natalello et al.

ACS MACRO LETTERS (2013)

添加到收藏夹

Review Chemistry, Multidisciplinary

Functional Block Copolymers: Nanostructured Materials with Emerging Applications

Felix H. Schacher et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Review Chemistry, Physical

Functional soft materials from metallopolymers and metallosupramolecular polymers

George R. Whittell et al.

NATURE MATERIALS (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Monodisperse cylindrical micelles by crystallization-driven living self-assembly

Joe B. Gilroy et al.

NATURE CHEMISTRY (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

B-N as a C-C substitute in aromatic systems

Michael J. D. Bosdet et al.

CANADIAN JOURNAL OF CHEMISTRY (2009)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ferrocenylhydridoborates: Synthesis, Structural Characterization, and Application to the Preparation of Ferrocenylborane Polymers

Matthias Scheibitz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

添加到收藏夹

Article Polymer Science

Soluble poly(ferrocenylenevinylene) with t-butyl substituents on the cyclopentadienyl ligands via ring-opening metathesis polymer ization

Georgeta Masson et al.

MACROMOLECULES (2008)

添加到收藏夹

Article Multidisciplinary Sciences

Cylindrical block copolymer micelles and co-micelles of controlled length and architecture

Xiaosong Wang et al.

SCIENCE (2007)

添加到收藏夹

Article Polymer Science

π-Conjugated polyphenylenes with diazaborole side chains synthesized via 1,2-phenylenediamine polymer

Isao Yamaguchi et al.

MACROMOLECULES (2007)

添加到收藏夹

Article Chemistry, Multidisciplinary

A synthetic route to borylene-bridged poly(ferrocenylene)s

JB Heilmann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

添加到收藏夹

Article Polymer Science

Synthesis and ring-opening metathesis polymerization of aryl-substituted 1,1′-(1,3-butadienylene)ferrocenes

RW Heo et al.

MACROMOLECULES (2005)

添加到收藏夹

Review Polymer Science

1,1-dimethylsilacyclobutane-mediated living anionic block copolymerization of [1]dimethylsilaferrocenophane and methyl methacrylate

C Kloninger et al.

MACROMOLECULES (2004)

添加到收藏夹

Article Chemistry, Multidisciplinary

Direct writing of patterned ceramics using electron-beam lithography and metallopolymer resists

SB Clendenning et al.

ADVANCED MATERIALS (2004)

添加到收藏夹

Article Chemistry, Physical

Nanostructure engineering by templated self-assembly of block copolymers

JY Cheng et al.

NATURE MATERIALS (2004)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis and characterization of soluble poly (ferrocenylenearylene)s from condensation of dilithio bis(alkylcyclopentadienide) arenes with iron(II) halides: A general route to conjugated poly(metallocene)s

GE Southard et al.

ORGANOMETALLICS (2001)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes

A Berenbaum et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.