Synthesis of cordierite using municipal solid waste incineration fly ash as one additive for enhanced catalytic oxidation of volatile organic compounds

Municipal solid waste incineration (MSWI) fly ash is a hazardous waste, which needs various recycling in order to reach net-zero waste. This work aimed to synthesize cordierite using MSWI fly ash as one additive and investigate influence of the additive on properties of the cordierite. As a result, the cordierite was successfully synthesized when the additive weight ratio was <15 % and the synthesis strategy was universally feasible for 14 kinds of different MSWI fly ashes. As a heat accumulator, the cordierite attained compressive strength of 42.1 MPa, water absorption of 26 %, bulk density of 1.87 g & sdot;cm(-3), and open porosity of 47 %. After five cycles of thermal impact at 1200 degree celsius, the strength was only decreased by 15 %. These properties were comparable to a commercial cordierite. As a catalyst carrier, after loading Mn and Cu species, the cordierite removed 100 % of toluene at 250 degree celsius. In comparison, a commercial cordierite only got a removal of 34.4 %. The enhanced activity was attributed to co-existing spinel and bytownite as well as imbedded Zn and Cu in the MSWI fly ash-added cordierite. Therefore, this work devotes to hazardous recycling, green development, and cycled economy.

Automated summary

This study successfully synthesized cordierite using MSWI fly ash as an additive and improved its properties. The cordierite showed promising performance as a heat accumulator and catalyst carrier, surpassing the commercial cordierite in terms of strength and pollutant removal efficiency.