期刊
JOURNAL OF ENERGY STORAGE
卷 74, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.est.2023.109208
关键词
Lithium -ion battery; Porous composite current collector; Electroless Cu deposition; Polymer; Through -hole array
This article develops lightweight and flexible current collectors by laser drilling polyimide film substrates to create through-hole arrays. Three-dimensional conductive paths are formed by electroless copper deposition on the polyimide films. The current collectors exhibit higher electrode mass-specific capacity and better tensile deformation performance compared to commercial copper foil in LIBs.
The current collector is a critical component of lithiumion batteries (LIBs). Herein, copper-coated polymer films (P@Cu) with through-hole arrays are developed lightweight and flexible current collectors. The through-hole arrays are created by laser drilling the polyimide film substrate. P@Cu composite current collectors are fabricated by electroless Cu deposition on polyimide films with through-hole arrays, which form three-dimensional conductive paths. As the anode current collector for LIBs, P@Cu exhibit a total electrode mass-specific capac-ity that is 54.58 % higher than that of the commercial Cu foil. Due to the polyimide substrate, the tensile deformation of P@Cu is 6.69 % higher than that of the commercial Cu foil. After 30,000 bending cycles, the conductivity of P@Cu is only reduced by 3.39 %, while the commercial Cu foil current collectors have broken by this point. The P@Cu composite foils with through-hole arrays are high-performance lightweight and flexible current collectors for LIBs.
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