4.8 Article

Photo-enzyme catalysis enabled E → Z isomerization of alkenes

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Biotechnology & Applied Microbiology

Photocatalyst-enzyme hybrid systems for light-driven biotransformation

Nan Yang et al.

Summary: Enzyme and photocatalyst hybrid systems have high efficiency under environmentally friendly conditions and can achieve various light-driven biotransformation. This review classifies existing photocatalyst-enzyme hybrid systems based on different hybridizing modes and discusses current challenges and potential strategies. Additionally, the future prospects of this field are provided.

BIOTECHNOLOGY ADVANCES (2022)

Article Multidisciplinary Sciences

Deracemization through photochemical E/Z isomerization of enamines

Mouxin Huang et al.

Summary: This study presents a distinctive photochemical E/Z isomerization strategy for the deracemization of α-branched aldehydes, which involves the use of simple aminocatalysts and readily available photosensitizers. The method enables the direct transformation of racemic α-branched aldehydes into enantiopure α-tertiary carbonyls with high selectivity.

SCIENCE (2022)

Article Spectroscopy

Binding parameters and molecular dynamics of Trypsin-Acid Yellow 17 complexation as a function of concentration

Elham Yadollahi et al.

Summary: This study investigates the interaction between Acid Yellow 17 and trypsin, revealing that the presence of this color decreases the absorption and fluorescence intensity of trypsin, as well as reduces the percent of turn, coil, and alpha-helix in trypsin structure. The computational study confirms these findings by showing that the interaction between this color and trypsin leads to less compactness in the trypsin structure.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2022)

Article Chemistry, Physical

Development of a Metal- and Oxidant-Free Enzyme-Photocatalyst Hybrid System for Highly Efficient C-3 Acylation Reactions of Indoles with Aldehydes

Yuan Yu et al.

Summary: An enzyme-photocatalyst hybrid system has been developed for aldehyde-based indole C-3 acylation. This system successfully synthesized a variety of indole C-3 acylated products under mild conditions and achieved indole derivatization. It provides a new strategy for the development of photoenzyme catalysis fields.

ACS CATALYSIS (2022)

Review Biochemistry & Molecular Biology

Photo-biocatalytic Cascades: Combining Chemical and Enzymatic Transformations Fueled by Light

Fatma Feyza Ozgen et al.

Summary: The use of light to drive biocatalytic reactions presents challenges such as incompatibility between enzymes and photocatalysts, as well as the formation of reactive radicals upon illumination. Overcoming these challenges requires the development of more effective strategies and methods.

CHEMBIOCHEM (2021)

Article Biochemistry & Molecular Biology

Fast and high-efficiency synthesis of 2-substituted benzothiazoles via combining enzyme catalysis and photoredox catalysis in one-pot

Zeng-Jie Yang et al.

Summary: By combining enzymatic and visible-light catalysis, an efficient and green method for synthesizing 2-substituted benzothiazoles has been developed, achieving high yields in a short amount of time with nearly 100% atomic utilization. This method showcases the potential of harnessing the catalytic activity of enzymes and visible light for organic synthesis, without the need for additional oxidants or metals, making it environmentally friendly.

BIOORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Engineering Fatty Acid Photodecarboxylase to Enable Highly Selective Decarboxylation of trans Fatty Acids

Danyang Li et al.

Summary: This research engineered a fatty acid photo-decarboxylase to selectively eliminate trans fatty acids from foods by enhancing the electronic interaction between the residues and the substrate, effectively improving selectivity. This method provides a safe, easy, and eco-friendly approach to removing trans fatty acids from edible oils.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Heteroleptic Copper-Based Complexes for Energy-Transfer Processes: E → Z Isomerization and Tandem Photocatalytic Sequences

Corentin Cruche et al.

Summary: Rare energy-transfer processes involving copper complexes were explored in this study. By utilizing the optimized heteroleptic copper complex Cu(bphen)(XantPhos)BF4, photosensitized E -> Z isomerization of olefins was demonstrated. The XantPhos ligand provided sensitizers with improved catalyst stability, and the bphen ligand lengthened the excited-state lifetime. Successful photoisomerization reactions were conducted on a series of 25 di- and trisubstituted alkenes.

ACS CATALYSIS (2021)

Article Chemistry, Organic

Copper-Photocatalyzed Contra-Thermodynamic Isomerization of Polarized Alkenes

Thibaud Bregent et al.

ORGANIC LETTERS (2020)

Article Spectroscopy

Comparative studies on the interaction of nine flavonoids with trypsin

Xiangrong Li et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2020)

Article Chemistry, Multidisciplinary

Photocatalyst-free visible light promoted E → Z isomerization of alkenes

Jianbin Xu et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

The Hitchhiker's guide to biocatalysis: recent advances in the use of enzymes in organic synthesis

Roger A. A. Sheldon et al.

CHEMICAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Light-Driven Kinetic Resolution of α-Functionalized Carboxylic Acids Enabled by an Engineered Fatty Acid Photodecarboxylase

Jian Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Physical

Photo-Biocatalysis: Biotransformations in the Presence of Light

Luca Schmermund et al.

ACS CATALYSIS (2019)

Article Chemistry, Organic

Photocatalytic E → Z Isomerization of β-Ionyl Derivatives

Keith Livingstone et al.

ORGANIC LETTERS (2019)

Article Chemistry, Multidisciplinary

One Photocatalyst, n Activation Modes Strategy for Cascade Catalysis: Emulating Coumarin Biosynthesis with (-)-Riboflavin

Jan B. Metternich et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Multidisciplinary

A Bio-Inspired, Catalytic E → Z Isomerization of Activated Olefins

Jan B. Metternich et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Organic

Stereoselective Synthesis of Z-α,β-Unsaturated Sulfones Using Peterson Reagents

Kaori Ando et al.

ORGANIC LETTERS (2015)

Article Chemistry, Multidisciplinary

Broadly Applicable Z- and Diastereoselective Ring-Opening/Cross-Metathesis Catalyzed by a Dithiolate Ru Complex

Ming Joo Koh et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Photocatalytic Hydrodefluorination: Facile Access to Partially Fluorinated Aromatics

Sameera M. Senaweera et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins

Brendan L. Quigley et al.

CHEMICAL SCIENCE (2014)

Article Chemistry, Multidisciplinary

Chelated Ruthenium Catalysts for Z-Selective Olefin Metathesis

Koji Endo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Multidisciplinary Sciences

Catalytic Z-selective olefin cross-metathesis for natural product synthesis

Simon J. Meek et al.

NATURE (2011)

Article Chemistry, Multidisciplinary

Nanoscale Chiral Rod-like Molecular Triads Assembled from Achiral Polyoxometalates

Jin Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Medicinal

Novel A-ring and B-ring modified combretastatin A-4 (CA-4) analogues endowed with interesting cytotoxic activity

Daniele Simoni et al.

JOURNAL OF MEDICINAL CHEMISTRY (2008)

Review Chemistry, Multidisciplinary

Biocatalysis in ionic liquids

Fred van Rantwijk et al.

CHEMICAL REVIEWS (2007)

Review Physiology

The retinal pigment epithelium in visual function

O Strauss

PHYSIOLOGICAL REVIEWS (2005)

Article Chemistry, Organic

Electronic detection of the enzymatic degradation of starch

A Star et al.

ORGANIC LETTERS (2004)

Article Chemistry, Organic

CP2TiCl2-catalyzed hydroalumination of internal alkynes:: an access to (Z)-olefins

A Parenty et al.

TETRAHEDRON LETTERS (2002)

Article Chemistry, Organic

Total synthesis of microtubule-stabilizing agent (-)-laulimalide

AK Ghosh et al.

JOURNAL OF ORGANIC CHEMISTRY (2001)

Review Multidisciplinary Sciences

Enzymes for chemical synthesis

KM Koeller et al.

NATURE (2001)

Review Multidisciplinary Sciences

Industrial biocatalysis today and tomorrow

A Schmid et al.

NATURE (2001)

Article Chemistry, Multidisciplinary

Evolution of a gram-scale synthesis of (+)-discodermolide

AB Smith et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

Article Chemistry, Multidisciplinary

Rhodium- or iridium-catalyzed trans-hydroboration of terminal alkynes, giving (Z)-1-alkenylboron compounds

T Ohmura et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)