☆ 4.6 Article

Stannaborates: tuning the ion conductivity of dodecaborate salts with tin substitution

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Physical

Investigating the Potential of Alkali Metal Plumba-closo-Dodecaborate (B11H11Pb2-) Salts as Solid-State Battery Electrolytes

Thomas A. Hales et al.

Summary: Metal dodecaborate salts are highly tunable ion conductors. By replacing a [B-H] unit with a Pb atom, the crystal structure of alkali metal salts can be modified to enhance ion conductivity. Li2B11H11Pb center dot xH2O exhibits similar superionic conductivity to LiCB11H12, while Na2B11H11Pb center dot xH2O and the potassium salt show lower conductivities. The divalent B11H11Pb2- anion in the dodecaborate cage may contribute to the weaker ion conductivity compared to CB11H12-. However, the insertion of a lead atom shows promise in enabling high ion conductivity in the solid state.

JOURNAL OF PHYSICAL CHEMISTRY C (2023)

添加到收藏夹

Review Nanoscience & Nanotechnology

Exploiting the paddle-wheel mechanism for the design of fast ion conductors

Zhizhen Zhang et al.

Summary: This article discusses the fundamental principles of designing superionic conductors and how to enhance cation diffusion through the role of framework anion rotational dynamics. By studying the interaction between cations and anions, it is hoped to achieve super-high conductivity in solid electrolytes.

NATURE REVIEWS MATERIALS (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ionic Conductivity of Nanocrystalline and Amorphous Li10GeP2S12: The Detrimental Impact of Local Disorder on Ion Transport

Lukas Schweiger et al.

Summary: Solids with high Li+ dynamics are crucial for high performance all-solid-state batteries. Molecular dynamics simulations suggest that introducing local disorder can enhance the ionic conductivity of LGPS. However, experimental evidence shows that ball-milling has a negative impact on Li+ ion transport in LGPS.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Physical

Hydrated lithium nido-boranes for solid-liquid hybrid batteries

Diego H. P. Souza et al.

Summary: Hydridoborate salts are promising candidates for solid-state electrolytes in the development of solid-state batteries. Different hydrated LiB11H14 samples show variations in ionic conductivity and oxidative stability. The addition of an ionic liquid or liquid electrolyte at the interface improves the contact between the solid-state electrolyte and the lithium electrode.

SUSTAINABLE ENERGY & FUELS (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Na2B11H13 and Na11(B11H14)3(B11H13)4 as potential solid-state electrolytes for Na-ion batteries

Diego H. P. Souza et al.

Summary: Solid-state sodium batteries are gaining attention for their improved safety, high energy density, and low cost compared to current lithium-ion batteries. Research on new materials like sodium-boranes as solid-state electrolytes is crucial for future battery applications.

DALTON TRANSACTIONS (2022)

添加到收藏夹

Article Chemistry, Physical

Comparative Molecular Dynamics Study of the Roles of Anion-Cation and Cation-Cation Correlation in Cation Diffusion in Li2B12H12 and LiCB11H12

Kartik Sau et al.

Summary: Complex hydrides show high ionic conductivities and are suitable for solid electrolytes in all-solid-state batteries. Research indicates that the reorientational motion of anions plays a crucial role in high cation diffusion, and an entropy-driven order-disorder phase transition is closely related to anion reorientation.

CHEMISTRY OF MATERIALS (2021)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis of closo-CB11H12- Salts Using Common Laboratory Reagents

Amanda Berger et al.

Summary: A novel and cost-effective method has been developed to synthesize the [CB11H12](-) anion with a 40% yield from [B11H14](-), avoiding the use of expensive and dangerous reagents. This method shows excellent reproducibility in product yield and purity, providing a more feasible pathway for commercial application.

INORGANIC CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Physical

Hydrated alkali-B11H14 salts as potential solid-state electrolytes

Diego H. P. Souza et al.

Summary: Metal boron-hydrogen compounds are considered promising candidates for solid electrolytes in the development of all-solid-state batteries, showing high ionic conductivity. An optimised low-cost preparation method has been proposed, resulting in exceptional ionic conductivity of hydrated LiB11H14 and NaB11H14.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

添加到收藏夹

Article Chemistry, Physical

Understanding Superionic Conductivity in Lithium and Sodium Salts of Weakly Coordinating Closo-Hexahalocarbaborate Anions

Mathias Jorgensen et al.

CHEMISTRY OF MATERIALS (2020)

添加到收藏夹

Article Chemistry, Physical

Structural and Dynamical Properties of Potassium Dodecahydro-monocarba-closo-dodecaborate: KCB11H12

Mirjana Dimitrievska et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

添加到收藏夹

Article Chemistry, Physical

Electrochemical Oxidative Stability of Hydroborate-Based Solid State Electrolytes

Ryo Asakura et al.

ACS APPLIED ENERGY MATERIALS (2019)

添加到收藏夹

Article Multidisciplinary Sciences

Multifunctionality of silver closo-boranes

Mark Paskevicius et al.

NATURE COMMUNICATIONS (2017)

添加到收藏夹

Article Chemistry, Physical

Halogenated Sodium-closo-Dodecaboranes as Solid-State Ion Conductors

Bjarne R. S. Hansen et al.

CHEMISTRY OF MATERIALS (2017)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Metal boranes: Progress and applications

Bjarne R. S. Hansen et al.

COORDINATION CHEMISTRY REVIEWS (2016)

添加到收藏夹

Review Chemistry, Physical

All solid-state polymer electrolytes for high-performance lithium ion batteries

Liping Yue et al.

ENERGY STORAGE MATERIALS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Wan Si Tang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

添加到收藏夹

Review Chemistry, Physical

A review of lithium and non-lithium based solid state batteries

Joo Gon Kim et al.

JOURNAL OF POWER SOURCES (2015)

添加到收藏夹

Article Chemistry, Physical

Superionic Conduction of Sodium and Lithium in Anion-Mixed Hydroborates Na3BH4B12H12 and (Li0.7Na0.3)3BH4B12H12

Yolanda Sadikin et al.

ADVANCED ENERGY MATERIALS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Exceptional Superionic Conductivity in Disordered Sodium Decahydro-closo-decaborate

Terrence J. Udovic et al.

ADVANCED MATERIALS (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Thermal Stability of Li2B12H12 and its Role in the Decomposition of LiBH4

Mark P. Pitt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Gregory R. Fulmer et al.

ORGANOMETALLICS (2010)

添加到收藏夹

Article Electrochemistry

Effect of electrolyte composition on lithium dendrite growth

Owen Crowther et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2008)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Stanna-closo-dodecaborate: The crystal structure of [Li(thf)(3)](2)]SnB11H11], vibrational spectroscopy, thermal analysis and DFT calculations

Torben Gaedt et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2007)

添加到收藏夹

Review Chemistry, Physical

Safety mechanisms in lithium-ion batteries

PG Balakrishnan et al.

JOURNAL OF POWER SOURCES (2006)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ruthenium complexes with the stanna-closo-dodecaborate ligand:: Coexistence of η1(Sn) and η3(B-H) coordination

T Gädt et al.

CHEMISTRY-A EUROPEAN JOURNAL (2006)

添加到收藏夹

Article Chemistry, Physical

Lithium ion secondary batteries; past 10 years and the future

Y Nishi

JOURNAL OF POWER SOURCES (2001)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.