期刊
POLYMERS FOR ADVANCED TECHNOLOGIES
卷 -, 期 -, 页码 -出版社
WILEY
DOI: 10.1002/pat.6238
关键词
curing behaviors; epoxy resin; flame retardancy; latent hardener; thermal properties
This study reported a flame-retardant, single-component epoxy resin with satisfactory comprehensive properties, which exhibited great potential for versatile industrial applications.
This work reported a flame-retardant, single-component epoxy resin (EP) via introducing diphenylphosphine (DPP) and benzimidazolyl-substituted cyclotriphosphazene (BICP) into EP. The differential scanning calorimetry (DSC) test showed that the onset curing temperature of DPP/BICP-15/10 was 50 degrees C lower than that of BICP-12 due to the catalytic decomposition effect of DPP toward BICP under heating. Besides, the shelf life of DPP/BICP-15/10 at room temperature reached similar to 14 days, demonstrating good storage stability. EP/DPP/BICP maintained satisfactory thermal properties and showed excellent flame retardancy with a UL-94V-0 classification. Compared with the unmodified EP sample, the peak heat release rate (PHRR) and total heat release (THR) of DPP/BICP-15/13 were decreased by similar to 68.1% and similar to 55.1%, respectively. Hence, this flame-retardant, single-component epoxy resin with satisfactory comprehensive properties exhibited great potential for versatile industrial applications.
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