期刊
RESOURCES CONSERVATION AND RECYCLING
卷 199, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.resconrec.2023.107261
关键词
Electrospinning; Lignocellulose; Nanofibers; Oleogels; PET; Rheology; Waste
This study explores the use of spent coffee grounds and post-consumer PET bottles to produce electrospun composite nanofibers, aiming to develop a new route for upcycling them into high-value oil-based products. By adjusting the ratio of coffee grounds and PET bottles, the properties of the fibers and oleogels can be modified.
Spent coffee grounds (SCG) and post-consumer PET bottles (PETbot) are major waste materials from the food industry. In this work, their use to obtain electrospun composite nanofibers is explored aiming to develop a new route for their upcycling into high added-value oil-based products. Raising the proportion of PETbot increased the average fiber diameter (from 0.36 to 0.89 mu m) and enhanced the tensile properties of the mats. Young's modulus and strain-at-break increased from 5.1 to 32.8 MPa and from 13.8 to 39.4 %, respectively, as the SGC: PETbot weight ratio decreased. Dispersions of the mats in castor oil exhibited shear-thinning and gel-like viscoelastic properties which can be tuned through the SCG:PETbot ratio. Friction coefficient values of result-ing oleogels tested in a tribological contact ranged from 0.165 to 0.092. SCG and PETbot can be used to obtain electrospun nanofibers with oil structuring capabilities while resulting oleogels are proposed as environmentally-friendly alternatives to semisolid lubricants.
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