期刊
CHEMICAL COMMUNICATIONS
卷 59, 期 99, 页码 14626-14635出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc04759h
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Constructing artificial photosynthetic systems for CO2 reduction is a promising pathway to produce carbon-neutral fuels and mitigate the greenhouse effect. However, utilizing earth-abundant catalysts for photocatalytic CO2 reduction remains challenging. Cobalt-based complexes with tripodal ligands are extensively studied as molecular catalysts for CO2 photoreduction, and their progress in electronic/steric tuning and dinuclear design to achieve synergistic effects is discussed.
Construction of artificial photosynthetic systems including CO2 reduction is a promising pathway to produce carbon-neutral fuels and mitigate the greenhouse effect concurrently. However, the exploitation of earth-abundant catalysts for photocatalytic CO2 reduction remains a fundamental challenge, which can be assisted by a systematic summary focusing on a specific catalyst family. Cobalt-based complexes featuring tripodal ligands should merit more insightful discussion and summarization, as they are one of the most examined catalyst families for CO2 photoreduction. In this feature article, the key developments of cobalt-based tripodal complexes as molecular catalysts for light-driven CO2 reduction are discussed to offer an upcoming perspective, analyzing the present progress in electronic/steric tuning through ligand modification and dinuclear design to achieve a synergistic effect, as well as the bottlenecks for further development.
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