☆ 4.8 Review

Advances in Biocarbon and Soft Material Assembly for Enthalpy Storage: Fundamentals, Mechanisms, and Multimodal Applications

SMALL (2023)

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Article Energy & Fuels

Char structure evolution during molten salt pyrolysis of biomass: Effect of temperature

Bin Li et al.

Summary: Pyrolysis of wheat straw in Li2CO3-K2CO3 binary salt enhanced charring reactions and resulted in higher biochar yield. The structure of biochar showed different trends at different pyrolysis temperatures, with the C content increasing and the H and O contents decreasing at 450-550°C, and the decrease in H content and increase in O content and decrease in C content at 600-700°C. The enhanced activation effect of the molten salt at higher temperature resulted in the formation of more porous structures and enriching the biochar with O-containing groups.

FUEL (2023)

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Article Materials Science, Multidisciplinary

Biomass Homogeneity Reinforced Carbon Aerogels Derived Functional Phase-Change Materials for Solar-Thermal Energy Conversion and Storage

Qingfeng Zhang et al.

Summary: A novel composite phase-change material was developed by encapsulating polyethylene glycol in a functional form stable composite carbon aerogel structure. The composite phase-change material exhibited good structure stability, comprehensive energy storage performance, and enhanced thermal response rate. This strategy can be efficiently used to develop novel composite phase-change materials with improved comprehensive thermal performance and high light-thermal conversion.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

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Article Chemistry, Multidisciplinary

Fe3O4-Functionalized Κ-Carrageenan/Melanin Hybrid Aerogel- Supported Form-Stable Phase-Change Composites with Excellent Solar/Magnetic-Thermal Conversion Efficiency and Enhanced Thermal Conductivity

Linzhao Jin et al.

Summary: Impregnating organic phase-change materials (PCMs) into biomass-derived aerogels effectively solves the liquid leakage issue of solid-liquid PCMs. However, the inefficient solar-thermal conversion and low thermal conductivity hinder their large-scale applications in solar utilization. In this study, novel form-stable PCM composites (CMPCM-Fe) with enhanced thermal conductivity and excellent solar and magnetic-driven thermal energy conversion and storage efficiency were fabricated through vacuum impregnation. The introduction of Fe3O4 nanoparticles improved the thermal conductivity (increased by 55.3%) and solar-thermal conversion efficiency (up to 93.5%) of CMPCM-Fe, making it suitable for multi-response thermal management.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

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Article Chemistry, Multidisciplinary

Fabrication of Biobased Advanced Phase Change Material and Multifunctional Composites for Efficient Thermal Management

Wondu Lee et al.

Summary: In this study, a novel phase change material (PCM) of erythritol (ET)-grafted polylactic acid (PLA) (ETPLA) was prepared to combine the properties of a biobased thermoplastic polymer and the heat storage of PCM. The thermally conductive ETPLA composites were fabricated using a hybrid filler system of oxidized carbon fiber (CF-OH) and aluminum nitride (AlN) through injection molding. The composites exhibited high through-plane thermal conductivity, enhanced mechanical properties, and a large latent heat, making them suitable for thermal management systems of next-generation electronic devices.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

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Article Chemistry, Multidisciplinary

Adaptive and Adjustable MXene/Reduced Graphene Oxide Hybrid Aerogel Composites Integrated with Phase-Change Material and Thermochromic Coating for Synchronous Visible/Infrared Camouflages

Bai-Xue Li et al.

Summary: A trilayer composite material integrating various functions such as thermal insulation, heat absorption, solar/electro-thermal conversions, and thermochromism has been developed for visible and infrared dual camouflages. It can hide target signatures from infrared images and visually blend with the surroundings in different scenarios, providing an adaptive and adjustable camouflage solution against multiband surveillance in complex environments.

ACS NANO (2023)

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Review Chemistry, Multidisciplinary

Technology Roadmap for Flexible Sensors

Yifei Luo et al.

Summary: Humans are increasingly relying on flexible sensors to address challenges and improve quality of life in the digital and big data era. However, the market adoption of flexible sensors is still limited despite advancements in research. In this paper, we identify the bottlenecks hindering the maturation of flexible sensors and propose potential solutions to expedite their deployment and commercialization.

ACS NANO (2023)

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Review Chemistry, Multidisciplinary

Green Flexible Electronics: Natural Materials, Fabrication, and Applications

Zengyu Hui et al.

Summary: The emergence of plastic electronics has met the increasing demand for flexible electronics but has also caused severe ecological problems. To achieve a green and eco-friendly concept, researchers have been exploring flexible electronics based on natural materials. This review summarizes recent advances in the design and fabrication of green flexible electronics, covering various natural materials and their derivatives, fabrication techniques, and a wide range of devices and applications. The challenges and opportunities of employing natural materials in green flexible electronics are also discussed.

ADVANCED MATERIALS (2023)

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Review Engineering, Environmental

Construction and application of biochar-based composite phase change materials

Qianwei Liang et al.

Summary: Biomass-synthesized biochar has abundant pore structure and adsorption capacity, which can be used to encapsulate phase change materials for carbon sequestration and have broad application prospects in solar energy utilization, energy-saving buildings, and environmental temperature control.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Engineering, Environmental

Anisotropically conductive phase change composites enabled by aligned continuous carbon fibers for full-spectrum solar thermal energy harvesting

Pengfei Zhang et al.

Summary: This study proposes a simple and scalable approach to develop anisotropically conductive phase change composites (PCCs) by fabricating and embedding aligned continuous carbon fibers (CFs) in paraffin wax (PW)/olefin block copolymer (OBC) blends. The PCCs exhibit excellent anisotropic thermal conductivity and high full-spectrum solar absorptance, which enable high photothermal efficiencies for solar thermal energy harvesting.

CHEMICAL ENGINEERING JOURNAL (2023)

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Review Chemistry, Multidisciplinary

Skin-Interfaced Wearable Sweat Sensors for Precision Medicine

Jihong Min et al.

Summary: Wearable sensors have the potential to revolutionize personalized healthcare by enabling continuous and noninvasive monitoring of analytes in sweat. However, there are challenges in improving sweat extraction and sensing capabilities, developing comfortable and reliable wearable devices, and understanding the clinical value of sweat analytes for biomarker discovery.

CHEMICAL REVIEWS (2023)

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Review Chemistry, Multidisciplinary

Phase Change Thermal Storage Materials for Interdisciplinary Applications

Ge Wang et al.

Summary: Functional phase change materials (PCMs) have attracted tremendous attention for their ability to store and release thermal energy. In this review, we discuss the mechanisms of thermal storage, transfer, and conversion, and summarize the latest advances in interdisciplinary applications of PCMs. We also explore the correlations between microscopic structures and thermophysical properties of composite PCMs. Current challenges and future prospects are highlighted to encourage further research in this field.

CHEMICAL REVIEWS (2023)

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Article Energy & Fuels

Construction of Wheat Bran Biomass Porous Aerogel by Starch Pasting for Fabrication of Phase Change Composites with High Latent Heat Storage and Temperature Regulation

Xiugui Zhang et al.

Summary: In order to improve the applicability in some extreme environments, research efforts have been conducted using carrier materials loaded with phase-change materials (PCMs). Wheat bran, which is often ignored and discarded, was utilized as a biomass carrier to incorporate polyethylene glycol (PEG) and fabricate composite PCMs.

ENERGY & FUELS (2023)

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Review Energy & Fuels

Recent Progress and Future Directions of Biomass-Derived Hierarchical Porous Carbon: Designing, Preparation, and Supercapacitor Applications

Yufeng Yin et al.

Summary: In the past decades, the depletion of fossil energy, environmental pollution, and greenhouse gas emissions have led to health threats and ecological imbalances. This has prompted researchers to explore green and sustainable supercapacitor energy storage and conversion systems using biomass porous carbon. This paper provides a comprehensive assessment of the correlation between biomass porous carbon properties and electrochemical energy storage performances of supercapacitors, summarizing recent advances in biomass porous carbon synthesis and discussing various strategies and mechanisms used. It also reviews the relationships between biomass porous carbon properties and electrochemical performances, and explores techniques to address the low energy density problem.

ENERGY & FUELS (2023)

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Article Multidisciplinary Sciences

Microwave-assisted design of nanoporous graphene membrane for ultrafast and switchable organic solvent nanofiltration

Junhyeok Kang et al.

Summary: Layered two-dimensional materials with interlayer structures can be used for organic solvent nanofiltration (OSN) membranes due to their precise molecular sieving ability and stability in harsh conditions. In this study, nanoporous graphene (NG) with a high density of sp(2) carbon domains was synthesized by microwave treatment and showed ultrafast organic solvent permeance and excellent stability. The membrane's molecular weight cut-off (MWCO) can be switched depending on the solvent type, allowing for the separation of multiple organic mixtures using a single membrane.

NATURE COMMUNICATIONS (2023)

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Article Multidisciplinary Sciences

Acidic graphene organocatalyst for the superior transformation of wastes into high-added-value chemicals

Aby Cheruvathoor Poulose et al.

Summary: This study presents a reusable graphene catalyst that can convert glycerol, produced from biomass fermentation, to high-value chemicals at room temperature without solvents. The catalyst shows excellent activity and selectivity for glycerol conversion to solketal, and it can also convert oils to biodiesel.

NATURE COMMUNICATIONS (2023)

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Article Multidisciplinary Sciences

Renewable formate from sunlight, biomass and carbon dioxide in a photoelectrochemical cell

Yuyang Pan et al.

Summary: The sustainable production of chemicals and fuels from solar energy and renewable carbon sources has been demonstrated through photoelectrochemistry. Biomass wastes and CO2 feedstocks were used to produce formate, with high Faradaic efficiencies over 85%. This solar-driven production system reduces cell voltage and achieves a record-high yield of formate.

NATURE COMMUNICATIONS (2023)

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Article Chemistry, Multidisciplinary

Improved Anisotropic Thermal Transfer Property of Form-Stable Phase Change Material Supported by 3D Bionic Porous Copper

Pan Guo et al.

Summary: In this study, a novel biomimetic-structured three-dimensional porous Cu skeleton with wood texture and cell wall structure was prepared by the wood template method to support organic phase change materials (PCMs) with low heat transfer and unstable morphology. The bionic porous Cu maintained the porous channel structure of wood, resulting in highly improved anisotropic thermal conductivity and good antileakage characteristics of the composite PCMs. The thermal conductivity of the composites in the vertical direction and the horizontal direction reached up to 26.8 and 9.2 times that of paraffin wax, respectively. This work provides a promising strategy for designing anisotropic thermal conductive structures of composite PCMs, with potential applications in thermal energy storage and thermal management.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

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Article Chemistry, Multidisciplinary

Flame-Retardant and Form-Stable Delignified Wood-Based Phase Change Composites with Superior Energy Storage Density and Reversible Thermochromic Properties for Visual Thermoregulation

Jiuao Wang et al.

Summary: Wood-based form-stable phase change materials (PTPCMs) with high energy storage density, excellent flame retardancy, and real-time and visual reversible thermochromic properties were successfully fabricated by impregnating a non-formaldehyde flame retardant (APA) and a thermochromic compound into delignified wood. The PTPCMs showed high thermal energy storage density and reliable thermal stability. The flame retardancy of PTPCMs increased with the concentration of APA. The reversible thermochromic properties allowed for the visualization of the phase transition process.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2023)

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Article Nanoscience & Nanotechnology

Flame-Retardant and Form-Stable Phase-Change Composites Based on Phytic Acid/ZnO-Decorated Surface-Carbonized Delignified Wood with Superior Solar-Thermal Conversion Efficiency and Improved Thermal Conductivity

Hao Yue et al.

Summary: To efficiently exploit solar-thermal energy, the development of form-stable phase-change material (PCM) composites with superior solar-thermal storage efficiency, excellent flame retardancy, and improved thermal conductivity is crucial. This study constructed phytic acid (PA)-modified, zinc oxide-deposited, and surface-carbonized delignified woods (PZCDWs) and fabricated novel form-stable PCMs (PZPCMs) by impregnating n-docosane into PZCDWs, resulting in PCMs with superior performance in solar-thermal energy storage, flame retardancy, and thermal conductivity. The addition of PA further enhanced the flame retardancy of PZPCMs, making these renewable wood-based PCM composites promising for solar energy harnessing and thermal modulation technologies.

ACS APPLIED MATERIALS & INTERFACES (2023)

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Article Chemistry, Multidisciplinary

Strong, Shape-Memory Lignocellulosic Aerogel via Wood Cell Wall Nanoscale Reassembly

Jonas Garemark et al.

Summary: In this work, strong shape-memory bio-aerogels with high specific surface areas and low thermal conductivity were prepared through a one-step treatment of native wood. The methodology developed for nanoscale reassembly of wood is a significant advancement for the design of biobased shape-memory aerogels.

ACS NANO (2023)

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Article Energy & Fuels

Unveiling sustainable nano-enabled phase change materials for high thermal stability and energy storage capacity

Dimberu G. Atinafu et al.

Summary: Thermal energy storage and conversion in phase change materials can be improved by adding nanomaterials. In recent years, there has been an increasing focus on developing renewable and sustainable phase-change composites. This study compares and demonstrates the sustainability of different nano-enabled PCMs using Ashby material selection and life-cycle assessment. The assessment shows that biochar-supported paraffin composites have high encapsulation efficiency, shape stability, low energy demand, and affordable price, making them desirable for insulation and building thermal energy management applications.

JOURNAL OF ENERGY STORAGE (2023)

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Article Energy & Fuels

Bamboo-derived phase change material with hierarchical structure for thermal energy storage of building

Xianfeng Yue et al.

Summary: This study uses bamboo-derived materials as the framework for phase change materials, which can reduce energy consumption and increase building energy efficiency. The hierarchical structure of the bamboo-based PCM provides ample space for loading paraffin and prevents leakage, while also having a higher thermal conductivity. The study demonstrates the promising potential of bamboo-based PCMs in building temperature regulation applications.

JOURNAL OF ENERGY STORAGE (2023)

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Review Chemistry, Physical

Nanopolyhybrids: Materials, Engineering Designs, and Advances in Thermal Management

Dimberu G. Atinafu et al.

Summary: The unbalanced growth in energy demand and consumption worldwide has led to the development of advanced materials for high thermal-management capabilities. Nanopolyhybrid design technologies have achieved significant progress in multiresponsive energy harvesting, thermoregulation, energy saving in construction, and miniaturization and integration of electronic systems. This is achieved by integrating nanomaterials and polymers with engineering strategies. The emerging applications of hybrid composites such as personal and electronic thermal management and advanced medical applications are highlighted. Current challenges and future trends and prospects are also summarized.

SMALL METHODS (2023)

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Review Engineering, Environmental

Porous and graphitic structure optimization of biomass-based carbon materials from 0D to 3D for supercapacitors: A review

Xiaohua Zhang et al.

Summary: This review summarizes the recent progress in the preparation methods of biomass-based porous graphitic carbon (BPGC), including activation, catalytic graphitization, and simultaneous activation-graphitization. The mechanisms of structure evolution during activation and graphitization are highlighted. The advances in optimizing and restructuring the microstructure of BPGC from 0D to 3D are presented. The structure-performance correlation of BPGC for supercapacitors is discussed, along with the challenges and opportunities for its further development in energy storage.

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Engineering, Environmental

Cloth-derived anisotropic carbon scroll attached with 2D oriented graphite layers for supporting phase change material with efficient thermal storage

Chengzhi Zhao et al.

Summary: In this study, a novel multistage two-dimensionally oriented porous carbon scroll was designed, which greatly enhanced thermal conductive paths along the carbon sheet and the graphite layer. Phase change composites (PCCs) obtained by impregnating paraffin into the carbon scrolls showed excellent thermal conduction and heat storage properties, stabilized shapes, and high photothermal conversion properties. These PCCs have a lot of potential in the field of solar thermal energy storage and thermal management.

CHEMICAL ENGINEERING JOURNAL (2023)

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Review Chemistry, Multidisciplinary

Biobased Nanomaterials?The Role of Interfacial Interactions for Advanced Materials

Monika Osterberg et al.

Summary: This review summarizes recent advances in biomass-based nanomaterials, with a focus on their surface interactions. Plant biomass-based nanoparticles, such as nanocellulose and lignin derived from industrial side streams, have great potential for developing lightweight, functional, biodegradable, or recyclable materials for a sustainable circular bioeconomy. The control of interactions during particle production and in applications is crucial for achieving optimal properties of the nanoparticles and materials. This article discusses solvent interactions during particle formation and production, as well as interactions with water, polymers, cells, and other components in applications.

CHEMICAL REVIEWS (2023)

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Article Chemistry, Physical

Probing the Diffusion Mechanism of n-Alkanes in Mesoporous Confinement Using Pulsed Field Gradient NMR

Jack H. H. Williams et al.

Summary: Pulsed field gradient NMR experiments were conducted to investigate the diffusion mechanism of liquid n-alkanes confined in mesoporous silicas of different pore diameters. A novel method using mixtures instead of pure liquids was employed to separate the effects of free volume and diffusion mechanism on diffusion coefficients. The diffusion mechanism was found to change with confinement, with Zimm mechanism in bulk liquids, reptation mechanism for C-f < 9, and coexistence of Rouse and reptation mechanisms for C-f between 9 and 34. The critical entanglement chain length significantly reduces in confined liquids compared to bulk.

JOURNAL OF PHYSICAL CHEMISTRY C (2023)

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Article Food Science & Technology

Biochar as a fast track to net zero

Annette L. L. Cowie

Summary: The current capacity of carbon dioxide removal falls short of the requirement to achieve the temperature target set by the Paris Agreement. Biochar derived from crop residues could assist China in reaching its 2060 net zero goal, while also providing health and environmental benefits.

NATURE FOOD (2023)

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Article Chemistry, Multidisciplinary

Space-Confined Electrochemical Reactions and Materials for High-Energy-Density Batteries

Juan Zhang et al.

Summary: Lithium-ion batteries have had a profound impact on global energy transition. To achieve high-energy rechargeable batteries, researchers have improved the energy-storage capability by encapsulating nonintercalation electrode materials into a three-dimensional conductive framework. This confinement preserves the structural and interfacial integrity, suppresses parasitic reactions, and enables efficient charge transfer.

ACCOUNTS OF MATERIALS RESEARCH (2023)

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Article Chemistry, Multidisciplinary

Adaptive and Adjustable MXene/Reduced Graphene Oxide Hybrid Aerogel Composites Integrated with Phase-Change Material and Thermochromic Coating for Synchronous Visible/Infrared Camouflages

Bai-Xue Li et al.

Summary: A trilayer composite material with thermal insulation, heat absorption, solar/electro-thermal conversions, and thermochromism has been fabricated for visible and infrared dual camouflages. This composite material can hide target signatures from infrared images and help the target evade visual surveillance through its green appearance.

ACS NANO (2023)

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Article Engineering, Multidisciplinary

Flexible hierarchical ZnO/AgNWs/carbon cloth-based film for efficient microwave absorption, high thermal conductivity and strong electro-thermal effect

Xiaopeng Han et al.

Summary: Flexible ZnO/carbon cloth (CC@ZnO) films with high microwave absorption performance were prepared, and further coated with silver nanowires to form CC@ZnO/AgNWs/PVA (CAP) films with highly conductive networks. These materials exhibit excellent properties in absorption performance, conductivity, and high-temperature resistance, with potential applications in the protection of wearable electronics.

COMPOSITES PART B-ENGINEERING (2022)

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Article Multidisciplinary Sciences

General synthesis of ultrafine metal oxide/reduced graphene oxide nanocomposites for ultrahigh-flux nanofiltration membrane

Wanyu Zhang et al.

Summary: This study reports a general synthetic method to achieve graphene oxide nanofiltration membranes with tunable interlayer spacing that have high water permeability and selectivity. The authors synthesized ultrafine metal oxide/reduced graphene oxide nanocomposites through a heterogenous nucleation and diffusion-controlled growth process, resulting in membranes with stable performance.

NATURE COMMUNICATIONS (2022)

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Article Multidisciplinary Sciences

Highly efficient and salt rejecting solar evaporation via a wick-free confined water layer

Lenan Zhang et al.

Summary: Recent advances in thermally localized solar evaporation have shown great potential in vapor generation, seawater desalination, wastewater treatment, and medical sterilization. This study demonstrates highly efficient and salt rejecting solar evaporation by manipulating fluidic flow in a wick-free confined water layer. The research elucidates the fundamentals of salt transport and offers a low-cost strategy for high-performance solar evaporation.

NATURE COMMUNICATIONS (2022)

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Review Nanoscience & Nanotechnology

Soft actuators for real-world applications

Meng Li et al.

Summary: Soft actuators are flexible and compliant, making them perfectly suited for interacting with the human body. While they have promising real-world applications, challenges remain in implementing physical intelligence, improving performance and multifunctionality, as well as manufacturing scalability and extending lifetime.

NATURE REVIEWS MATERIALS (2022)

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Article Energy & Fuels

Biomass-based shape-stable phase change materials supported by garlic peel-derived porous carbon for thermal energy storage

Yue Luo et al.

Summary: In this study, a shape-stable phase-change material (SSPCM) was developed using activated garlic peel as a low-cost and environmentally friendly alternative. The SSPCM showed excellent thermal stability, shape stability, and waste heat storage ability, making it a potential candidate for waste heat recovery and recycling applications.

JOURNAL OF ENERGY STORAGE (2022)

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Article Nanoscience & Nanotechnology

Dopamine-Decorated Ti3C2Tx MXene/Cellulose Nanofiber Aerogels Supported Form-Stable Phase Change Composites with Superior Solar-Thermal Conversion Efficiency and Extremely High Thermal Storage Density

Xiaosheng Du et al.

Summary: This study synthesized and analyzed a 2D dopamine-decorated MXene nanosheet with superior solar-thermal conversion and storage performance. By combining it with cellulose nanofibers, a novel biomass-derived PCM composite was prepared. The resulting eMPCMs exhibited high thermal storage density and excellent PCM loading capacity, with significant improvements in solar-thermal conversion and storage efficiency, solar-thermal-electricity conversion capacity, and thermal conductivity.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Nanoscience & Nanotechnology

Radiative Cooling Nanofabric for Personal Thermal Management

Mohammad Irfan Iqbal et al.

Summary: This study develops a nanofabric with special optical properties that can reflect sunlight and transmit mid-infrared radiation, significantly impacting the thermal regulation of the human body in outdoor environments. The nanofabric reduces skin temperature and eliminates heat stress in most climate conditions, making it a feasible solution for better thermoregulation. It also paves the way for energy-free personal cooling technology, meeting the growing demand for healthcare, climate change, and sustainability.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Review Chemistry, Multidisciplinary

Improving Wastewater Treatment by Triboelectric-Photo/Electric Coupling Effect

Feilong Dong et al.

Summary: This paper provides an overview of the potential energies that can be harvested at various stages of the wastewater treatment process and introduces the application of TENG devices for the collection of these neglected energies. The mechanisms and catalytic performances of TENGs coupled with photo/electric catalysis are discussed, and a thorough investigation of TENG devices and their coupled applications is summarized. The concept of the intimate coupling of self-powered photoelectric catalysis and biodegradation is proposed to further improve removal efficiencies in wastewater treatment.

ACS NANO (2022)

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Review Chemistry, Multidisciplinary

Biomass-Derived Carbon for High-Performance Batteries: From Structure to Properties

Yu Sun et al.

Summary: This review summarizes the latest research progress in biomass-derived carbon materials as energy storage materials for batteries, covering structures and mechanisms. It also highlights the challenges and strategies for future development. This is of great importance for researchers to choose appropriate strategies to design biomass-derived carbon materials and promote the application of biomass materials in battery design.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Structural Design and Fabrication of Multifunctional Nanocarbon Materials for Extreme Environmental Applications

Sijia Wu et al.

Summary: This article reviews the critical aspects of structural design and fabrication of nanocarbon materials for extreme environments, as well as their breakthroughs in the fields of wide-temperature structural-material construction, low-temperature energy storage, underwater sensing, and electronics operated at high temperatures.

ADVANCED MATERIALS (2022)

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Article Engineering, Environmental

Encapsulation of dodecane in gasification biochar for its prolonged thermal/shape stability, reliability, and ambient enthalpy storage

Dimberu G. Atinafu et al.

Summary: Latent heat storage based on phase-changing materials (PCMs) is a promising technology for thermal energy storage. However, the practical applications of PCMs are restricted due to their low thermal conductivity and expensive supporting materials. The development of shape-stable composite PCMs using renewable precursors has gained attention. In this study, waste biomass materials were activated and pyrolyzed to produce biochar, which was used for encapsulating organic PCM. The composite materials exhibited improved thermal stability, conductivity, and latent heat retention, making them suitable for thermal-regulation applications.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Thermodynamics

Capric-stearic acid mixture impregnated carbonized waste sugar beet pulp as leak-resistive composite phase change material with effective thermal conductivity and thermal energy storage performance

Ahmet Sari et al.

Summary: The present investigation focuses on developing a potential composite phase change material (PCM) with leak-resistive and high thermal conductivity. By carbonizing sugar beet pulp, a porous framework is created and physically integrated with the capric-stearic acid eutectic mixture (CSEM) to enhance the thermal conductivity and leak resistance of the composite material.

ENERGY (2022)

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Article Environmental Sciences

Preparation and thermal conductivity enhancement of a paraffin wax-based composite phase change material doped with garlic stem biochar microparticles

Teng Xiong et al.

Summary: In this study, low-cost and eco-friendly biochar microparticles were prepared from garlic stems and added to paraffin wax to enhance its thermal conductivity. The results showed that the addition of 5% biochar microparticles significantly increased the thermal conductivity of paraffin wax, with minimal effects on phase change temperature and latent heat capacity.

SCIENCE OF THE TOTAL ENVIRONMENT (2022)

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Article Energy & Fuels

Biomass porous potatoes/MXene encapsulated PEG-based PCMs with improved photo-to-thermal conversion capability

Yu Fang et al.

Summary: Encapsulated phase-change materials (PCMs) have been widely studied in solar thermal energy storage. This study successfully synthesized a series of potatoes phase-change materials (PPMs) through vacuum impregnation method and introduced MXene nanosheets. The results showed improved photo-to-thermal conversion efficiency and PEG adsorption rate in the PPMs.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2022)

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Article Chemistry, Multidisciplinary

Interface Growth of PANI-ZnO Nanohybrids on a Self-Formed Grapefruit Peel Aerogel to Construct a Quick Self-Restored Gas Sensor

Chuang Wang et al.

Summary: Gas sensors based on compound conductive polymers and metal oxides with p-n heterojunctions have attracted a lot of attention. This study introduces a sustainable and highly sensitive gas sensor using a self-formed grapefruit peel aerogel loaded with PANI-ZnO nanohybrids. The sensor demonstrates excellent gas sensing behaviors and high structural stability, and it is capable of detecting formaldehyde at low concentrations and restoring its sensing performance quickly with sunlight exposure.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Applied

Molecular-scale controllable conversion of biopolymers into hard carbons towards lithium and sodium ion batteries: A review

Li-Jing Xie et al.

Summary: This article provides an overview of the chemical structures and preparation methods of biomass-derived hard carbons, highlighting current challenges and future opportunities.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Biomass-derived nanostructured coatings based on cellulose nanofibers-melanin hybrids toward solar-enabled multifunctional energy management

Weiqing Yang et al.

Summary: Solar-to-thermal conversion is an efficient way to convert sunlight into thermal energy. This study designs a cost-effective, scalable, biodegradable nanocomposite for solar-to-thermal applications. By balancing photothermal and water-absorbing capacities, the designed solar evaporator achieves efficient evaporation and improved voltage output.

NANO ENERGY (2022)

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Review Nanoscience & Nanotechnology

Bio-based polymers with performance-advantaged properties

Robin M. Cywar et al.

Summary: Selective transformations of bio-based compounds can lead to the development of new polymers to displace those produced from fossil carbon, with a focus on performance-advantaged bio-based polymers that can encourage industry adoption and offset fossil carbon use in the context of global plastics pollution and climate change.

NATURE REVIEWS MATERIALS (2022)

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Article Energy & Fuels

High power and energy density dynamic phase change materials using pressure-enhanced close contact melting

Wuchen Fu et al.

Summary: The research team proposes an approach to achieve spatial control of the melt-front location of pure phase change materials using pressure-enhanced close contact melting. They demonstrate the effectiveness of this approach using paraffin wax and gallium, with high energy density and power density. This method uses pure and cost-effective materials, overcoming complexities and cost of composite phase change materials.

NATURE ENERGY (2022)

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Article Energy & Fuels

Watermelon Flesh-Derived Carbon Aerogel with Hierarchical Porous Structure for Interfacial Solar Steam Generation

Bo Zhu et al.

Summary: Solar-enabled interfacial steam generation is hindered by high material cost and low evaporation rate. In this study, a 3D carbon aerogel (CA) with hierarchical pores was prepared and utilized as an efficient photothermal material for seawater desalination. The CA showed broad and strong light absorption, and when incorporated into a 3D evaporator, exhibited high evaporation rate and long-term stability under simulated sunlight.

SOLAR RRL (2022)

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Review Chemistry, Multidisciplinary

A Review on Graphene-Based Electromagnetic Functional Materials: Electromagnetic Wave Shielding and Absorption

Yuxing Xia et al.

Summary: EM functional materials, especially graphene-based materials, are crucial in solving EM wave pollution. By designing graphene-based materials with well-controlled microstructures and optimized EM properties, EM energy attenuation and conversion can be significantly improved. This study outlines multiscale design strategies for graphene-based EM functional materials and reviews their applications in EM wave shielding and absorption, with a focus on the latest advances in graphene-based assemblies.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Multidisciplinary Sciences

Dynamic morphological transformations in soft architected materials via buckling instability encoded heterogeneous magnetization

Neng Xia et al.

Summary: A magnetic regulation approach is developed to achieve controllable transformation of morphable structures and uncover their dynamic modulation mechanism and potential applications. By encoding magnetic profiles, magnetic inputs drive various morphological transformations and geometric reconfigurations, allowing for predetermined and controlled buckling states. The dynamic modulations can be applied to build systems with switchable fluidic properties and achieve capabilities such as fluidic manipulation, selective particle trapping, sensitivity-enhanced biomedical analysis, and soft robotics.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Flexible and Biocompatible Silk Fiber-Based Composite Phase Change Material for Personal Thermal Management

Chongwei Wang et al.

Summary: In this study, a flexible and biocompatible composite phase change material (PCM) for wearable personal thermal management was prepared using renewable natural silkworm cocoons and biocompatible capric acid. The results showed that the composite PCM exhibited excellent performance and stability under different environmental conditions.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Energy & Fuels

Nanosilver modified navel orange peel foam/polyethylene glycol composite phase change materials with improved thermal conductivity and photo-thermal conversion efficiency

Shikun Xiao et al.

Summary: This study developed a novel phase change material by using nano-silver modified porous carbon as the carrier and polyethylene glycol as the phase change medium. The experimental results showed that the addition of nano-silver improved the photo-thermal conversion ability, thermal conductivity, and thermal reliability of the material. The prepared phase change material exhibited favorable thermal stability and reusability, making it suitable for applications such as thermal management and solar energy storage.

JOURNAL OF ENERGY STORAGE (2022)

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Article Energy & Fuels

Anisotropic reed-stem-derived hierarchical porous biochars supported paraffin wax for efficient solar-thermal energy conversion and storage

Shu Tian et al.

Summary: Developing and utilizing cheap and widely available biowaste for high-value phase change energy storage is valuable. In this study, reed stems were processed to connect macropore channels through carbonization and enriched micropores. By impregnating with paraffin wax, shape-stable composite phase change materials (CPCMs) with a three-dimensional multi-level pore structure were obtained. The CPCMs exhibited high loading rate, energy storage capacity, and good heat transfer performance. Furthermore, this work contributes to energy saving and carbon emission reduction.

JOURNAL OF ENERGY STORAGE (2022)

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Article Energy & Fuels

Biomass modified boron nitride/polyimide hybrid aerogel supported phase change composites with superior energy storage capacity and improved flame retardancy for solar-thermal energy storage

Rongbiao Shen et al.

Summary: This study develops a form-stable, enhanced thermal conductivity and improved flame retardant phase change composite with superior energy storage capacity and photothermal conversion capability, which effectively absorbs and utilizes solar energy.

SOLAR ENERGY (2022)

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Review Nanoscience & Nanotechnology

End-to-end design of wearable sensors

H. Ceren Ates et al.

Summary: Wearable sensors that access biophysical and biochemical information can monitor physiological state and aid in diagnosis. These devices can be worn in various forms and have shown potential in early detection and monitoring of diseases. Future wearable sensors are expected to enable multimodal and real-time continuous measurement.

NATURE REVIEWS MATERIALS (2022)

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Review Chemistry, Multidisciplinary

A unified view on catalytic conversion of biomass and waste plastics

Kyungho Lee et al.

Summary: This article summarizes the catalytic conversion of biomass and waste plastics, with a focus on bond activation chemistry and catalyst design. Tracking the historical and recent developments, it is found that biomass and plastic have started to influence each other's fields, providing new insights and opportunities for existing technologies and future advancements.

NATURE REVIEWS CHEMISTRY (2022)

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Article Energy & Fuels

Popcorn-derived porous carbon based adipic acid composite phase change materials for direct solar energy storage systems

Feilong Shao et al.

Summary: As a typical solar energy collector, direct absorption solar collectors (DASCs) have shown great potentials in solar energy utilization. In this study, a direct solar storage system was developed by using biomass-derived porous carbons (PC) as solar energy absorbance materials and adipic acid (AA) as phase change materials (PCMs). The integration of solar energy collection, photo-thermal conversion and long-term energy storage was achieved. The PC-CPCMs-based composite materials showed promising results in terms of photothermal conversion efficiency and thermal conductivity.

JOURNAL OF ENERGY STORAGE (2022)

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Article Nanoscience & Nanotechnology

Thermally Conductive and Leakage-Proof Phase-Change Materials Composed of Dense Graphene Foam and Paraffin for Thermal Management

Hongling Li et al.

Summary: Graphene foams (GFs) with high densities were synthesized to act as interconnected porous networks in shape-stable CPCMs. These CPCMs exhibit excellent thermal stability and shape stability, and have significantly enhanced thermal conductivity compared to pure PCM.

ACS APPLIED NANO MATERIALS (2022)

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Article Nanoscience & Nanotechnology

D-Mannitol/Graphene Phase-Change Composites with Structured Conformation and Thermal Pathways Allow Durable Solar-Thermal-Electric Conversion and Electricity Output

Weizhi Lin et al.

Summary: This study presents a solar thermoelectric generator (STEG) that utilizes a phase-change material (PCM) to achieve durable electricity generation. Through the use of a structured PCM, the STEG exhibits efficient solar-thermal-electric conversion and reliable charging capabilities for electronic devices.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Article Nanoscience & Nanotechnology

Design of Interconnected Carbon Fiber Thermal Management Composites with Effective EMI Shielding Activity

Bin Wu et al.

Summary: This study presents a multifunctional epoxy resin-based composite with interconnected carbon fiber network structure and low thermal resistance interface, achieving excellent thermal conductivity, EMI shielding effectiveness, and mechanical property stability.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Review Chemistry, Multidisciplinary

Aerogels Meet Phase Change Materials: Fundamentals, Advances, and Beyond

Panpan Liu et al.

Summary: Aerogel-based composite phase change materials (PCMs) have significant research and application value. This paper reviews the latest advances in aerogels for high-performance and multifunctional composite PCMs, with emphasis on their applications in acoustic-thermal, solar-thermal-electricity energy conversion, and other fields. The relationships between the structure and thermophysical properties of aerogels in composite PCMs are discussed, as well as the combination of aerogels and 3D printing technology, providing valuable guidance for the rational design of aerogel-based composite PCMs.

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Nacre-Mimetic Hierarchical Architecture in Polyborosiloxane Composites for Synergistically Enhanced Impact Resistance and Ultra-Efficient Electromagnetic Interference Shielding

Shuai Liu et al.

Summary: This study proposes a concept of a nacre-mimetic hierarchical composite that can provide protection against both impact and electromagnetic interference (EMI). The resulting composite demonstrates excellent impact protection with high energy dissipation capacity through strain-rate enhancement, structural densification, lamella dislocation, and crack propagation. Additionally, it exhibits ultra-efficient EMI shielding effectiveness and can be applied in impact monitoring and wireless alarm systems.

ACS NANO (2022)

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Article Environmental Sciences

Use of biochar co-mediated chitosan mesopores to encapsulate alkane and improve thermal properties

Dimberu G. Atinafu et al.

Summary: Phase-change materials (PCMs) play a significant role in energy conservation and thermal management systems, but their excessive seepage and insufficient thermal conductivity limit their real-world applications. In this study, anisotropic-like biochar combined with chitosan was designed to encapsulate dodecane, overcoming the high manufacturing costs and environmental issues associated with PCM supporting materials. The resulting composite PCM exhibited outstanding latent heat retention, high thermal conductivity, leakage-free properties, and repeatable utilization above the melting point of dodecane. This study provides important insights for the development of next-generation sustainable energy storage.

ENVIRONMENTAL RESEARCH (2022)

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Article Polymer Science

Interfacial Friction Controls the Motion of Confined Polymers in the Pores of Nanoparticle Packings

R. Bharath Venkatesh et al.

Summary: The dynamics of confined polymers are influenced by factors such as entanglement, interfacial friction, and environmental conditions. This study investigates the motion of polydimethylsiloxane in silica nanoparticle packings and reveals the interplay of confinement, interfacial friction, and humidity on polymer dynamics.

MACROMOLECULES (2022)

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Article Multidisciplinary Sciences

Continuously processing waste lignin into high-value carbon nanotube fibers

Fuyao Liu et al.

Summary: The high value utilization of renewable biomass materials is crucial for sustainable development. We have developed a method to continuously prepare high-performance carbon nanotube fibers from lignin with satisfactory strength and electrical conductivity. The production rate is also impressive, making this method applicable in various fields.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Sustainable Food Waste Management: Synthesizing Engineered Biochar for CO2 Capture

Xiangzhou Yuan et al.

Summary: This study proposes the use of food waste-derived engineered biochar (FWDEB) for CO2 capture and demonstrates its high adsorption capacity. The CO2 uptake of FWDEB is limited by micropore volume and surface area, specifically the narrow micropores less than 8 angstroms. The KOH activation process generates basic O- and N-functional groups, which enhance the CO2 adsorption of FWDEB. Furthermore, the life cycle assessment confirms the negative net global warming potential of FWDEB-based CO2 capture. This method shows promise in mitigating climate change and achieving a waste-to-resource strategy.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Multidisciplinary

Electrospun Lignin-Based Phase-Change Nanofiber Films for Solar Energy Storage

Li Niu et al.

Summary: Functional phase-change nanofiber films were developed for solar-to-thermal energy conversion and storage. The films showed excellent solar-to-thermal energy conversion and storage ability and have significant implications for addressing the global energy crisis.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Nanoscience & Nanotechnology

Lipophilic Modified Hierarchical Multiporous rGO Aerogel-Based Organic Phase Change Materials for Effective Thermal Energy Storage

Wenxing Luo et al.

Summary: This study introduces a new scheme for preparing shape-stable composite organic PCMs using hydrogel and freeze-drying methods. The rGO-COF aerogel exhibits excellent absorption ability and affinity for PEG, resulting in high PEG loading rate and leak resistance.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Review Chemistry, Multidisciplinary

Engineered Living Materials For Sustainability

Bolin An et al.

Summary: Engineered living materials (ELMs) are a new form of materials composed of living matter or cell communities embedded in self-regenerating matrices or artificial scaffolds. Similar to natural materials like bone and skin, ELMs possess the functional capabilities of living organisms, including the ability to grow, self-organize, self-repair, and perform programmed biological functions upon sensing external cues. ELMs show promise in areas such as green energy production, bioremediation, disease treatment, and fabricating advanced smart materials.

CHEMICAL REVIEWS (2022)

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Article Engineering, Manufacturing

Biomass-based carbon aerogel/Fe3O4@PEG phase change composites with satisfactory electromagnetic interference shielding and multi-source driven thermal management in thermal energy storage

Rongbiao Shen et al.

Summary: By using biomass-based carbon aerogels as porous supporting materials, magnetic Fe3O4@polyethylene glycol was encapsulated to obtain shape-stable composites with excellent thermal storage capability and EMI shielding effectiveness. The addition of Fe3O4 achieved satisfactory EMI shielding effectiveness, and the composites exhibited outstanding performance in multi-source driven thermal management.

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2022)

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Review Environmental Sciences

Waste-derived biochar for water pollution control and sustainable development

Mingjing He et al.

Summary: This review discusses the application of biochar in municipal wastewater treatment, industrial wastewater decontamination, and stormwater management. Biochar can be engineered to target specific contaminants in industrial wastewater treatment and enhance processes in municipal wastewater treatment and stormwater management. The scalability and commercialization of biochar production need to be investigated to maximize environmental, societal, and economic benefits.

NATURE REVIEWS EARTH & ENVIRONMENT (2022)

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Review Engineering, Electrical & Electronic

Sustainable Approach for Developing Graphene-Based Materials from Natural Resources and Biowastes for Electronic Applications

Simran Jindal et al.

Summary: Graphene, with its exceptional characteristics, has become a revolutionary substance that scientists are using various natural resources to synthesize. The research on graphene is exploring its potential in environmental protection and sustainable development.

ACS APPLIED ELECTRONIC MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Solid-Liquid Composites for Soft Multifunctional Materials

Robert W. Style et al.

Summary: Solid-liquid composites, incorporating liquid phases like water, liquid metals, or complex fluids into solid materials, have emerged as a new paradigm in material design, showcasing unique properties and characteristics due to the vastly different properties of liquids and solids. In recent years, the development of solid-liquid composites has led to the study and application of novel materials with new functional responses in various fields, such as soft electronics, robotics, 3D printing, wet granular systems, and cell biology.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

The Future of Flash Graphene for the Sustainable Management of Solid Waste

Najmul Haque Barbhuiya et al.

Summary: The method of flash graphene (FG) production converts bulk quantities of carbonaceous materials into graphene, providing a way to convert various solid wastes containing carbon into valuable products, thus reducing waste volume and enabling resource valorization.

ACS NANO (2021)

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Review Green & Sustainable Science & Technology

Recent Advances in Functionalized Nanoporous Carbons Derived from Waste Resources and Their Applications in Energy and Environment

Stalin Joseph et al.

Summary: This article summarizes the recent research progress in the design and development of waste-derived advanced functionalized porous carbon materials, as well as discussing the methods and technologies used to synthesize these materials. The article highlights the potential applications of these materials in the fields of environment, energy storage, and conversion applications.

ADVANCED SUSTAINABLE SYSTEMS (2021)

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Article Agricultural Engineering

Critical impacts of pyrolysis conditions and activation methods on application-oriented production of wood waste-derived biochar

Mingjing He et al.

Summary: This study investigated the impacts of different pyrolysis conditions and activation methods on the properties of biochar. It found that a temperature of 650 degrees Celsius was effective in forming carbonized structure, while 750 degrees Celsius was critical for the development of a porous structure. Longer pyrolysis duration increased pore volume, and activated biochar had a larger pore volume suitable for high-end applications.

BIORESOURCE TECHNOLOGY (2021)

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Article Chemistry, Physical

Hierarchically porous wood-derived carbon scaffold embedded phase change materials for integrated thermal energy management, electromagnetic interference shielding and multifunctional application

Ming Zhou et al.

Summary: A novel porous wood carbon scaffold/paraffin wax composite has been synthesized, showing excellent energy storage and electromagnetic interference shielding performance, demonstrating great potential in multifunctional applications.

CARBON (2021)

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Review Chemistry, Multidisciplinary

Interfacial Assembly and Applications of Functional Mesoporous Materials

Linlin Duan et al.

Summary: Functional mesoporous materials are synthesized through self-assembly at different interfaces, allowing for unique mesostructures and precise control. Controlling interfacial tension is crucial for influencing the self-assembly process, and recent breakthroughs based on the monomicelles assembly mechanism show promise for enhancing synthesis efficiency and precision of mesoporous materials.

CHEMICAL REVIEWS (2021)

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Article Construction & Building Technology

Evaluation of thermal properties of phase change material-integrated artificial stone according to biochar loading content

Young Uk Kim et al.

Summary: The strength performance of specimens was slightly degraded when 6% biochar was incorporated, while biochar use within 4% yielded similar or higher strength results. Moreover, the thermal conductivity decreased as the amount of biochar in the mixture increased; these thermal conductivity characteristics depended on the pore characteristics of the biochar type.

CONSTRUCTION AND BUILDING MATERIALS (2021)

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Article Chemistry, Physical

Development of Renewable Biomass-Derived Carbonaceous Aerogel/Mannitol Phase-Change Composites for High Thermal-Energy-Release Efficiency and Shape Stabilization

Huan Liu et al.

Summary: This study successfully developed phase-change composites consisting of biomass-derived carbonaceous aerogel (BDCA) and mannitol, which exhibit high thermal energy density and energy-release efficiency. The composites effectively reduce supercooling, improve thermal conductivity, and enhance thermal stability.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Engineering, Environmental

Biomass-derived N-doped porous carbon nanosheets for energy technologies

Satpal Singh Sekhon et al.

Summary: The research on biomass-derived PCNs and their nitrogen doping is crucial for energy conversion, and innovative green methods can improve the production efficiency and sustainability of PCNs, as well as explore suitable preparation methods in different biomasses.

CHEMICAL ENGINEERING JOURNAL (2021)

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Editorial Material Multidisciplinary Sciences

Pathways to tough yet soft materials

Nikola Bosnjak et al.

SCIENCE (2021)

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Article Green & Sustainable Science & Technology

Biomass-derived biochar materials as sustainable energy sources for electrochemical energy storage devices

Chenrayan Senthil et al.

Summary: Biomass and biochar as electrode materials for electrochemical energy storage devices have gained significant research attention due to their abundant sources, efficient production processes, and potential for sustainable energy storage applications. The exploration of biomass towards realizing sustainable energy storage devices is promising with various biomass sources and tailored biochar properties.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

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Article Chemistry, Physical

paper Sustainable self-powered electro-Fenton degradation using N, S co-doped porous carbon catalyst fabricated with adsorption-pyrolysis-doping strategy

Chen Chen et al.

Summary: The study addresses the challenge of developing catalysts with high activity and selectivity in the EF system, as well as the controllable output power of a triboelectric nanogenerator for collecting mechanical energy. By using an adsorption-pyrolysis-doping strategy, the researchers were able to tailor the carbon catalyst to achieve efficient electrosynthesis. They also developed a 3D printed revolving roller-compacted triboelectric nanogenerator for self-powering the EF system, resulting in high decolorization efficiency of resistant mixed basic dyes in industrial wastewater.

NANO ENERGY (2021)

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Review Chemistry, Multidisciplinary

Carbon-Based Composite Phase Change Materials for Thermal Energy Storage, Transfer, and Conversion

Xiao Chen et al.

Summary: Phase change materials offer a way to store renewable thermal energy, with carbon-based composite PCMs showing potential for enhanced performance. However, challenges remain in terms of improving efficiency and expanding applications, highlighting opportunities for future advancements.

ADVANCED SCIENCE (2021)

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Article Energy & Fuels

Walnut shell derived bio-carbon/methyl palmitate as novel composite phase change material with enhanced thermal energy storage properties

Gokhan Hekimoglu et al.

Summary: Two types of bio-carbons were developed from walnut shell, serving as shape stabilizer and thermal conductivity enhancer for phase change materials in thermal controlling applications. The bio-carbons showed impressive performance in preventing leakage of phase change materials and increasing thermal conductivity.

JOURNAL OF ENERGY STORAGE (2021)

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Review Chemistry, Multidisciplinary

Soft Materials by Design: Unconventional Polymer Networks Give Extreme Properties

Xuanhe Zhao et al.

Summary: Hydrogels possess extreme mechanical properties and have diverse applications. While many hydrogels have been developed, a set of general principles for designing them for various applications remains a central need.

CHEMICAL REVIEWS (2021)

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Article Chemistry, Physical

Flexible phase change materials for thermal energy storage

Jinming Shi et al.

Summary: This article reviews the development and applications of flexible phase change materials (PCMs), and discusses their potential in various smart applications as well as the challenges associated with their development.

ENERGY STORAGE MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Efficient Phase-Change Polymer Composite Film from Emulsion Gels Stabilized by Cellulose Nanofiber-Based Amphiphiles

Arindam Chakrabarty et al.

Summary: The study developed a film-forming phase-change polymer synthesized from emulsion gels stabilized by cellulose nanofiber-based amphiphiles, achieving solid-solid phase transition with efficient energy storage performance. The composite film showed a high latent heat for melting and crystallization, providing significant advancement in designing efficient energy-storage materials using plant-derived biocompatible nanomaterials.

ACS APPLIED POLYMER MATERIALS (2021)

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Article Chemistry, Physical

Green, fast and scalable preparation of few-layers graphene

Quanzhu Zhou et al.

Summary: Few-layers graphene was prepared by liquid-phase exfoliation with carbon quantum dots as exfoliating agents, resulting in high yield and excellent properties.

FLATCHEM (2021)

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Article Chemistry, Physical

Self-powered electro-Fenton degradation system using oxygen-containing functional groups-rich biomass-derived carbon catalyst driven by 3D printed flexible triboelectric nanogenerator

Yingzheng Zhu et al.

Summary: This study utilizes 3D printing technology to fabricate a printed flexible wave-like triboelectric nanogenerator for driving the EF system in methylene blue degradation. By exploring high-quality EF catalysts and self-powered aspects, it provides a strong power supply to enhance system performance.

NANO ENERGY (2021)

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Review Chemistry, Physical

Sustainable Carbon Materials toward Emerging Applications

Guojun Lan et al.

Summary: The production and utilization of renewable materials should aim to be carbon neutral for a sustainable society. Sustainable carbon materials, which have applications in CO2 utilization, renewable energy storage, and biomedicine, are gaining attention, but face challenges in energy consumption and environmental pollution during preparation. Developing low-cost, scalable, and environmentally friendly methods for producing sustainable carbon materials, particularly using biomass as a precursor, is crucial for advancement in this field.

SMALL METHODS (2021)

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Article Chemistry, Multidisciplinary

Smart Fibers and Textiles for Personal Health Management

Huimin Wang et al.

Summary: Fibers and textiles are essential in human society, with recent innovations in smart fibers and textiles with sensing, thermal regulation, and energy management capabilities attracting significant interest. These smart materials are predicted to revolutionize personal health management, providing the foundation for intelligent wearables. However, there are challenges such as technological advancements and market competition, with future directions focusing on continuous innovation to meet the demand for smart wearable devices.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Tailoring Highly Ordered Graphene Framework in Epoxy for High-Performance Polymer-Based Heat Dissipation Plates

Junfeng Ying et al.

Summary: By developing a highly ordered graphene framework, embedding it into epoxy, and constructing efficient phonon transport paths, the thermal conductivity of the composite material was effectively improved. The HOGF/EP composite material has a record-high thermal conductivity and shows excellent performance in practical heat dissipation applications.

ACS NANO (2021)

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Review Chemistry, Physical

Fabrication, mechanisms and perspectives of conductive polymer composites with multiple interfaces for electromagnetic interference shielding: A review

Ming Wang et al.

Summary: This paper discusses the importance of EMI shielding materials in modern society, the drawbacks of metal-based materials, and the advantages of conductive polymer composites. The focus is on how CPC with multiple interfaces can enhance EMI shielding effectiveness.

CARBON (2021)

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Article Engineering, Environmental

Introduction of eicosane into biochar derived from softwood and wheat straw: Influence of porous structure and surface chemistry

Dimberu G. Atinafu et al.

Summary: This study explores the use of "green" composite phase change materials prepared using biochar materials and organic phase change material n-eicosane (ES) for efficient thermal energy storage applications. The research found that composite materials derived from wheat straw biochar showed high energy storage capacity, while those derived from softwood biochar had lower latent heat storage capacity.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Hypophosphite tailored graphitized hierarchical porous biochar toward highly efficient solar thermal energy harvesting and stable Storage/Release

Pan-Pan Zhao et al.

Summary: This work demonstrates the fabrication of hierarchical porous carbons (HPCs) derived from chestnuts using aluminum hypophosphite (AP) as an activator, which leads to unique interpenetrating HPC network structures with high pore volume and thermal conductivity. The HPC-stabilized composite PCM with 85 wt% octadecane (Octadecane85@HPC) shows high transition enthalpy and reliability in thermal cycle test, with higher energy storage capacity compared to similar bio-based PCMs. The solar thermal energy conversion efficiency of Octadecane85@HPC reaches 96.1%, indicating excellent solar energy harvesting capacity.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Confined Chemical Transitions for Direct Extraction of Conductive Cellulose Nanofibers with Graphitized Carbon Shell at Low Temperature and Pressure

Duan-Chao Wang et al.

Summary: By controlling the continuous reaction process and isolating oxygen, this research successfully extracted intrinsically conductive cellulose nanofibers from biomass at a low temperature. The synthesis of large-scale twisted graphene films from CNFene suspensions offers new possibilities for applications in energy storage, catalysis, and sensing, while also saving a significant amount of energy compared to traditional methods.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Physical

Progress and Perspectives in Photo- and Electrochemical-Oxidation of Biomass for Sustainable Chemicals and Hydrogen Production

Hui Luo et al.

Summary: Biomass is a recognized ideal resource substitute for fossil fuels, with oxidation derivatives from biomass-derived compounds being used in the production of biodegradable polymers and pharmaceuticals. Combining biomass oxidation with hydrogen generation reactions presents a promising strategy for coproducing high value chemicals and hydrogen.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Hard Carbon Anodes for Next-Generation Li-Ion Batteries: Review and Perspective

Lijing Xie et al.

Summary: Hard carbons, with their enriched microcrystalline structure, have attracted attention as a promising anode material for high-energy LIBs, but face challenges such as low initial efficiency and capacity issues. Current research efforts are focused on addressing these challenges to enable practical application in next-generation batteries.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Different dimensional nanoadditives for thermal conductivity enhancement of phase change materials: Fundamentals and applications

Piao Cheng et al.

Summary: Thermal energy storage technologies based on phase change materials (PCM) have been widely studied for their superb regulation and efficient energy utilization. Adding highly thermal conductive nanoadditives to PCM is an effective strategy to enhance thermal conductivity. The review emphasizes the comparison of different dimensional nanoadditives and their construction of thermally conductive pathways.

NANO ENERGY (2021)

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Article Chemistry, Physical

Three-Dimensional Interpenetrating Network Phase-Change Composites with High Photothermal Conversion and Rapid Heat Storage and Release

Zhijie Bao et al.

Summary: The study focused on the fabrication of three-dimensional interpenetrating network phase-change composites with enhanced thermal conductivity and photothermal conversion capability by adding carbon nanotubes and carbon spheres. These composites show promising potential in solar thermal energy applications.

ACS APPLIED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Synthesis, formation mechanisms and applications of biomass-derived carbonaceous materials: a critical review

Bei Zhang et al.

Summary: The transformation of biomass to carbonaceous materials has attracted increasing attention due to its high carbon content and renewable nature. Various applications of biomass-derived carbonaceous materials are being sought for their potential cost-effective production in an eco-friendly manner. Developing carbon nanomaterials from biomass shows attractive potential for biomass valorization, with discussions on the merits and limitations of various synthesis methods being prominent.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Phase change material-based thermal energy storage

Tianyu Yang et al.

Summary: PCMs with large latent heat show promise for thermal energy storage, but low thermal conductivity limits power density and storage efficiency. Developing high heat capacity PCMs, optimizing device design, and integrating PCM with potential applications are key for future research opportunities in thermal energy storage.

CELL REPORTS PHYSICAL SCIENCE (2021)

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Proceedings Paper Materials Science, Multidisciplinary

3D printed carbon fiber reinforced thermoplastic composites: A review

Nidhi Dixit et al.

Summary: Additive manufacturing technology has advanced to produce functional parts, and researchers are focusing on improving the strength of printed composite materials for various applications.

MATERIALS TODAY-PROCEEDINGS (2021)

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Article Chemistry, Physical

The design of phase change materials with carbon aerogel composites for multi-responsive thermal energy capture and storage

Keyan Sun et al.

Summary: A multi-responsive thermal energy capture and storage system was developed using Fe-doped carbon aerogel as a supporting matrix and eicosane as a PCM. The system can simultaneously respond to light, electricity, magnetism, and temperature, converting various energy sources into thermal energy stored as latent heat. The PCM shows excellent performance, with a mild transition onset temperature, high thermal energy storage density, shape stability, and great phase transition stability even after numerous heating-cooling cycles.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Nanoscience & Nanotechnology

Alkylated Nanofibrillated Cellulose/Carbon Nanotubes Aerogels Supported Form-Stable Phase Change Composites with Improved n-Alkanes Loading Capacity and Thermal Conductivity

Xiaosheng Du et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Engineering, Environmental

Superior and highly absorbed electromagnetic interference shielding performance achieved by designing the reflection-absorption-integrated shielding compartment with conductive wall and lossy core

Wan-Cheng Yu et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Engineering, Chemical

Form-Stable Phase-Change Composites Supported by a Biomass-Derived Carbon Scaffold with Multiple Energy Conversion Abilities

Malik Muhammad Umair et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Green & Sustainable Science & Technology

A novel strategy for enhancing the thermal conductivity of shape-stable phase change materials via carbon-based in situ reduction of metal ions

Yan Chen et al.

JOURNAL OF CLEANER PRODUCTION (2020)

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Phase-Change Materials for Controlled Release and Related Applications

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Conductive Wood for High-Performance Structural Electromagnetic Interference Shielding

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MATERIALS RESEARCH EXPRESS (2020)

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NATURE REVIEWS MATERIALS (2020)

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Tuning surface functionality of standard biochars and the resulting uplift capacity of loading/energy storage for organic phase change materials

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CHEMICAL ENGINEERING JOURNAL (2020)

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NATURE SUSTAINABILITY (2020)

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Preparation of Thermally Conductive Polymer Composites with Good Electromagnetic Interference Shielding Efficiency Based on Natural Wood-Derived Carbon Scaffolds

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Porous carbon supported nanoceria derived from one step in situ pyrolysis of Jerusalem artichoke stalk for functionalization of solution-gated graphene transistors for real-time detection of lactic acid from cancer cell metabolism

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Novel Straw-Derived Carbon Materials for Electromagnetic Interference Shielding: A Waste-to-Wealth and Sustainable Initiative

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Sustainable self-powered electro-Fenton degradation of organic pollutants in wastewater using carbon catalyst with controllable pore activated by EDTA-2Na

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NANO ENERGY (2019)

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Ultrafast Laser Pulses Enable One-Step Graphene Patterning on Woods and Leaves for Green Electronics

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Enhanced Thermal-to-Flexible Phase Change Materials Based on Cellulose/Modified Graphene Composites for Thermal Management of Solar Energy

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Highly Efficient Thermo- and Sunlight-Driven Energy Storage for Thermo-Electric Energy Harvesting Using Sustainable Nanocellulose-Derived Carbon Aerogels Embedded Phase Change Materials

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Ultra-high surface area and nitrogen-rich porous carbons prepared by a low-temperature activation method with superior gas selective adsorption and outstanding supercapacitance performance

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Nanoconfinement effects of N-doped hierarchical carbon on thermal behaviors of organic phase change materials

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Introduction of organic-organic eutectic PCM in mesoporous N-doped carbons for enhanced thermal conductivity and energy storage capacity

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Covalent-supramolecular hybrid polymers as muscle-inspired anisotropic actuators

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Synthesis of porous carbon from cotton using an Mg(OH)(2) template for form-stabilized phase change materials with high encapsulation capacity, transition enthalpy and reliability

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Functionalised heterogeneous catalysts for sustainable biomass valorisation

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Facile synthesis of few-layer graphene from biomass waste and its application in lithium ion batteries

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Unique elastic N-doped carbon nanofibrous microspheres with hierarchical porosity derived from renewable chitin for high rate supercapacitors

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Biocompatible PEG-Chitosan@Carbon Dots Hybrid Nanogels for Two-Photon Fluorescence Imaging, Near-Infrared Light/pH Dual-Responsive Drug Carrier, and Synergistic Therapy

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One-Step Preparation of Form-Stable Phase Change Material through Self-Assembly of Fatty Acid and Graphene

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Porous layer-stacking carbon derived from in-built template in biomass for high volumetric performance supercapacitors

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Review on nanoencapsulated phase change materials: Preparation, characterization and heat transfer enhancement

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Giant Tunneling Piezoresistance of Composite Elastomers with Interlocked Microdome Arrays for Ultrasensitive and Multimodal Electronic Skins

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Emerging Applications of Phase- Change Materials ( PCMs): Teaching an Old Dog New Tricks

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Volatile Times for the Very First Ionic Liquid: Understanding the Vapor Pressures and Enthalpies of Vaporization of Ethylammonium Nitrate

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Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction

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ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Evolution of disposable bamboo chopsticks into uniform carbon fibers: a smart strategy to fabricate sustainable anodes for Li-ion batteries

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Prospective Life Cycle Assessment of Graphene Production by Ultrasonication and Chemical Reduction

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Review on miniaturized paraffin phase change actuators, valves, and pumps

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MICROFLUIDICS AND NANOFLUIDICS (2014)

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A gravure printed antenna on shape-stable transparent nanopaper

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Lightweight and Flexible Graphene Foam Composites for High-Performance Electromagnetic Interference Shielding

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Biodegradable transparent substrates for flexible organic-light-emitting diodes

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ENERGY & ENVIRONMENTAL SCIENCE (2013)

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Two-Dimensional Mesoporous Carbon Nanosheets and Their Derived Graphene Nanosheets: Synthesis and Efficient Lithium Ion Storage

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Tailoring Carbon Nanotube Density for Modulating Electro-to-Heat Conversion in Phase Change Composites

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NANO LETTERS (2013)

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Electro- and Photodriven Phase Change Composites Based on Wax-Infiltrated Carbon Nanotube Sponges

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Conversion of biomass to selected chemical products

Pierre Gallezot

CHEMICAL SOCIETY REVIEWS (2012)

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Black perspectives for a green future: hydrothermal carbons for environment protection and energy storage

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ENERGY & ENVIRONMENTAL SCIENCE (2012)

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KOH activation of carbon-based materials for energy storage

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Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): Study of adsorption isotherms and kinetic models

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CHEMICAL ENGINEERING JOURNAL (2011)

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Biomedical Applications of Biodegradable Polymers

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JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS (2011)

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Thermal properties of graphene and nanostructured carbon materials

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NATURE MATERIALS (2011)

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Covalent Bonded Polymer-Graphene Nanocomposites

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JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2010)

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Unveiling thermal transitions of polymers in subnanometre pores

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NATURE COMMUNICATIONS (2010)

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Sustainable biochar to mitigate global climate change

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NATURE COMMUNICATIONS (2010)

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The origins and evolution of controlled drug delivery systems

Allan S. Hoffman

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Superior thermal conductivity of single-layer graphene

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NANO LETTERS (2008)

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Measurement of the elastic properties and intrinsic strength of monolayer graphene

Changgu Lee et al.

SCIENCE (2008)

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Enhanced mobility of confined polymers

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NATURE MATERIALS (2007)

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Making graphene visible

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APPLIED PHYSICS LETTERS (2007)

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Melt coaxial electrospinning: A versatile method for the encapsulation of solid materials and fabrication of phase change nanofibers

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NANO LETTERS (2006)

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Review Chemistry, Multidisciplinary

Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering

George W. Huber et al.

CHEMICAL REVIEWS (2006)

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Recent progress in the synthesis of porous carbon materials

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General strategies for nanoparticle dispersion

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Electric field effect in atomically thin carbon films

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SCIENCE (2004)

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