Metal-organic framework-decorated PTFE reinforced membranes with immobilized caffeic acid radical scavenger towards improved performance and durability of PEMFC

During the continuous operation of fuel cell, the generated free radicals have an irreversible effect on the proton exchange membrane (PEM), and the introduction of free radical scavengers is an effective strategy for improving its durability. In this study, we proposed to prepare thin and highly durable reinforced membranes by immobilizing organic radical scavenger caffeic acid on the fibrous PTFE supporting layer decorated with amino-functionalized metal-organic framework. The electrostatic force between the amino and sulphonic acid groups can induce an orderly aggregation of hydrophilic cationic groups within the Nafion, endowing the reinforced composite PEMs with superior proton conductivity. The mechanical properties and dimensional stability of the reinforced membranes were effectively enhanced by the reinforcement of the PTFE layer decorated with the MOF network, and the hydrogen crossover was mitigated. The thickness of Nafion reinforced membranes was reduced to 25 mu m with the PTFE reinforcement. After assembling in a single cell, the Nafion composite membrane (PPUC-Nafion-3) with a 3 wt% doping of caffeic acid achieved a maximum power density (PDmax) of 812.64 mW cm-2 and the open circuit voltage (OCV) decay rate of only 1.11 mV h-1 over 100 h. For comparison under the same conditions, recast Nafion possessed a much lower PDmax of only 486.30 mW cm-2 and a higher OCV decay rate of 1.91 mV h-1. This study demonstrates an effective approach to developing highly durable and thin PEMs for the realization of PEMFC with improved output performance and durability simultaneously.

Automated summary

In this study, thin and highly durable reinforced membranes were prepared by immobilizing caffeic acid, an organic radical scavenger, on a fibrous PTFE supporting layer decorated with amino-functionalized MOF. The reinforced membranes exhibited superior proton conductivity, enhanced mechanical properties and dimensional stability, and reduced hydrogen crossover. Compared to recast Nafion, the composite membrane achieved a higher power density and lower voltage decay rate. These findings demonstrate a promising approach for developing durable and thin PEMs for PEMFCs.