期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 487, 期 -, 页码 84-91出版社
ELSEVIER
DOI: 10.1016/j.colsurfa.2015.09.058
关键词
Silver nanopartide; Poly(ethylene oxide)-poly(propylene oxide) block copolymer; Silver nitrate; Silver ion reduction; Reaction temperature; Hydration; Dehydration
We report here on the silver (Ag) nanoparticle synthesis in aqueous solutions of poly(ethylene oxide)poly(propylene oxide) (PEO-PPO) block copolymers in the absence of any additional agents. In particular, we examined the effect of reaction temperature, molecular weight of PEO-PPO block copolymer and PEO-PPO block copolymer concentration on the reduction of silver ions (Ag+) and the resulting formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions. We found that Ag nanoparticles were formed from aqueous silver nitrate (AgNO3) solutions containing PEO-PPO block copolymer above 100 degrees C. This is most likely due to the dehydration of Ag+ caused by thermal motion of water molecules in higher-temperature aqueous solution at high vapor pressure. We also found that the formation of Ag nanoparticles in aqueous PEO-PPO block copolymer solutions was enhanced with larger molecular weight of PEO-PPO block copolymer and with increase in the concentration of PEO-PPO block copolymer in aqueous solutions. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据