Different supported Ni catalysts for dry reforming of methane: Effect of calcination temperature

Due to the increased environmental consciousness about reducing greenhouse gas emissions of CH4 and CO2, an intriguing study issue is the dry reformation of CH4 (DRM) over a catalyst made of Ni.). Herein in this work, 5.0 wt% NiO was loaded on various supports (S = TiO2-P25, Al2O3, MgO, and ZrO2) through the process of dry impregnation. At 600 degrees C or 800 degrees C, the catalysts were then calcined to investigate the impact of calcination temperature on the catalytic performance. The catalysts were characterized by N2 physisorption, Raman spec-troscopy, thermalgravimetric analysis, XRD, and TEM. The best catalyst was obtained when the MgO-supported Ni catalyst was operated at 700 degrees C and was calcined at 600 degrees C. This catalyst gave average conversions of CH4 and CO2 of 70.04 % and 77.2 %, respectively. However, when the calcination temperature of the same catalyst was increased to 800 degrees C, the average conversions of CH4 and CO2 dropped to 37.9 % and 48.07 %, respectively. Thus, the calcination pretreatment strongly influenced the catalyst performance, where rising the calcination tem-perature lowered the activity. The Al2O3-supported sample had the highest surface area, metal-support inter-action, and activity. It produced a large amount of carbon nanotubes, whereas the MgO-supported sample presented the least carbon formation, the lowest deactivation factor, and no morphology change due to the reaction in the TEM.

Automated summary

This study investigates the impact of calcination temperature on the catalytic performance of Ni catalysts supported on different materials. The results show that the calcination temperature strongly influences the catalyst activity, with higher temperatures resulting in lower activity. The Al2O3-supported catalyst exhibits the highest surface area, metal-support interaction, and activity.