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Article
Chemistry, Multidisciplinary
Guanglei Dong et al.
Summary: This study presents an atom-precise 18-copper nanocluster (Cu18H) with a pseudo D-3-symmetrical triple-helical Cu-15 core. Cu18H exhibits unique multi-layered 3D chirality and forms an infinite double-stranded helix through intra-strand and inter-strand interactions. The hierarchical assemblies of Cu18H not only resemble the structure of DNA but also exhibit crystallization-induced emission enhancement and aggregation-induced emission enhancement effects, as well as efficient catalysis of electron transfer reactions.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Minghui Zhu et al.
Summary: In this study, we report a method of using Preyssler anion as a supramolecular template for constructing {Mo22Fe8} macrocycle. The macrocycle exhibits selective anion binding behavior in solution, and the 1:2 host-guest complex formed in the solid state can transport protons more effectively through an extended hydrogen-bonding network.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Hui-Min Zeng et al.
Summary: By controlling the assemblies of rhodamine R6G and [Mo8O26](4-), this study successfully enhances the solid state luminescence of the fluorescent dye and achieves reversible transformation and tunable luminescence. The research provides new ideas for the structural design, synthesis and transformation of POM-based hybrid materials, opening the way towards the design of novel multifunctional hybrid systems.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Physical
Hui-Min Zeng et al.
Summary: The controllable construction of pure inorganic polyoxometalate (POM) zite materials with well-defined secondary building units (SBUs) is challenging. In this work, three distinct POM porous framework compounds 1-3 based on specific SBUs and transition-metal Ag linkers were self-assembled, providing valuable experience for synthetic chemists to obtain more interesting materials. Compound 1-3 exhibit cell type-specific, dose-dependent, and pH-sensitive anticancer behavior, making them promising anticancer agents for lung cancer therapy.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Soumaya Khlifi et al.
Summary: Researchers have developed a unique supramolecular framework by utilizing the affinity between POM and natural cyclodextrins, allowing for the encapsulation of various substances in large cavities and functionalization; X-ray analysis revealed that the framework forms honeycomb and checkerboard-like networks in α-CD and γ-CD, respectively, while leading to a distorted checkerboard-like structure in β-CD.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Chemistry, Inorganic & Nuclear
Naoki Ogiwara et al.
Summary: In this review, the recent advances in POM-based ionic crystals are summarized, including the design strategies, proton conductivity, and mechanisms for proton conduction.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Zhen-Qing Qi et al.
Summary: The development of novel systems for chiral polyoxometalates (POMs) is an attractive research field because of their fascinating topological structures and well-defined functions. Here, we have developed a new reaction route for the synthesis of two unprecedented chiral Waugh POM-based supramolecular architectures. The solution studies corroborate the weak interactions between the components.
CHEMICAL COMMUNICATIONS
(2022)
Review
Chemistry, Inorganic & Nuclear
Hong Chen et al.
Summary: The development of new infrared nonlinear optical crystals with excellent comprehensive performance is urgently needed due to the limitations of currently available materials. Transition-metal-based chalcogenides are identified as promising sources for IR-NLO candidates, offering rich structural diversity and broad IR transparent windows. This review provides insights into the relationship between dimensionality, bandgap, and NLO properties of transition-metal-based chalcogenides, and proposes future directions for the field.
COORDINATION CHEMISTRY REVIEWS
(2021)
Review
Chemistry, Inorganic & Nuclear
Jessica Margalef et al.
Summary: The success of phosphine-oxazoline ligands has led to advancements in P-oxazoline ligand families, resulting in diverse structures and more efficient ligands for asymmetric transformations. Through proper design, these heterodonor bidentate ligand families exhibit superior catalytic performance in a variety of asymmetric reactions.
COORDINATION CHEMISTRY REVIEWS
(2021)
Review
Polymer Science
Hui Zou et al.
Summary: Helical polymers have been extensively studied for their applications in chiral recognition and resolution, showing high chiral recognition ability and depending on their highly ordered helical structures. Recent advances have been made in developing chiral recognition and resolution systems based on helical polymers, especially polyacetylenes and polyisocyanides. This field continues to inspire further research and advancements in chiral-related disciplines.
CHINESE JOURNAL OF POLYMER SCIENCE
(2021)
Article
Chemistry, Inorganic & Nuclear
Hui-Min Zeng et al.
Summary: In this paper, three compounds were synthesized via conventional solution method, with Compound 1 showing excellent catalytic performance for water oxidation due to its unique structure. The Co-Mo complex catalyst based on Compound 1 features a Co-doped 2D porous framework and Co-Mo synergistic effect, providing extraordinary electrocatalytic activity for water oxidation.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Tao Chen et al.
Summary: Hierarchical assemblies of a new silver nanocluster, Ag-70-TPP, have been synthesized and characterized, showing a highly space-efficient double helical 4H close packing pattern directed by ligands. The chirality of Ag-70-TPP and van der Waals forces interactions between ligands play a key role in driving its arrangement, with observed interlocking of phosphine ligands contributing to the structure. This work provides important and unprecedented insights into the internal structure and crystallographic arrangement of nanoclusters.
NANOSCALE HORIZONS
(2021)
Article
Chemistry, Multidisciplinary
Hui-Min Zeng et al.
Summary: This paper investigates a pure 2D inorganic POM-based framework that undergoes a single crystal to single crystal conversion when soaked in organic solvents miscible to water, resulting in a more densely packed identical framework and the formation of nanowires. The change in morphology is closely linked to the surface tension of water, with lower surface tension achieved through dehydration promoting the formation of nanowires, as revealed through SXRD, PXRD, SEM, TGA, and EIS.
NANOSCALE ADVANCES
(2021)
Review
Chemistry, Inorganic & Nuclear
Zexi Zhu et al.
Summary: This article focuses on discussing the generation of chirality for discrete metal oxide clusters, chirality transfer via a supramolecular approach, chirality amplification in self-assemblies, and the related functional properties in solutions. The main goal is to overcome the difficulties in controlling and maintaining a stable chiral state of POMs for further corresponding performances. This review highlights the importance of induced chirality and material properties in solution systems, which have been actively researched but not yet reviewed in this interesting area.
DALTON TRANSACTIONS
(2021)
Review
Chemistry, Multidisciplinary
Bo Han et al.
Summary: Asymmetric organocatalysis has made significant contributions to organic synthesis since the early 2000s, especially in medicinal chemistry. This review provides a comprehensive overview of the specific applications of asymmetric organocatalysis in pharmaceutical synthesis, with a focus on the synthesis strategies of various bioactive molecules and their future prospects.
CHEMICAL SOCIETY REVIEWS
(2021)
Article
Chemistry, Inorganic & Nuclear
Sa Yao et al.
Summary: By varying the charge density of Keggin-type polyoxotungstate anions, the affinity of polyoxometalates (POMs) to gamma-cyclodextrin (γ-CD) was found to be directly correlated, providing insights into their interactions and behavior within supramolecular aggregates.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Multidisciplinary
Soumitra Mokashi-Punekar et al.
ADVANCED MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Jiaomin Lin et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2020)
Article
Chemistry, Multidisciplinary
Jia-Hong Huang et al.
ACS CENTRAL SCIENCE
(2020)
Article
Chemistry, Multidisciplinary
Zhan-Guo Jiang et al.
Article
Nanoscience & Nanotechnology
Lubin Ni et al.
ACS APPLIED MATERIALS & INTERFACES
(2019)
Article
Multidisciplinary Sciences
Chao Liu et al.
NATURE COMMUNICATIONS
(2018)
Article
Chemistry, Multidisciplinary
Clement Falaise et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Multidisciplinary
Akihito Konishi et al.
CHEMISTRY-A EUROPEAN JOURNAL
(2017)
Article
Chemistry, Multidisciplinary
Huayan Yang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2017)
Article
Chemistry, Multidisciplinary
Mhamad Aly Moussawi et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2017)
Article
Chemistry, Multidisciplinary
Mhamad Aly Moussawi et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2017)
Review
Chemistry, Multidisciplinary
Tao Wen et al.
ACCOUNTS OF CHEMICAL RESEARCH
(2017)
Review
Chemistry, Multidisciplinary
Eiji Yashima et al.
Article
Chemistry, Multidisciplinary
I. Caglar Tanrikulu et al.
Review
Chemistry, Multidisciplinary
Minghua Liu et al.
Article
Chemistry, Multidisciplinary
Yilei Wu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2015)
