期刊
ADVANCED ENERGY MATERIALS
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202303192
关键词
large capacity; lithium-oxygen batteries; molecular engineering; redox mediator; shuttle effect
This study demonstrates a method to improve the cycling performance of lithium-oxygen batteries under high capacity conditions by using a redox mediator, D-TEMPO, which promotes the electron transfer between the electrode and Li2O2.
Aprotic lithium-oxygen (Li-O-2) batteries hardly cycle at the condition of high area capacity for realizing their high energy density, because the unconducive lithium peroxide (Li2O2) discharge product limits the electron transfer between electrode and O-2/Li2O2. Here, it is demonstrated that one of redox mediator (RM), triethylene glycol bis-2,2,6,6-tetramethylpiperidin-1-oxyl radical (D-TEMPO), can be effectively used to promote the electron transfer between electrode and Li2O2, which the shuttle effect of RM can be cooperatively inhibited by regulating the size of RM and the thickness of ion-selective membrane. As a result, the Li-O-2 battery coupled with double cathodes, D-TEMPO, and ion-selective membrane can be stably operated for 46 days at a capacity of 5 mAh cm(-2). The concept in this work provides the cooperative design of a stable solution-mediated pathway for high-capacity Li-O-2 battery with long cycle stability.
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