4.8 Article

Poly(lactic acid) stereocomplex microspheres as thermally tolerant optical resonators

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NANOSCALE
卷 15, 期 47, 页码 19062-19068

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d3nr05318k

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Thermally tolerant polymer optical resonators are prepared from a stereocomplex of poly(l-lactic acid) and poly(d-lactic acid). The microspheres of the stereocomplex poly(lactic acid) exhibit higher thermal stability compared to homochiral poly(lactic acid). The optical resonator properties of the microspheres are preserved at elevated temperatures.
Thermally tolerant polymer optical resonators are fabricated from a stereocomplex of poly(l-lactic acid) and poly(d-lactic acid) through the oil-in-water miniemulsion method. The thermal stability of the microspheres of the stereocomplex poly(lactic acid) (SC-PLA) is superior to that of the homochiral poly(lactic acid) (HC-PLA). As a result of the high thermal stability, the optical resonator properties of the SC-PLA microspheres are preserved at an elevated temperature of up to 230 degrees C, which is 70 degrees C higher than that of microspheres formed from HC-PLA. Thermally tolerant polymer optical resonators are fabricated from a stereocomplex of poly(l-lactic acid) and poly(d-lactic acid) through the oil-in-water miniemulsion method.

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