The electronic states of iodo-bridged platinum nanowire complexes were investigated using polarized FT-IR spectroscopy. The N-H symmetrical stretching mode was found to be highly sensitive to the electronic states, distinguishing between mixed-valence (MV) and averaged-valence (AV) states. The first Pt(iii) nanowire complexes were synthesized by applying chemical pressure to the counter-anions.
The electronic states of iodo-bridged platinum nanowire complexes have been studied using polarized FT-IR spectroscopy. The N-H symmetrical stretching mode was found to be highly sensitive to the electronic states, distinguishing mixed-valence (MV) and averaged-valence (AV) states. The first Pt(iii) nanowire complexes have been realized by the chemical pressures of the counter-anions.
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