期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 970, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.172651
关键词
Kesterite; Heterojunctions; Intrinsic mechanism; Band alignment
This study investigates the effects of ultrathin Al2O3 on the photovoltaic performance of CZTSSe solar cells. The results show that appropriate treatment with Al2O3 can promote the separation and transport of photogenerated carriers, thereby enhancing the performance of the cells.
The p/n heterojunction with low surface recombination losses and good band alignment is one of the key factors for obtaining efficient photovoltaic (PV) devices. Here, ultrathin Al2O3 is introduced, and the effects of its thickness and growth temperature on the PV performance of Cu2ZnSn(S,Se)4 (CZTSSe) solar cells are investi-gated. The result indicates that the increased depletion width and built-in voltage after appropriate Al2O3 treatment promote the separation and transport of photogenerated carriers. The absorber surface composition and defect are optimized, and the interface band alignment is modified by reducing the conduction band offset successfully, which drives the carrier collection and increases open-circuit voltage by 60 mV. The dual passiv-ation mechanism of chemical passivation and field-effect passivation is realized by introducing Al2O3 into kes-terite solar cells. This work not only reveals the intrinsic mechanism for performance enhancement CZTSSe solar cells with Al2O3, but also provides a significant guidance for the band adjustment at the interface.
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