Experimental and theoretical study to control the heavy metals in solid waste and sludge during pyrolysis using modified expanded vermiculite

Na+/K+/Mg2+/Ca2+ expansion-modified vermiculite and calcination expansion (700 degrees C, 800 degrees C and 900 degrees C)- modified vermiculite (700-Mg-V, 800-Mg-V and 900-Mg-V) were prepared as additives to control the emission of five heavy metals (Zn, Cr, Cu, Pb, and Cd) during the pyrolysis of municipal sewage sludge, paper mill sludge, municipal domestic waste, and aged refuse. Mg2+-Modified vermiculite obtained via thermally activated calci-nation at 800 degrees C retained 65% of heavy metals from all raw materials at 450 degrees C. Zn, Cr, and Cu retained nearly 90%. Although modified vermiculite could reduce the ecological risk, Cd had an ecological risk level higher than Zn, Cr, Cu, and Pb. The fine textural properties, laminated morphology, and expansion capacity of modified vermiculite were positively correlated with its retention of heavy metals. Heavy metals interacted with the (002) surface of vermiculite, and the reactions were mainly concentrated near the 17-O and surrounding atoms. The heavy-metal monomers were less capable of binding to the (002) surface of vermiculite than the oxides and chlorides of heavy metals. The effect of heavy-metal oxides and chlorides binding to the (002) surface of vermiculite was related to heavy metals.

Automated summary

Na+/K+/Mg2+/Ca2+ expansion-modified vermiculite and calcination expansion-modified vermiculite were used to control the emission of heavy metals during pyrolysis. The retention of heavy metals by modified vermiculite was influenced by its textural properties, morphology, and expansion capacity.